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Cumulenes and Allenes
Synthesis of Phosphinobutatrienes from 2-Vinyl-1-phosphirenes and Alkyllithium Reagents
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Author(s):
M. Ogasawara
Publication date
(Online):
2008
Publisher:
Georg Thieme Verlag KG
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Synthesis of 2-trifluoromethylated piperidines and azepanes
Author and book information
Book Chapter
Publication date (Print):
2008
Publication date (Online):
2008
Page
: 1
DOI:
10.1055/sos-SD-044-00046
SO-VID:
657b0185-6267-4058-ab37-0462490875dc
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Book chapters
pp. 1
Dehydrohalogenation of 1-Halocyclooctenes
pp. 1
1,6-Elimination of Alcohols
pp. 1
1,4-Dehalogenation of 1,4-Dihaloalk-2-ynes
pp. 1
1,1-Dehalogenation and Rearrangement of 2-Alkenylidene-1,1-dihalocyclopropanes
pp. 1
Synthesis by Rearrangement
pp. 1
1,6-Addition of Bromine to 1,5-Dien-3-ynes
pp. 1
1,4-Addition of Hydrosilanes to Conjugated Enynes
pp. 1
Ring Enlargement of 2-(Diazomethyl)bicyclo[4.4.1]undeca-1,3,5,7,9-pentaene
pp. 1
Thermal Decomposition of a Disodium Salt of a Cyclobutane-1,3-dione Bis(tosylhydrazone)
pp. 1
In Situ from Ortho Esters and a Propargyl Alcohol
pp. 1
Synthesis of Product Subclass 7
pp. 1
Of 1-Halogen-Substituted Allenes
pp. 1
[2+2] Cycloadditions
pp. 1
From (-1-Bicyclo[6.1.0]non-9-yl)-1-nitrosourea
pp. 1
Arylations and Vinylations
pp. 1
Allylzinc Intermediates from Alkynyl Sulfoxides and Alkynyl Sulfones
pp. 1
Wittig Alkenations and Related Reactions
pp. 1
From 1,1,3,3-Tetraalkylallenes
pp. 1
Reduction of α-Carbonyl-Substituted Allenes
pp. 1
Trapping of Hexapentaenylidene Species
pp. 1
With Allenyl Ethers and Ketones
pp. 1
Wittig Reaction of Alka-2,3-dienoyl Chlorides with Alkylidenephosphoranes
pp. 1
From Arylalkynes and Alkynes
pp. 1
[3+2] Cycloadditions of Allenes
pp. 1
Ring-Closing Alkene Metathesis by Using Grubbs' First-Generation Catalyst
pp. 1
Synthesis of Product Subclass 2
pp. 1
Lithium-Mediated Reactions
pp. 1
Using Tributyltin Hydride
pp. 1
From 1,3-Diethynylallenes
pp. 1
Dimerization of Allenylidene Species
pp. 1
Ring Enlargement by Extrusion of Nitrogen from 7-Diazobicyclo[2.2.1]hepta-2,5-diene
pp. 1
Photorearrangement of Vinylidenecyclopropanes to Butatriene Derivatives
pp. 1
Oxidation of Heteroatom-Substituted Allenes
pp. 1
From 1,1-Dihalocyclopropanes
pp. 1
Substitution of 2-Halobuta-1,3-dienes and Related Compounds
pp. 1
Addition Reactions
pp. 1
Ring-Closure Reactions
pp. 1
Double Dehydrohalogenation of 2,3-Dihalobut-2-enes
pp. 1
Zirconium-Mediated Coupling Reactions of 1,3-Diynes with Aldehydes or Ketones
pp. 1
From α,β-Unsaturated Substrates
pp. 1
Synthesis of Product Subclass 5
pp. 1
Prototropic Rearrangements
pp. 1
Oxidation Reactions
