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Ene-X Compounds (X=S, Se, Te, N, P)
Alk-1-enyl(halo)phosphines by the Reaction of Tungsten–Phosphinidene Complexes and Chloroalkenes
other
Author(s):
A. C. Gaumont
,
M. Gulea
Publication date
(Online):
2007
Publisher:
Georg Thieme Verlag KG
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UCL: UN SDG 01 No Poverty
Author and book information
Book Chapter
Publication date (Print):
2007
Publication date (Online):
2007
Page
: 1
DOI:
10.1055/sos-SD-033-00825
SO-VID:
796a820b-141f-48e2-b6b4-deac8f94e0cb
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Book chapters
pp. 1
Knoevenagel-Type Reactions
pp. 1
Addition–Elimination of Organoselenium Compounds to Alkenes
pp. 1
Peterson Reactions of α-Silyl Derivatives
pp. 1
Wittig, Horner–Wadsworth–Emmons, and Related Reactions of Selenium Precursors with Carbonyl Compounds
pp. 1
Sulfonylation of Alkynes
pp. 1
Ring Expansion of Cycloprop-2-enylidenephosphines with Azides
pp. 1
Elimination Reactions from Thietanes
pp. 1
Synthesis of Product Subclass 9
pp. 1
Addition/Cyclization of Sulfonamide Anions with Alkynyliodonium Trifluoromethanesulfonates
pp. 1
Alkylation of Alken-1-yl Selenides
pp. 1
Conversion of 2,3-Dihydrothiophenes into 6-Oxo-2-thiabicyclo[3.2.0]heptane-4-carboxylic Acids
pp. 1
Synthesis from α-Sulfinyl Carbanions
pp. 1
Using Azeotropic Removal of Water
pp. 1
1-Phenyl-2,3-dihydro-1-phosphole 1-Oxides by McCormack Reaction of Dichloro(phenyl)phosphine and Buta-1,3-dienes Followed by Hydrolysis
pp. 1
Using Bromotrimethylsilane
pp. 1
[4+2] Cycloadditions
pp. 1
Ring Enlargement of Five-Membered Rings
pp. 1
Cyclization of α-Phosphonovinyl Radicals
pp. 1
Use as a Protecting Group for Alcohols
pp. 1
Protecting Group for Alcohols
pp. 1
From 5-Sulfanylated Pentan-2-ones or 5-Bromopentan-2-ones
pp. 1
Metal-Catalyzed Cross-Coupling Reactions
pp. 1
Cycloaddition Reactions
pp. 1
Hydrophosphorylation of Alkynes
pp. 1
Addition Reactions
pp. 1
Oxidative Fragmentation of Alk-1-enyl Benzyl Sulfoxides
pp. 1
Replacement or Modification of Substituents on the C=C Bond of Alk-1-enyl Tellurides
pp. 1
Metal Alk-1-eneselenolates
pp. 1
Reaction of Ethyl Bromoacetate with Sulfoximides
pp. 1
N,N′-Disubstituted Hydrazines or Trisubstituted Hydrazines
pp. 1
Synthesis by Isomerization and Rearrangement
pp. 1
Condensation of a Ketone or Aldehyde with an Amine
pp. 1
Nitration of Alkenes
pp. 1
1-Methyl-2,3-dihydro-1-phosphole 1-Oxides and Sulfides by Acid- or Base-Catalyzed Isomerization
pp. 1
Electrocyclic Ring Closure of Enethiones
pp. 1
Synthesis from 1-(Arenesulfonyl)-5-iodobut-1-enyl Methyl Sulfides
pp. 1
Synthesis of Product Subclass 1
pp. 1
Isomerization of 2,5-Dihydrothiophenes
pp. 1
With Triarylphosphines
pp. 1
Transition-Metal-Catalyzed Cyclization
pp. 1
Synthesis of Product Subclass 1
pp. 1
Condensation of Amides with Dialdehydes
pp. 1
Enolization/Acylation of Thietan-3-one Derivatives
pp. 1
Alk-1-enylphosphonous Diamides by Reaction between Enamines, Phosphorus Trihalides, and Amines
pp. 1
Reaction of Organotellurenyl Halides and Derivatives with Alk-1-enyl Cuprates or Alk-1-enyl Mercury Derivatives
pp. 1
Solid-Phase Hantzsch Synthesis
pp. 1
Selenosulfonylation of Alkenes Followed by Selenium Oxidation
pp. 1
Phosphite-Mediated Elimination Reactions
pp. 1
Addition of Halogens to Alk-1-enyl Tellurides
pp. 1
Transformation of Alk-1-enylphosphonates into the Corresponding Phosphonic Acids
pp. 1
Alkylation of Cycloalk-1-ene-1-thiolates
pp. 1
Elimination of Trialkylsilanol from Silyl Nitronates
pp. 1
Electrocyclic Ring-Closure Reactions
pp. 1
Modification of Substituents
pp. 1
1,2,3,4-Tetrahydrophosphinines by Cycloaddition of an In Situ Formed Phosphabuta-1,3-diene and Unsaturated Esters
pp. 1
Reductions of Nitroalkenes
pp. 1
Intramolecular Titanocene(II)-Promoted Alkenations of Thioesters
pp. 1
Exchange of Selenolate Ligands in Metal Complexes
pp. 1
Reactions of Sulfenyl Chlorides with Propargylic Alcohols
pp. 1
Synthesis from 1-(Arylsulfonyl)-6-halopent-1-enyl Methyl Sulfides
pp. 1
Cationic Interconversion of 4-Thiopyrans into 2-Thiopyrans
pp. 1
Alkene Cross Metathesis
pp. 1
3-Bromo-1-phenyl-2,3-dihydro-1-phosphole 1-Oxide by Isomerization with Bromination of 1-Phenyl-2,5-dihydro-1-phosphole 1-Oxide