pp. 1
[3,3]-Sigmatropic Rearrangements
pp. 1
Dehydrohalogenation of 2-Halopropenes
pp. 1
Rearrangements
pp. 1
Via In Situ Formation of Propargyl Sulfenates
pp. 1
Reactions of Propargylic Amine Derivatives
pp. 1
Oxidative Cyclizations of Enallenes
pp. 1
Dehydrosilylation of Silyl Enol Ethers
pp. 1
Ring Enlargement by the Doering–Moore–Skattebøl Reaction
pp. 1
Copper-Mediated Reactions
pp. 1
Debromosulfinylation from 1-(Bromomethyl)vinyl Sulfides
pp. 1
Using Acid Chlorides
pp. 1
Palladium-Catalyzed Reactions of Propargylic Substrates
pp. 1
Double Dehydrohalogenation of 1,4-Dihalobut-2-enes
pp. 1
Hydrolysis of 1-Cyano-Substituted Allenes
pp. 1
Ring Transformations
pp. 1
Lithiation and Silylation of Hexa-2,4-diynes
pp. 1
Aldol Additions of Allenyl Enolate
pp. 1
Ring Enlargement by Thermolysis of Tricyclo[4.1.0.0]hept-5-ylidene or 1-Ethynyl-2-vinylcyclopropane
pp. 1
Macrocyclic Allenes
pp. 1
Using Photochemical Methods
pp. 1
1,1-Dehalogenation and Rearrangement of 1,1-Dihalocyclopropanes
pp. 1
Base-Promoted Reactions
pp. 1
Wittig Reaction of Aldehydes or Ketones with Allenylidenephosphoranes
pp. 1
Condensation of Propargylsilanes with Carbonyl and Related Compounds
pp. 1
Intermolecular Reactions To Form Heterocyclic Products
pp. 1
Synthesis of Product Subclass 4
pp. 1
Dehydration
pp. 1
Electrocyclization of Octa-3,5-diene-1,7-diynes
pp. 1
Double Dehydrobromination of 2,4-Dibromopenta-1,4-dienes
pp. 1
Double Alkenation Using Titanium-Substituted Ylides
pp. 1
Retro-Diels–Alder Reactions
pp. 1
Ring-Opening Reactions
pp. 1
Of α-Halogen-Substituted Allenes
pp. 1
Debromination of 3,4-Dibromohexa-1,2,4,5-tetraenes
pp. 1
Reductive 1,4-Dechlorination of a 2,5-Dichloropent-1-en-3-yne
pp. 1
Dehalogenation of 1,1-Dihalocyclopropanes through Carbenoid Intermediates
pp. 1
Dimerization of Allenylidene–Chromium Species
pp. 1
Elimination from Vinyl- and Allylmetal Intermediates
pp. 1
From Nonactivated Substrates
pp. 1
Dimerization of Vinylidene Species or Vinylidene Equivalents Generated from -Dihaloalkenes
pp. 1
Base-Promoted Rearrangement of a Conjugated Bisallene to an Alkenylbutatriene
pp. 1
Debromosulfinylation of 1-(Bromomethyl)vinyl Sulfoxides and Sulfimides
pp. 1
Condensation of Other Propargylic Organometallic Reagents with Carbonyl Compounds
pp. 1
From Diarylacetylenes and Alkynes
pp. 1
Dimerization of Vinylidene Species or Vinylidene Equivalents Generated from 1-Halo-1-hydroalkenes
pp. 1
Base-Induced Borane Elimination from Bis(1-iodoalkenyl)boranes
pp. 1
Substitution Reactions of Metalated Allenes
pp. 1
Carbonylations
pp. 1
Reactions with Copper Acetylides
pp. 1
From Two Arylalkynes
pp. 1
Double Wittig Reaction of a Phosphorus Diylide with an Aldehyde
pp. 1
Reactions with Enol Ethers
pp. 1
Reduction of Allenes Bearing an Epoxide Moiety
pp. 1
Vinylcopper and Vinylmagnesium Intermediates from Propargyl Ethers and Organocopper and Organomagnesium Reagents
pp. 1
Alkenation Reactions
pp. 1
Samarium-Mediated Reactions
pp. 1
Of 1-Oxygen-Substituted Allenes
pp. 1
Of Acylsilanes
pp. 1
Ene Reactions
pp. 1
Chromium-Catalyzed Reactions
pp. 1
Reduction of Alkynyl-Substituted Allenes
pp. 1
Diels–Alder Reactions of Allenes
pp. 1
Palladium-Catalyzed Double Arylation of 1,4-Diaryl-1,3-diynes
pp. 1
Desulfurization–Dimerization of Dithioacetals with Hexacarbonyltungsten(0)
pp. 1
Reactions with Copper Cyanide
pp. 1
Aluminum-Mediated Reactions of Propargylic Substrates
pp. 1
Miscellaneous Methods
pp. 1
Stoichiometric Deprotonation Followed by Protonation
pp. 1
Cyclohexa-1,2-dienes
pp. 1
Elimination from β-Sulfinylallyl Alcohol Derivatives
pp. 1
Wittig-Type Alkenation from Aromatic Dialdehydes
pp. 1
Vinylzirconium and Vinyltitanium Intermediates from Propargyl Ethers and Propargyl Bromides
pp. 1
Retro-Diels–Alder Reaction
pp. 1
Reactions Using Various Copper Nucleophiles
pp. 1
Of α-Oxygen-Substituted Allenes
pp. 1
Double Elimination of Methanol from 1,7-Dimethoxyhepta-2,4-diynes
pp. 1
Of Donor-Substituted Allenes
pp. 1
Ruthenium-Catalyzed Reactions
pp. 1
Of Acceptor-Substituted Allenes
pp. 1
1,4-Addition of Hydrogen Halides and Halogens to Conjugated Enynes
pp. 1
Alkynylations
pp. 1
Synthesis via Alkenylidenemagnesium Intermediates
pp. 1
Reduction of Pent-2-en-4-yn-1-ols with Lithium Aluminum Hydride
pp. 1
Condensation of Propargylboranes with Carbonyl and Related Compounds
pp. 1
Using Aryl Esters
pp. 1
Reactions with Hydride Reagents
pp. 1
From 4-Hydroxybut-2-ynylstannanes
pp. 1
1,4-Addition of Nucleophiles to Ynones and Ynoates
pp. 1
Other Methods for the Synthesis of Butatrienes
pp. 1
From Vinylalkynes and Alkynes
pp. 1
Sulfur Elimination from Alkylidenecyclopropanethiones
pp. 1
Reactions with Oxygen Nucleophiles
pp. 1
1,2-Dehalogenation of 2,3-Dihalo-1,3-dienes
pp. 1
1,2-Dehydration of Alka-2,3-dienols
pp. 1
Prins Reaction of Allenes
pp. 1
Asymmetric Elimination Using Sharpless Oxidation
pp. 1
Substituent Modification
pp. 1
1,6-Addition of Organometallic Reagents to Acceptor-Substituted Enynes
pp. 1
Synthesis via Alkenyltitanocene Derivatives
pp. 1
Thermal and Photochemical Decomposition of Sodium Salts of Cyclohepta-2,4,6-trien-1-one Tosylhydrazone
pp. 1
Intramolecular Reactions
pp. 1
Reactions of Propargylic Ethers
pp. 1
Elimination of Alcohols and Related Reactions
pp. 1
Electrocyclization of ()-Hexa-1,3-dien-5-ynes
pp. 1
[6]- and Higher Cumulenes
pp. 1
With Allenes
pp. 1
From 1,1-Dibromocyclopropanes
pp. 1
Reactions of Allenylidene Species with Diazoalkanes
pp. 1
Spontaneous Rearrangement on Chromatographic Workup
pp. 1
Of α-Functionalized Allenes
pp. 1
S2″ Substitution on Pent-4-en-2-ynyl Derivatives and Related Reactions