pp. 1
Wittig Reaction of Amides
pp. 1
[2,3]-Sigmatropic Rearrangements of Ylides Obtained from 1-[(Ethoxycarbonyl)methyl]-2-ethynylthiacycloalkanes
pp. 1
From -Ethyl -(4-Oxobutyl) Dithiocarbonates
pp. 1
3-Methylene-2,3-dihydro-1-phosphole 1-Oxides by Thallium Ethoxide Mediated Conversion of 1-Benzyl-3-methyl-1-phospholium Salts
pp. 1
Synthesis from Diphenylthiirene 1,1-Dioxide and 1-Cyclohex-1-enylpyrrolidine
pp. 1
[4+2]-Cycloaddition Reactions of 1-Azabutadienes
pp. 1
Elimination of Nitrous Acid
pp. 1
A 4-(Dichloromethylene)-1,2,3,4-tetrahydrophosphinine 1-Oxide via Hydroboration of the Corresponding 1,4-Dihydrophosphinine 1-Oxide
pp. 1
Tantalum-Mediated Additions to Alkynyl Sulfides
pp. 1
Synthesis from 2-Acetoxy- and 2-(Benzoyloxy)tetrahydrothiophenes
pp. 1
Synthesis of Product Subclass 14
pp. 1
Synthesis of -Acyl-1,2-dihydroazetes
pp. 1
2-Phosphabicyclo[3.1.0]hex-3-ene 2-Sulfides by Cyclopropanation of 1-Phosphole 1-Sulfides with Ethyl Diazoacetate
pp. 1
Synthesis of Product Subclass 4
pp. 1
Hydride Reductions
pp. 1
Substitution and Addition–Elimination Reactions
pp. 1
Synthesis from Imines and Enamines and Electrophilic Sulfur Agents
pp. 1
Conversions of Alkynes into Alkenyl and Allenyl Sulfoxides
pp. 1
Alkylidenation of Carbonyl Groups via Titanium Carbenes
pp. 1
Reaction of Sulfenes and Ynamines or Ketene ,-Acetals
pp. 1
Base-Catalyzed Ring-Opening Reactions of Sulfur-Containing Heterocycles
pp. 1
S-Alkylation Using Methyl Trifluoromethanesulfonate
pp. 1
Synthesis of Product Subclass 15
pp. 1
Aza-Wittig Reactions
pp. 1
Intramolecular Baylis–Hillman Reactions of Organotellurenyl Bromides
pp. 1
Dehydrohalogenation of (2-Haloalkyl)sulfonium Salts
pp. 1
Reactions with Sulfenyl Chlorides
pp. 1
Cyclopropyliminium Ion Rearrangement
pp. 1
1,4-Dihydrophosphinines by Reaction of Dilithiated Penta-1,4-dienes with Dichlorophosphines
pp. 1
Knoevenagel Condensation of Activated Sulfones
pp. 1
Michael Addition
pp. 1
Elimination of Nitrous Acid
pp. 1
Rearrangement of Bicyclic Sulfonium Ylides
pp. 1
Derivatization of Stable Nitrosoalkenes
pp. 1
Isomerization
pp. 1
Synthesis of α,β-Unsaturated Oximes
pp. 1
Addition Reactions to the C=C Bond of Alk-1-enyl Tellurides
pp. 1
Photocycloaddition of Thiones to Alkynes
pp. 1
Reaction of Metal Complexes with 1,2,3-Selenadiazoles
pp. 1
Synthesis of Product Subclass 8
pp. 1
Thermolysis Reactions
pp. 1
Addition of Organotellurenyl Halides and Amides
pp. 1
Synthesis by Ring-Closure Reactions
pp. 1
Alk-1-enylselenonium Salts
pp. 1
Alkenation Reactions
pp. 1
Decarboxylation of 2-(Methylsulfanyl)propanoic Acid
pp. 1
Hydrogenation of Alk-1-ynylphosphonates
pp. 1
A 5-(Diphenylphosphoryl)-2,3-dihydro-1-phosphole 1-Oxide by Isomerization with Substitution of a 2,5-Dihydro-1-phosphole 1-Oxide
pp. 1
Takai Alkylidenation
pp. 1
Addition of Hydrogen Sulfide to Alkynes
pp. 1
1-Chloro-4-methyl-2,3-dihydro-1-phospholes by Reduction of the Phosphorus Trichloride–Isoprene McCormack Cycloadduct
pp. 1
The Heck Reaction
pp. 1
Deoxygenation of Alk-1-enyl Sulfoxides
pp. 1
Oxidation of Oximes and Amines
pp. 1
Hydrophosphinylation of Alkynes
pp. 1
Using Carbon Nucleophiles
pp. 1
Synthesis of Product Subclass 7
pp. 1
Horner–Wittig Reaction of Alkenyl Phosphine Oxides Functionalized with a Phenylsulfanyl Substituent
pp. 1
A 1,2,3,4-Tetrahydrophosphinine 1-Oxide by Cyclization of a Diallylphosphine Oxide with Isomerization
pp. 1
Synthesis from Dihydro- and Tetrahydrothiopyrans
pp. 1
Synthesis by Substituent Modification
pp. 1
Classical Hantzsch Reaction
pp. 1
By the Action of Protic Acid Catalysis
pp. 1
Metal-Catalyzed Phosphorus–Carbon Cross-Coupling Reaction
pp. 1
Ring Opening of Epoxy Sulfides
pp. 1
Alk-1-enyl(amino)phosphines by Vinylation of Halophosphines
pp. 1
Reduction of Phosphorus Compounds
pp. 1
Pyrolyses of Sulfoxides
pp. 1
Direct Borylation of Imines (or Enamines)
pp. 1
Synthesis of Product Subclass 6
pp. 1
Lithiation of 2,3-Dihydrothiophene and Its Reactions with Electrophiles
pp. 1
2-Carbamoylation of 1,4-Dihydropyridines
pp. 1
Synthesis from Phosphamides and Aldehydes
pp. 1
Wittig and Horner–Wittig Reactions
pp. 1
Coupling of Metal Selenides or Metal Alkane- or Areneselenolates with Alk-1-enyl Heteroatom Derivatives and Related Reactions
pp. 1
Imination of Alk-1-enyl Sulfoxides
pp. 1
Reactions with Sulfodiimines
pp. 1
Rhodium-Catalyzed Alkene–Allene Carbocyclization
pp. 1
Dimerization of 2,3-Dihydrothiophene and Its 1,1-Dioxide
pp. 1
Synthesis of Cyclic Alk-1-enyl Sulfides
pp. 1
Heck Reactions of 2,3-Dihydropyrroles
pp. 1
Nickel-Catalyzed Phosphorus–Carbon Cross-Coupling Reactions
pp. 1
Synthesis of Product Subclass 8
pp. 1
Wadsworth–Emmons Alkenation
pp. 1
Synthesis by Transformation of a Cyclic Substrate
pp. 1
Ring-Closing Metathesis of -Alk-3-enylenamines
pp. 1
Photolysis of Pent-4-ynethiol
pp. 1
Ring Opening to Propenethial ,-Dioxides and Subsequent Cycloaddition or Rearrangement
pp. 1
Reduction of Alk-1-enyltellurium Halides
pp. 1
Alkylation/Elimination
pp. 1
Carboxymethylation of Substituted Vinyl Trifluoromethanesulfonates
pp. 1
Mannich-Type Reaction
pp. 1
Addition of Enolates and Enol Ethers
pp. 1
Iodocyclization of Alk-3-ynylsulfonamides
pp. 1
Oxidative Elimination of Sulfanyl or Selanyl Moieties
pp. 1
Synthesis from (Phosphorylalk-1-enyl)copper(I) Compounds
pp. 1
Elimination Reactions from Azetidines
pp. 1
Sulfonylation of Alkenes Followed by Elimination
pp. 1
Applications of Product Subclass 12 in Organic Synthesis
pp. 1
Pummerer Reactions
pp. 1
Using Aldehydes and Tributylarsine
pp. 1
Synthesis of Product Subclass 11
pp. 1
Peterson Alkenation of α-Silylalkyl Sulfones
pp. 1
Elimination Reactions from Pyrrolidines
pp. 1
Hydrogenation of Pyridine, Pyridinium Salts, and Dihydropyridines
pp. 1
Synthesis of Product Subclass 7
pp. 1
Condensations of Sulfinyl Carbanions (and Related Species) with Carbonyl Compounds
pp. 1
Alk-1-enyl Selenoxides
pp. 1
Synthesis of Product Subclass 12
pp. 1
Sulfenylation of Alkenethiolate Anions
pp. 1
Free-Radical Additions of Tellurium Species
pp. 1
Condensation of Sulfonyl Carbanions with Carbonyl Compounds
pp. 1
From Epoxides
pp. 1
Bamford–Stevens Elimination of the Tosylhydrazone of Dihydrothiophen-3(2)-one
pp. 1
Chlorosulfenylation of Alkenes, Followed by Sulfur Oxidation and Elimination
pp. 1
Functionalization of Allyl Sulfones and Derivatives
pp. 1
Synthesis by Elimination Reactions
pp. 1
Synthesis of Product Subclass 18
pp. 1
Synthesis by Substituent Modification
pp. 1
1-Substituted 2,3-Dihydro-1-phosphole 1-Oxides by Cyclization of Benzylphosphine Oxides and α,β-Unsaturated Ketones
pp. 1
Phosphetium Salts of Ring-Fused 1,2-Dihydrophosphetes by Ring Closure of (Arylmethylene)chlorophosphoranes
pp. 1
Reaction of Alkynes with Dialkylsulfoxonium Salts
pp. 1
Synthesis by Double-Bond Rearrangement of Tetrahydrophosphinines
pp. 1
Applications of Product Subclass 5 in Organic Synthesis
pp. 1
Addition to Metal Alk-1-yneselenolates
pp. 1
Alk-1-enyl Tellurides
pp. 1
Addition–Elimination of Organoselenenyl Halides and Related Compounds
pp. 1
Addition to Alk-1-ynyl Selenides
pp. 1
Reaction of 1-(1-Adamantylcarbonylmethyl)pyridinium Bromide with (Arylmethylene)cyanothioacetamides
pp. 1
Syntheses from Alkyl Sulfides
pp. 1
Synthesis from Organometallic Intermediates Generated from Alk-1-ynylphosphine Oxides
pp. 1
Hydroamination
pp. 1
Synthesis from (Borylalk-1-enyl)phosphonates
pp. 1
Synthesis of Product Subclass 9
pp. 1
Synthesis from 1,2-Azaborolium Salts
pp. 1
Intramolecular Cyclization of Sulfines Derived from S-Unsaturated Dithioesters
pp. 1
Michaelis–Arbuzov-Type Reaction
pp. 1
Dehydration of Pyrrolidin-3-ols
pp. 1
S-Oxidation of Isothiazol-3(2)-ones
pp. 1
2,3-Dihydro-1-phosphole 1-Oxides by Base-Catalyzed Rearrangement of 6-Oxa-3-phosphabicyclo[3.1.0]hexanes
pp. 1
Reduction of Chlorophosphines
pp. 1
Addition Reactions
pp. 1
1,2,3,4-Tetrahydrophosphinines via Bromination of the Corresponding 1,2,3,6-Tetrahydrophosphinines
pp. 1
Through Nucleophilic Attack on -Sulfonylimines
pp. 1
Reduction of the Sulfoxide Group
pp. 1
Miscellaneous Methods
pp. 1
Dissolving-Metal Reductions
pp. 1
Elimination from β-Heteroatom-Substituted Alkylphosphonates
pp. 1
Synthesis of Product Subclass 4
pp. 1
Cyclization/Isomerization of δ-Chloroimines
pp. 1
Reaction of 4-Amino-1,2-dihydropyrazol-3-one with Thionyl Chloride
pp. 1
Aza-Diels–Alder Reaction of 1-Azadienes
pp. 1
Through Deprotonation and Quenching of -Sulfanyl- and -Sulfinylimines
pp. 1
Synthesis from Thiophenones
pp. 1