pp. 1
Of Cyclic Ethers, Amines, and Sulfides
pp. 1
Reactions of Zirconacycles with Aldehydes To Form Butatrienyl Monoalcohols
pp. 1
Butatrienes ([3]Cumulenes)
pp. 1
Amination, Amidation, and Imidation Reactions
pp. 1
Condensation of Propargylstannanes with Carbonyl and Related Compounds
pp. 1
Dehalogenation of 1,7-Dihalocycloheptenes
pp. 1
Hexapentaenes ([5]Cumulenes)
pp. 1
From 1,3-Diarylallenes
pp. 1
Synthesis Using or via (Hydroxyalkenyl)phosphonate and (Hydroxyalkenyl)phosphine Oxide Intermediates
pp. 1
Dimerization of Vinylidene Species or Vinylidene Equivalents
pp. 1
Using Tris(trimethylsilyl)silane
pp. 1
Horner–Emmons-Type Reactions of Aldehydes or Ketones
pp. 1
S2′ Substitution of Organocopper(I) Reagents with a 3-Alkoxyalkyne
pp. 1
[2+2]-Cycloaddition Reactions of Allenes
pp. 1
Using Thermal Methods
pp. 1
Pyrolysis of Hexakis(trimethylsilyl)but-2-yne
pp. 1
Pauson–Khand Reactions of Allenes
pp. 1
Of Spiroketals
pp. 1
Gallium-Mediated Reactions
pp. 1
Allenes as Precursors
pp. 1
With Alkylcopper Reagents
pp. 1
Of Lactones
pp. 1
Dehydrohalogenation of 3-Bromo-1,2-dihydronaphthalenes
pp. 1
Dimerization of Allenylidene Species Generated from Propargylic Precursors
pp. 1
Dehydrohalogenation of 1-Halocycloheptenes
pp. 1
Desulfurization of Cyclic Trithiocarbonates
pp. 1
Elimination from Vinyl Sulfoxides and Vinyl Sulfones
pp. 1
Ring Enlargement of Bicyclo[5.1.0]octa-3,5-dien-2-one
pp. 1
Nickel-Mediated Reactions
pp. 1
[3+2] Cycloadditions
pp. 1
Cycloocta-1,2-dienes
pp. 1
Other Methods Involving Elimination
pp. 1
With Ketones
pp. 1
Extrusion of Nitrogen from an Aryldiazomethane
pp. 1
Reactions with CH-Acidic Compounds
pp. 1
Of Nonactivated Allenes
pp. 1
Reactions of Propargylic Sulfonates
pp. 1
Cyclodeca-1,2-dienes
pp. 1
Reactions with Zinc Reagents
pp. 1
Synthesis from 2-Halo-3-(trimethylsilyl)cycloheptenes
pp. 1
From 9,9-Dibromobicyclo[6.1.0]nonane Derivatives
pp. 1
Synthesis by Elimination
pp. 1
Dimerization of Vinylidene–Tungsten Species
pp. 1
1,4-Addition of Hydroboranes to Conjugated Enynes
pp. 1
Reactions with Aluminum or Tin Reagents
pp. 1
Single Dehydrohalogenation of Haloallenes
pp. 1
Thermal Claisen Rearrangement of Propargyl Vinyl Ethers
pp. 1
Reactions of Propargylic Alcohols
pp. 1
Baylis–Hillman-Type Reaction of Alkenylphosphorus Compounds with Aldehydes
pp. 1
Cyclohexa-1,2,4-trienes
pp. 1
Wittig Reaction of Carbon Suboxide with Alkylidenephosphoranes
pp. 1
[4+2]-Cycloaddition Reactions
pp. 1
1,3-Elimination from Substituted Vinylic or Allylic Derivatives
pp. 1
Dehydration of Ketones
pp. 1
Synthesis of Product Subclass 6
pp. 1
Formation of a Butatriene from 2-Nitro-1,1-diphenylethene
pp. 1
Reactions of 1,2,3-Trienylidene Species with Group 14 Hydrides
pp. 1
Reactions of Propargylic Halides
pp. 1