Addition and Elimination of Halogen
pp. 1
Replacement of Lithium by Organostannyl and Organosilyl Groups
pp. 1
Synthesis by Conjugate Addition
pp. 1
Synthesis from But-3-ynethiols and Derivatives
pp. 1
Additions of Sulfenic Acids to Alkynes
pp. 1
Reduction and Suzuki Coupling Reactions of Lactam-Derived Vinyl Phosphates
pp. 1
Addition of Nucleophiles to Alk-1-ynylselenonium Salts
pp. 1
S-Alkylation of Alk-1-enyl Sulfides
pp. 1
Ring-Closing Metathesis of -Alk-3-enyl--alk-1-ynylsulfonamides
pp. 1
A 1-Imino-1,2-dihydro-1λ-phosphet-1-amine by Cycloaddition of an Imino(methylene)phosphorane and an Acetylene
pp. 1
From Isoxazoles
pp. 1
Alkylation of Alk-1-enethiolates
pp. 1
Reactions of Azides with Triarylphosphines and Triorganyl Phosphites
pp. 1
Intramolecular Cyclization of Aminoaldehydes and Derivatives
pp. 1
The Stille and Other Palladium-Catalyzed Cross-Coupling Reactions
pp. 1
Synthesis of Product Subclass 1
pp. 1
[2,3]-Sigmatropic Rearrangements of 1-[(Ethoxycarbonyl)methyl]-2-ethynylthiepane Sulfonium Ylides
pp. 1
Aromatization of 2,3-Dihydrothiophenes
pp. 1
Reaction of Areneselenenyl Halides and Related Compounds with Alk-1-enyllithiums
pp. 1
Reactions of 1-Bromoalkenes with Trialkylstannyl Sulfides
pp. 1
Reaction of Zirconacycles with Sulfur Monochloride
pp. 1
Lithiation of 2,3,4,5-Tetrahydrothiepin 1-Oxide
pp. 1
Reduction of Thiophenes
pp. 1
Reaction of Phosphorus Trihalides and Buta-1,3-dienes Followed by Reaction with Alcohols
pp. 1
Copper-Catalyzed S2′ Substitution of Propargyl Chlorides
pp. 1
Diels–Alder Reactions of Dienyl Sulfones
pp. 1
Retro-Diels–Alder Reactions of 9,10-Ethano-9,10-dihydroanthracene-11-thiols
pp. 1
Synthesis of Product Subclass 7
pp. 1
A 1-Imino-1,2-dihydro-1λ-phosphet-1-amine by Ring Closure of a Phosphabuta-1,3-diene Effected by an Azide
pp. 1
From an -Methylthiirenium Ion
pp. 1
Intramolecular Cyclization of Amino Acetals
pp. 1
Addition of Other Carbon Nucleophiles
pp. 1
[4+2] and [2+2] Cycloadditions of 2-Methylenethietes
pp. 1
Exchange of Groups on Tellurium in Alk-1-enyl-λ-tellanes
pp. 1
Synthesis from Dithioacetals
pp. 1
Synthesis from (Dialkoxyphosphoryl)phosphoniomethanides
pp. 1
Modification of an Existing Double Bond
pp. 1
Modification of the Existing Double Bond in Alk-1-enylphosphonates
pp. 1
Synthesis from Alkynyl Sulfides
pp. 1
Isomerization Reactions
pp. 1
Free-Radical Additions
pp. 1
Double Michael Additions of Malonate Anions to Alk-1-enyl Alk-1-ynyl Sulfones
pp. 1
Synthesis from Cycloalkanones and Dithioacetals or Thiols
pp. 1
1,2-Photoaromatization Reaction of an Azabicyclohexane-Type Diels–Alder Adduct
pp. 1
Substitution of Pentaaryltellurium Trifluoromethanesulfonates
pp. 1
Wadsworth–Emmons–Horner Reactions
pp. 1
Synthesis from Propenethial
pp. 1
Functionalization of Simple Alk-1-enyl Sulfones
pp. 1
P—C Bond Formation from Dialkyl Phosphonates or Trialkyl Phosphites and Vinyl Halides
pp. 1
Ring-Opening Reactions
pp. 1
Synthesis from 3-Methyl-6-sulfanylhexan-2-ones
pp. 1
Reaction of Alkenes with Elemental Sulfur
pp. 1
Transformations of 1-Haloalkenes and Their Analogues
pp. 1
Elimination Reactions of (α-Azidoalkyl)benzotriazoles
pp. 1
[2,3]-Sigmatropic Rearrangement of 1-[(Ethoxycarbonyl)methyl]-2-ethynylthiocane Sulfonium Ylides
pp. 1
Oxidation Reactions
pp. 1
1,2-Elimination Reactions
pp. 1
Cyclic Alk-1-enesulfonic Esters and Sulfonamides by Metathesis Reactions
pp. 1
Intramolecular Cyclization of Carbamates and Aldehydes
pp. 1
Elimination from α-Oxygenated Alkylphosphine Oxides
pp. 1
Enethiolization of Thiocarbonyl Compounds
pp. 1
In Situ Preparation of δ-Chloroimines
pp. 1
Extrusion of Sulfur Dioxide from 3-Sulfanyl-2,5-dihydrothiophene 1,1-Dioxides
pp. 1
Elimination of a Thiol from Bis(dithioacetals)
pp. 1
Photocyclization of Bis(2-phenylvinyl) Sulfide
pp. 1
Nitrosation of Alkenes
pp. 1
Synthesis of Product Subclass 9
pp. 1
Reduction of (1)-But-1-en-3-ynyl Ethyl Sulfides
pp. 1
Cyclization of 2-Cyano--(ethoxycarbonyl)-1-azabutadienes
pp. 1
Synthesis from Amino(chloro)phosphines
pp. 1
Reaction of -Alkenyl(phenyl)-λ-iodanes with Thioamides
pp. 1
Hydroboration of Alkynyl Sulfides
pp. 1
Synthesis of Product Subclass 7
pp. 1
Mannich-Type Reactions
pp. 1
Elimination of a Hydrogen Halide or Ethanol
pp. 1
Synthesis of Product Subclass 6
pp. 1
Synthesis from Other Alkenyl Sulfoxides
pp. 1
Oxidation of the Sulfur Atom
pp. 1
Alk-1-enesulfenyl Chlorides from Allenes and Sulfur Dichloride
pp. 1
Horner–Wittig Reaction of Ketones and Aldehydes
pp. 1
Heating Dialk-1-enyl Disulfides
pp. 1
Synthesis from α-Stannylated Carbanions
pp. 1
Syntheses from Dithioacetals and Trithioorthoformates
pp. 1
Alkenesulfenamides by Addition of Amidosulfenyl Chlorides to Alkynes
pp. 1
Reaction of a Sulfonium Ylide with Diphenylthiirene Dioxide
pp. 1
Synthesis of Product Subclass 2
pp. 1
Cyclization after Isolation of δ-Chloroimines
pp. 1
Aldol-Type Condensations and Related Processes
pp. 1
Of Hydrazines to Alkynes
pp. 1
Synthesis by Double-Bond Rearrangement of 2,5-Dihydro-1-phosphole Derivatives
pp. 1
Stereoselective Addition of Grignard Reagents to Alkynyl Sulfides
pp. 1
Alk-1-enesulfenyl Chlorides from Alkynes and Sulfur Dichloride
pp. 1
Photochemical Reactions between 1-Bromoalk-1-enes and Sulfides
pp. 1
Synthesis by Ring Transformation
pp. 1
Reaction of -Tosylsulfimides with Potassium -Butoxide
pp. 1
Addition of Trialkylammonium Salts to Activated Alkynes
pp. 1
Reductions of Tellurium Compounds
pp. 1
Using Heteroatom Nucleophiles
pp. 1
A Biphosphinin-4(1)-ylidene 1,1′-Dioxide by Photolysis of a 2-Phosphabicyclo[3.1.0]hexane Oxide
pp. 1
A Biphosphinin-4(1)-ylidene 1,1′-Dioxide by Coupling of Two Units of a Phosphinin-4(1)-one 1-Oxide
pp. 1
Substitution of Metals
pp. 1
Condensation of Sulfinyl(sulfonyl)methanes with Aldehydes
pp. 1
Alkali Metal Cleavage of Alk-1-enyl Alkyl Sulfides
pp. 1
Synthesis from Imines
pp. 1
Addition–Elimination Reactions of Phosphoranes
pp. 1
Deprotonation of Thiocarbonyl Compounds
pp. 1
A 1,2,3,4-Tetrahydrophosphinine 1-Oxide by Hydrogenation of a 1,2-Dihydrophosphinine 1-Oxide
pp. 1
Microwave Activation
pp. 1
Synthesis of Product Subclass 10
pp. 1
Reaction of Organotellurenyl Halides with Grignard Reagents
pp. 1
Photochemical Cycloaddition of 3-Aminopropenals and Alkenes
pp. 1
Synthesis from 1,5-Diketones and Hydrogen Sulfide/Hydrogen Chloride, Phosphorus Pentasulfide, or Hexamethyldisilathiane
pp. 1
Synthesis from Zirconacyclic and Titanacyclic Phosphonates
pp. 1
Enolization of Dihydrothiopyranones
pp. 1
Ring Enlargement of Seven-Membered Rings
pp. 1
Reactions with Copper Thiolates
pp. 1
Addition of Tellurium(IV) Halides or Organotellurium Trihalides to Alkynes
pp. 1
Reduction of Alk-1-enylditellanes
pp. 1
Rearrangement and/or Elimination Reactions
pp. 1
Reduction of Alkynyl Sulfides
pp. 1
Elimination Reactions of 2-Methyl-4-sulfanylbut-3-en-2-ols
pp. 1
Synthesis through 1,2-Elimination Reactions of Amines
pp. 1
Addition of β-Dicarbonyl Anions
pp. 1
Substitution of Heteroatoms
pp. 1
Synthesis from Primary and Secondary Sulfonamides
pp. 1
Synthesis from 4,4-Dihalobut-3-enethiols
pp. 1
Addition of Benzenetellurinyl Trifluoromethanesulfonate to Alkynes
pp. 1
Other Variations
pp. 1
Transfer Dehydrogenation
pp. 1
Synthesis of 4-Methylene-2,6-diphenyl-4-thiopyrans
pp. 1
Using Alk-1-enylmercury(II) Halides
pp. 1
Synthesis of Product Subclass 13
pp. 1
Using Alk-1-enyltributylstannanes
pp. 1
Alk-1-enylphosphonous Dihalides by the Reaction of Phosphorus Trihalides and Organometallic Derivatives
pp. 1
Addition of Hydrogen
pp. 1
1,4-Addition Reactions
pp. 1
From Phosphorus Ylides
pp. 1
Other Alkenation Reactions
pp. 1
Reaction of Allenes and Alkynes with Sulfur Dioxide
pp. 1
Synthesis of -Mesyl- and -Nitro-1,2-dihydroazetes
pp. 1
Miscellaneous Syntheses of Alk-1-enesulfonic Acid Derivatives from Other Sulfur Compounds
pp. 1
With Alkynes
pp. 1
A 1,4-Dihydrophosphinine 1-Oxide via the Chlorination of a λ-Phosphinine
pp. 1
Radical Deoxygenation of 3-Azatricyclo[2.2.1.0]heptan-5-ols
pp. 1
Miscellaneous Approaches
pp. 1
Copper- or Lewis Acid Mediated Cleavages of Sulfides
pp. 1
3-Aryl-2,3-dihydro-1-phosphole 1-Oxides by Isomerization with Arylation of 2,5-Dihydro-1-phosphole 1-Oxides
pp. 1
From 3-(Difluoromethylene)-2-methyl-6-phenylhexane-1-thiol
pp. 1
A 1,2,3,4-Tetrahydrophosphinin-4-one 1-Oxide by Hydrolysis of a λ-Phosphinine
pp. 1
By the Action of Calcium Chloride as a Desiccant
pp. 1
Hydrodesulfurization of a Thiolactam-Derived Enol Ether
pp. 1
Functionalization of Boronates
pp. 1