With Allenyl Ethers and Amides
pp. 1
Base-Promoted Hydrogen Transfer from a Cycloalk-3-ynone
pp. 1
Pentatetraenes ([4]Cumulenes)
pp. 1
With Allenyl Ethers and Nitriles
pp. 1
Transition-Metal-Catalyzed Cross-Coupling Reactions of Allenes
pp. 1
Elimination from Phenyl Vinyl Selenoxides
pp. 1
Alkylations
pp. 1
Intermolecular [4+2]-Cycloaddition Reactions
pp. 1
Wittig Reaction of a Ketene with a Vinylidenephosphorane
pp. 1
[5+2] Cycloadditions of Allenes
pp. 1
1,4-Disilylation of 1,4-Disilyl-1,3-diynes by a Silylmanganese Reagent
pp. 1
Dehydrohalogenation of 1-Halocyclononenes
pp. 1
Dehydrohalogenation of 1-Halocyclohexenes
pp. 1
Elimination from 2-Halo-3-(trimethylsilyl)cyclohexenes
pp. 1
Carbonylation Reactions
pp. 1
Magnesium-Mediated Reactions
pp. 1
Dehydroxylation of Hexa-2,4-diyne-1,6-diols
pp. 1
1,4-Disilylation of 1,4-Disilyl-1,3-diynes
pp. 1
1,2- and 1,4-Elimination from 5-Methoxypent-2-yn-1-ols
pp. 1
Substitution Reactions of Oxygen- and Halogen-Substituted Allenes
pp. 1
Sulfur Elimination from Penta-1,2,3,4-tetraene Episulfides
pp. 1
Oxidation of Alkynyl-Substituted Allenes
pp. 1
Reduction of Alka-4,5-dien-2-ynols or Related Alcohols by Lithium Aluminum Hydride
pp. 1
Organocopper-Mediated Reactions of Propargylic and Related Substrates
pp. 1
Reactions with Sulfur Nucleophiles
pp. 1
Sulfanyl-, Selanyl-, or Carbometalation of Alkynylphosphine Oxides and Reaction with Aldehydes
pp. 1
1,4-Addition of Carbon Pronucleophiles to Conjugated Enynes
pp. 1
Dehalogenation of 2,3-Dihalopropenes and Deoxyhalogenation of β-Haloallyl Alcohol Derivatives
pp. 1
Dehydroxylation of Alk-2-yne-1,4-diols
pp. 1
1,4-Elimination from 4-Hydroxybut-2-ynylsilanes or -stannanes
pp. 1
Bicyclo[4.4.0]deca-1,3,5,7,8-pentaenes
pp. 1
Elimination from β-Sulfinylallyl Alcohol Derivatives and 1-(Sulfinylalkyl)vinyl Trifluoromethanesulfonates
pp. 1
Synthesis by Substitution
pp. 1
Synthesis by Addition
pp. 1
Synthesis of Product Subclass 3
pp. 1
Ring Enlargement by Cope Rearrangement from 1,2-Diethynylcyclopropanes
pp. 1
Iron-Catalyzed Reactions of Propargylic Substrates
pp. 1
Reduction of α,ω-Dihydroxypolyynes
pp. 1
Dimerization of Terminal Alkynes by Transition-Metal Catalysts
pp. 1
Reactions of Various Propargylic Substrates
pp. 1
Reductions of Allenes
pp. 1
Synthesis of Enantiomerically Enriched Allenes
pp. 1
Ring Enlargement by Extrusion of Nitrogen from 2-Diazobicyclo[3.2.0]hepta-3,6-diene and Its Benzo Derivative
pp. 1
From 1-Bromo-1-fluorocyclopropanes
pp. 1
Reactions with Borane Reagents
pp. 1
Of Spirobisepoxides
pp. 1
Miscellaneous Reactions
pp. 1
Zinc-Mediated Reactions
pp. 1
Dehydrohalogenation of 3-Bromocyclooct-3-en-1-one
pp. 1
On Pent-4-en-2-ynyl Methanesulfinates with Alkylsilver(I) Reagents
pp. 1
Elimination from Enol Phosphates
pp. 1