Base-Induced Cyclizations of Alkynyl Benzyl Sulfides
pp. 1
Synthesis of Product Subclass 2
pp. 1
4-Methoxy-1-methyl-2,3-dihydro-1-phosphole 1-Oxide by Isomerization with Chloro Substitution of 3-Chloro-1-methyl-2,5-dihydro-1-phosphole 1-Oxide
pp. 1
Transformations of Thiiranes and Thiirane -Oxides
pp. 1
Synthesis from Hydrazines and Carbonyl Compounds
pp. 1
Synthesis by Substituent Modification
pp. 1
Synthesis of β-Nitroenamines and β-Nitrovinyl Sulfides
pp. 1
Palladium-Catalyzed Phosphorus–Carbon Cross-Coupling Reactions
pp. 1
Synthesis from (Tellanylalk-1-enyl)phosphonates
pp. 1
Reduction with Phosphorus Compounds
pp. 1
Alkylation of Alk-1-enyltelluride Anions
pp. 1
Replacement of Tin by Hydroxyalkyl Groups
pp. 1
Synthesis of Product Subclass 17
pp. 1
Addition of Thiolates to Alkynes
pp. 1
Nucleophilic Addition of Triphenylphosphine to Activated Alkynes
pp. 1
With Alkenes
pp. 1
Monosubstituted or N,N-Disubstituted Hydrazines
pp. 1
Displacement Reactions on Alk-1-enyl Derivatives by Telluride Anions
pp. 1
Reaction of Chlorotropylium Salts with Thiols
pp. 1
Addition of Organotin Reagents
pp. 1
Ring Enlargement of Diazothiiranimines
pp. 1
Synthesis from -Sulfonylimines and Related Compounds
pp. 1
-Halopyridinones and Related Compounds by Direct Halogenation
pp. 1
Synthesis of Product Subclass 5
pp. 1
Nucleophilic Substitutions of 3-Bromo-2,3-dihydrothiophene 1,1-Dioxide
pp. 1
Oxidation of Metal Alk-1-eneselenolates
pp. 1
Metal-Catalyzed Addition of Triphenylphosphine to Alkynes
pp. 1
Intramolecular Condensation of Tosylamines and Acetals
pp. 1
Synthesis of Product Subclass 12
pp. 1
Using Tebbe's Reagent
pp. 1
Acidic Hydrolysis
pp. 1
Functionalization of 1,2,3,4-Tetrahydropyridines
pp. 1
Synthesis from Alkyl Sulfoxides
pp. 1
Addition Reactions to Alkynyl Sulfoxides
pp. 1
S-Oxidation Using Monoperoxyphthalic Acid
pp. 1
Addition Reactions Involving Thiophene 1-Oxides
pp. 1
Combination of Enones and Two Three-Atom Fragments
pp. 1
Synthesis of Acyclic Alk-1-enyl Sulfides
pp. 1
Ring Enlargement of 4,5-Dihydrothiophenium and Thiophenium 1-Methylides
pp. 1
Synthesis of Polyenyl Sulfides
pp. 1
Peterson-Type Alkenation
pp. 1
Synthesis from 1,6-Bis(acylsilanes)
pp. 1
A 1′,4′-Dihydro-2,4′-biphosphinine by Special Reaction of a λ-Phosphinine in the Presence of Lithium 2,2,6,6-Tetramethylpiperidide
pp. 1
A 2,3-Dihydro-1-phosphole 1-Oxide by Dehydration of a 2,3,4,5-Tetrahydro-1-phosphol-2-ol 1-Oxide
pp. 1
Other Approaches Involving Nitriles
pp. 1
Elimination of a Metal Hydroxide
pp. 1
Synthesis of Heterocycles
pp. 1
Elimination Reactions Leading to Thiacyclohept-2-enes, Thiacyclooct-2-enes, and Related Systems
pp. 1
[2+2]-Photochemical Cycloadditions to 2,3-Dihydrothiophene 1,1-Dioxide
pp. 1
Dimerization of 3,4-Dihydro-2-thiopyran
pp. 1
1-Alkoxy-2,3-dihydro-1-phospholes via McCormack Cycloaddition of Phosphorous Acid Derivatives and Buta-1,3-dienes
pp. 1
Synthesis from Other Enethiones
pp. 1
Hydrophosphination under Basic Conditions
pp. 1
Synthesis from Other -Borylenamines
pp. 1
Dehydrogenation
pp. 1
Reaction of Organotellurenyl Halides with Alkynylboranes or Vinylaluminum Compounds
pp. 1
Alk-1-enyl Selenones
pp. 1
Electrocyclic Ring Closure of Thionins
pp. 1
Addition of Thiols or Their Derivatives to Alkynes
pp. 1
Alkylations of Oximes
pp. 1
Halogen–Lithium Exchange from (Halomethyl)phosphonates
pp. 1
Synthesis of Product Subclass 16
pp. 1
Addition of Diselenides
pp. 1
Electrophilic Additions to Thiophene 1,1-Dioxides
pp. 1
Nucleophile-Induced Cyclization of δ-Chloroimines
pp. 1
Chirality on the Nitrogen Atom
pp. 1
Chlorosulfenylation–Dehydrochlorination of Cycloalkenes
pp. 1
Cross-Metathesis Reactions
pp. 1
Applications of Product Subclass 14 in Organic Synthesis
pp. 1
Synthesis from Nitriles
pp. 1
Addition Reactions
pp. 1
Synthesis of Chiral Auxiliaries for Corey–Chaykovsky Epoxidation
pp. 1
Addition of Thiols to Cycloalk-2-enones, Followed by Chlorination–Dehydrochlorination of the Adducts
pp. 1
Dihydrodiol Formation or Oxidation/Dimerization
pp. 1
Aldol-Type Condensations and Dehydrations
pp. 1
Removal of Methanol from Aryl 4,4-Dimethoxybut-2-enyl Sulfides
pp. 1
Rearrangement of a 3,6,7-Triazatricyclo[3.2.1.0]octane Derivative
pp. 1
Aldol-Type Condensations of α-Sulfonimidoyl Carbanions and the Dehydration of the Intermediate β-Hydroxylated Sulfoximides
pp. 1
Reactions of Nitriles with Triarylphosphines
pp. 1
Ring-Fused 1,2-Dihydrophosphetes by Cycloaddition of 1,2-Thiaphospholes and Ynamines
pp. 1
Sulfinylation with Other Enantiopure Sulfinylating Reagents
pp. 1
Synthesis by Selective Saturation
pp. 1
Asymmetric Addition of Nucleophiles to Pyridinium Salts
pp. 1
Sulfonomercuration of Alkenes Followed by Demercuration
pp. 1
Addition–Elimination Reactions of Nitroalkenes
pp. 1
Other Approaches Involving Imines
pp. 1
Reactions with Sulfoximides
pp. 1
Of Sulfonates
pp. 1
Reaction of a Perfluorinated Alkene and -Butanethiol
pp. 1
From (1,2-Epoxyalkyl)phosphine Oxides
pp. 1
Synthesis from Alkenes
pp. 1
Addition Reactions to 2,3-Dihydropyridinium Salts
pp. 1
Annulated 2,3-Dihydro-1-phospholes by Isomerization with Substitution of 2,5-Dihydro-1-phospholes Followed by Ring Closure
pp. 1
Hydrogenation of 2-Methylenethietes
pp. 1
By the Action of Molecular Sieves as Catalysts and Desiccants
pp. 1
Synthesis by the Elimination Reactions of Thiolanes
pp. 1
Synthesis from Imines or Enamines and Phosphorus Electrophiles
pp. 1
Using Dialkyltitanocenes
pp. 1
Ring Enlargement of Six-Membered Rings
pp. 1
Nickel-Catalyzed Replacement of a Vinylic C—S Bond with a C—C Bond
pp. 1
Suzuki Reactions of Vinyl Trifluoromethanesulfonates
pp. 1
Synthesis of Product Subclass 4
pp. 1
Addition of Alcohols, Thiols, and Amines
pp. 1
Ring Enlargement of Thiirenes
pp. 1
[2+2] Cycloaddition between an Imine and a Ketene Aminal
pp. 1
Ring-Closing Metathesis of Ene-Enamides
pp. 1
Synthesis from λ-Phosphinines and λ-Phosphinines
pp. 1
Addition of Selenium Compounds to Allenes
pp. 1
Base-Catalyzed Isomerization of 2,5-Dihydrothiophene 1,1-Dioxides
pp. 1
Nucleophilic Additions to Thiophene 1-Oxides or 1,1-Dioxides
pp. 1
Synthesis by Ring Transformation
pp. 1
Synthesis of Product Subclass 3
pp. 1
Sulfilimine Formation
pp. 1
Thermal Rearrangement of Prop-2-ynyl Vinyl Sulfide
pp. 1
Photoisomerism of 2,3-Dihydrothiophenes to 2-Alkylidenetetrahydrothiophenes
pp. 1
Synthesis of Thiopyrylium Salts
pp. 1
Modifications of Existing Alk-1-enyl Tellurium Species
pp. 1
Cross-Coupling Reactions
pp. 1
Elimination Reactions of 2-Hydroxyazepanes and Derivatives
pp. 1
Synthesis of Product Subclass 14
pp. 1
Samarium(II) Iodide Mediated Double Electrophilic Reduction
pp. 1
Elimination of a Phenylselanyl Group
pp. 1
Alkenylation of Tertiary Phosphines
pp. 1
Condensation of Ammonia with 1,5-Diketones
pp. 1
Alkylation of Enamines
pp. 1
Synthesis from Amino(chloro)phosphines Generated In Situ
pp. 1
Applications of Product Subclass 2 in Organic Synthesis
pp. 1
Synthesis by Double-Bond Rearrangement of Phosphole Derivatives
pp. 1
Alk-1-enesulfenyl Chlorides by Chlorination of Enethiols or Alk-1-enyl Sulfides
pp. 1
Reaction of Haloalkenes with Hydrogen Sulfide
pp. 1
Synthesis by Ring-Closure Reactions
pp. 1
Addition of Tellurols and Metal Tellurides
pp. 1
Functionalization of Simple -Alk-1-enyl- and -Alk-2-enylsulfoximides
pp. 1
Elimination of a Methanesulfonate Group
pp. 1
Addition of Organocopper and Organocuprate Reagents
pp. 1
Synthesis from ω-Halothioacylsilanes
pp. 1
Pyrolysis of 1,2-Ethanedithiol or Thiirane
pp. 1
Alk-1-enesulfenamides from Alk-1-enesulfenate Anions
pp. 1
Synthesis of a 2-Methylene-1,2-dihydrophosphete via a Zirconium-Containing Tricyclic 1,2-Dihydrophosphete
pp. 1
Metal-Catalyzed Addition of Thiols and Their Borabicyclo Derivatives to Alkynes
pp. 1
Addition Reactions
pp. 1
Reduction of Unsaturated Lactams
pp. 1
Diels–Alder Additions
pp. 1
Wittig and Related Reactions
pp. 1
Synthesis from Propenethial ,-Dioxide
pp. 1
Nitration of Vinylsilanes or Vinylstannanes
pp. 1
Using Bis-aminals and α-Haloacetic Acids
pp. 1
Three-Component Hantzsch Synthesis
pp. 1
Electrocyclic Ring Closure of (3,5)-1,1,1,7,7,7-Hexafluoro-3,4,5-tris(trifluoromethyl)hepta-3,5-diene-2-thione
pp. 1
Using Base or Hexacarbonylchromium Catalysis
pp. 1
Reduction of Lactams Followed by Elimination
pp. 1
Ylide Formation
pp. 1
Addition of Amines to Hexafluoropropene Trimers
pp. 1
Other Methods
pp. 1
Synthesis of Product Subclass 10
pp. 1
Iodotrimethylsilane-Induced Elimination–Deoxygenation of Sulfoxides
pp. 1
Palladium-Catalyzed Reactions with Thiolanes and Their Equivalents