Elimination Reactions, Rearrangements, and Metathesis Reactions
pp. 1
[2+1] Cycloadditions
pp. 1
1,5-Substitution Reactions
pp. 1
Synthesis of Product Subclass 3
pp. 1
Palladium-Catalyzed Reactions
pp. 1
Synthesis of Product Subclass 9
pp. 1
Dehydrohalogenation of Halocycloheptatrienes
pp. 1
Cyclonona-1,2-dienes
pp. 1
Wittig Reaction
pp. 1
Palladium-Catalyzed 1,4-Disilylation of 1,4-Disilyl-1,3-diynes
pp. 1
With Soft Carbon Nucleophiles Catalyzed by a Palladium Complex
pp. 1
1,4-Addition of Organometallic Reagents to Conjugated Enynes
pp. 1
Reactions of Allenylidene–Rhodium Complexes with Diazomethane
pp. 1
From 7-Bromo-7-(trimethylstannyl)bicyclo[4.1.0]heptane
pp. 1
Other Reactions with Carbon Nucleophiles
pp. 1
Nitrogen Elimination by Oxidation of Pyrazol-3-ones Using Lead(IV) Acetate
pp. 1
Intramolecular [4+2]-Cycloaddition Reactions
pp. 1
Oxidation of Hexapentaenes Followed by Carbon Monoxide Elimination
pp. 1
Synthesis of Product Subclass 1
pp. 1
With Aldehydes
pp. 1
Additions on α-Carbonyl-Substituted Allenes
pp. 1
Elimination from 1-(Sulfinylalkyl)vinyl Trifluoromethanesulfonates
pp. 1
Reactions with Samarium Reagents
pp. 1
S2′ Substitution of Organocopper Reagents with a 3-Alkoxyalkyne
pp. 1
On 2-(But-3-en-1-ynyl)oxiranes with Alkylsilver(I) Reagents
pp. 1
Borane- or Gallium-Mediated Reactions of Propargylic Substrates
pp. 1
S2′ Substitution of Organocopper Reagents with 3-Acetoxycycloalkynes
pp. 1
Using Catalytic Potassium -Butoxide
pp. 1
Oxidation of Carboxy-Substituted Allenes
pp. 1
1,4-Elimination of Alcohols
pp. 1
Elimination from 1,1-Disubstituted Cyclopropane Derivatives
pp. 1
[4+2] Cycloadditions
pp. 1
Oxidation with 3-Chloroperoxybenzoic Acid
pp. 1
Synthesis via β-Hydroxyallylphosphonate Derivatives Prepared from Ketenes or Ketene Equivalents
pp. 1
Electrophilic 1,4-Addition to 1,3-Diynes
pp. 1
Claisen Rearrangement of Allenyl Ethers
pp. 1
Synthesis Mediated by Carbene Species
pp. 1
Oxidation of α-Hydroxy-Substituted Allenes
pp. 1
With Imines
pp. 1
Synthesis from 1,1-Dimetalloalkenes
pp. 1
Additions to Heteroatom-Substituted Allenes
pp. 1
Miscellaneous Reactions of Propargylic Substrates
pp. 1
Substitution of Haloallenes
pp. 1
Synthesis of Product Subclass 1
pp. 1
Metathesis and Cycloisomerization
pp. 1
Synthesis of Product Subclass 4
pp. 1
Lithium-, Magnesium-, or Zinc-Mediated Reactions of Propargylic and Related Substrates
pp. 1
Synthesis of Phosphinobutatrienes from 2-Vinyl-1-phosphirenes and Alkyllithium Reagents
pp. 1
Reactions Involving Allenylidene Species
pp. 1
Palladium(0)-Catalyzed Carbonylation of a Macrocyclic Propargylic Methanesulfonate in the Presence of an Alcohol
pp. 1
[2,3]-Sigmatropic Rearrangements
pp. 1
Coupling Reactions between 1,1-Dichloroalkenes and Terminal Alkenes
pp. 1
Synthesis from 3-Oxo-, 3-Acetoxy-, or 3-Mesyloxy Cyclic Alkynes
pp. 1
Reduction of Heteroatom-Substituted Allenes
pp. 1
Ring-Opening Reactions of Epoxides
pp. 1
Via In Situ Formation of Propargyl Phosphinites
pp. 1
Ring Enlargement by Photochemical Rearrangement of 2-Ethynylcycloheptanone
pp. 1
Friedel–Crafts Acylation and Alkylation of Conjugated Enynes
pp. 1
Eliminations
pp. 1
From 4-Hydroxybut-2-ynylsilanes
pp. 1
Synthesis of Product Subclass 8
pp. 1
Nazarov Reactions
pp. 1
Dehydration of Allylic Alcohols
pp. 1
Reactions of 1,2,3-Trienylidene Species with Alkenes
pp. 1
Vinylpalladium Intermediates from -Propargylsulfonamides
pp. 1
Zirconocene-Mediated Reactions
pp. 1
Conjugate Addition of Organometallic Reagents to Acceptor-Substituted Enynes
pp. 1
Dehydrohalogenation
pp. 1
Cyclohepta-1,2-dienes
pp. 1
Reactions of 1,2,3-Trienylidene Species
pp. 1
Reactions with Nitrogen Nucleophiles
pp. 1
Dimerization of Allenylidene Species Generated from Bromoallenes
pp. 1
Borane-Mediated Reactions
pp. 1
S2″ Substitution on Penta-2,4-diynyl Esters
pp. 1
1,8-, 1,10-, and 1,12-Addition of Organometallic Reagents to Acceptor-Substituted Enynes
pp. 1
Ring Enlargement by Cope Rearrangement from 1,2-Diethynylcyclobutane and 1-Ethynyl-2-vinylcyclobutane
pp. 1
Metal–Vinylidene Routes to Allenes
pp. 1
Photochemical or Thermal Reaction of Intermediate Allyl Anions
pp. 1
Peterson Reaction
pp. 1
Base-Promoted Cyclization of 1-(3-Chloropropyl)-7-(3-phenylprop-2-ynyl)tricyclo[4.1.0.0]heptane
pp. 1
Dimerization of Alkenylidene Species Generated from Dialkenylcuprates
pp. 1
Via In Situ Formation of Propargyl Phosphites
pp. 1
Reactions with Grignard Reagents
pp. 1
S2′ Substitution on 2-Bromo-1-en-3-ynes
pp. 1
Synthesis from 1-Halo-1-(phenylsulfinyl)cyclopropanes via Carbenoid Intermediates
pp. 1
Flash-Vacuum Pyrolysis of Thiocyanates and Related Compounds
pp. 1
Dehalogenation of 2,3-Dihalocyclohexenes
pp. 1
Rearrangement and Dehydration of Epoxyalkynols
pp. 1
Reactions of Zirconacycles with Ketones To Form Butatrienyl Diols
pp. 1
Double Dehydrochlorination and Ring Opening of 1,1-Dichlorocyclopropanes
pp. 1
Elimination from Vinylsilanes and Vinylstannanes
pp. 1
Wittig and Related Reactions
pp. 1
Dehydrohalogenation of 1-Halocyclohexa-1,4-dienes
pp. 1
Via [2,3]-Wittig Rearrangement
pp. 1
Asymmetric Elimination Using Chiral Diferrocenyl Diselenides
pp. 1
Dehalogenation
pp. 1
Synthesis of Product Subclass 2
pp. 1
Intramolecular Ene Reaction of Oct-1-ene-7-yne
pp. 1
Intermolecular Reactions To Form Carbocyclic Products
pp. 1
Halogenation of Propargylic Substrates
pp. 1
Cyclohepta-1,2,4,6-tetraenes
pp. 1
Dehydrosulfonylation of Vinyl Trifluoromethanesulfonates
pp. 1
Dehydrohalogenation of 1-Halocyclodecenes
pp. 1
Ring Enlargement by Extrusion of Nitrogen from Phenyldiazomethanes
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