pp. 1
Flash-Vacuum Pyrolysis of Sulfur-Containing Cyclic Derivatives
pp. 1
Coupling Reactions of Vinyl Phosphates
pp. 1
Synthesis from Benzothietes
pp. 1
Dehydration
pp. 1
Reactions of β-Alkoxy Michael Acceptors with Triphenylphosphine Imide
pp. 1
Double Bond Shift of Allyl Selenides and Related Reactions
pp. 1
Cyclization of -Allyl α-Phosphonovinyl Radicals
pp. 1
Of Hydrazines to β-Substituted Alkenes
pp. 1
Dithionite Reductions
pp. 1
Addition of Malonate Derivatives to Azetes
pp. 1
With Triorganyl Phosphites
pp. 1
Pummerer-Type Rearrangement of α-Chloroalkyl Sulfoxides
pp. 1
Dehydrochlorination of Cyclic Sulfides
pp. 1
Synthesis of Product Subclass 5
pp. 1
Synthesis of Product Subclass 2
pp. 1
Replacement of Lithium by Alkyl and Hydroxyalkyl Groups
pp. 1
Base-Induced Conversions of 2-Thiopyrans into 4-Thiopyrans
pp. 1
Platinium-Mediated Cycloisomerization of Ene-Ynamides
pp. 1
Isomerization Reactions
pp. 1
Addition–Elimination of Selenols
pp. 1
Synthesis of Product Subclass 2
pp. 1
Synthesis from 5-Substituted Pentan-2-ones
pp. 1
Of Bromides
pp. 1
Addition of Amines to a Perfluoroenone
pp. 1
4,5-Dihydro-2-thienyl 2-Trifluoromethanesulfonate by Enolization of Thiophen-2(3)-one
pp. 1
Functionalization of Alk-1-ynyl Sulfones
pp. 1
Synthesis from 1,4-Dien-3-ones and 1-En-4-yn-3-ones by Michael Addition
pp. 1
Oxidation of Alk-1-enylphosphines
pp. 1
Elimination of HX from β-Nitro Halides
pp. 1
Alk-1-enyltelluronium Salts
pp. 1
Synthesis of Product Subclass 6
pp. 1
Synthesis from -Allylphosphoric Triamides
pp. 1
Ring-Opening Reactions of Thiaoxabicyclo[3.2.1]octanes and Thiaoxabicyclo[3.3.1]nonanes
pp. 1
Condensation of Arylaldehydes with α-Azido-Esters
pp. 1
Synthesis of Product Subclass 3
pp. 1
Oxidation of Alk-1-enyl Metal Tellurides
pp. 1
Peterson and Wadsworth–Emmons Alkenation Reactions
pp. 1
Intramolecular Michael Additions
pp. 1
Stereoselective Reduction of Ketene Dithioacetals
pp. 1
Synthesis from Sulfonium Ylides Stabilized by a Phosphoryl Substituent
pp. 1
Reaction of an Areneselenenyl Halide with Vinylboronic Acids and Esters
pp. 1
Reaction of a Dichlorophosphite and a Buta-1,3-diene
pp. 1
Light-Induced Ring Contraction of 1,2-Dithiins
pp. 1
Sulfinylation with Menthyl 4-Toluenesulfinate
pp. 1
Alk-1-enesulfenic Acids by the Enethiolization of Sulfines
pp. 1
Alkenylation Reactions
pp. 1
Oxidation of Alk-1-enyl Tellurides
pp. 1
Dissolving Metal Reduction of Aromatic Amines
pp. 1
Allylic Bromination of 4,5-Dihydrothiepin 1,1-Dioxide
pp. 1
Heck Reaction
pp. 1
Birch Reduction
pp. 1
Applications of Product Subclass 4 in Organic Synthesis
pp. 1
Enethiolization of ω-Halothioacylsilanes
pp. 1
Cyclization of -Phenyl-2-cyano-1-azabutadienes
pp. 1
From Halocyclizations
pp. 1
Elimination Reactions of Aryl 2-Chlorobut-3-enyl Sulfides
pp. 1
Metal-Catalyzed Hydrophosphorylation
pp. 1
Synthesis from (1-Silylalkyl)phosphonates
pp. 1
Ring-Closing Metathesis of Ene-Ynamides
pp. 1
Reduction of Phosphonates and Phosphinates
pp. 1
Coupling Reactions of Lactam-Derived Alkenyl Trifluoromethanesulfonates
pp. 1
Reduction of Alk-1-enyl Telluroxides
pp. 1
Cyclization Involving a Halogen Leaving Group
pp. 1
Skeletal Rearrangement Reactions
pp. 1
Synthesis of Product Subclass 5
pp. 1
Ring Contraction of Thiophene 1,1-Dioxides
pp. 1
Elimination of Sulfuric Acid
pp. 1
Metal-Catalyzed Hydrophosphination
pp. 1
Oxidative Amination
pp. 1
Dehydrohalogenation
pp. 1
Addition of Arene- or Alkaneselenenyl Halides, Selenosulfonates, and Related Compounds
pp. 1
Wittig-Type Reaction
pp. 1
Syntheses via Organophosphorus Reagents
pp. 1
Addition of Iron–Telluride Complexes
pp. 1
α-Functionalization
pp. 1
Double-Bond Isomerization
pp. 1
Alkylidenation of Amides with Thioacetals Using a Titanium(II) Complex
pp. 1
Synthesis of Product Subclass 6
pp. 1
Using an Aldehyde and a Base–Titanium(IV) Chloride System
pp. 1
Nitration of α,β-Unsaturated Carboxylic Acids
pp. 1
Formal Exchange of Ring Members with Retention of Ring Size
pp. 1
Reaction of Divinyl Diselenides with Tributyltin Hydride
pp. 1
Synthesis of Product Subclass 8
pp. 1
Cope and Hofmann Eliminations
pp. 1
Addition of Organometallic Compounds
pp. 1
Synthesis of Product Subclass 5
pp. 1
Elimination–Addition from Vinylidene Bisphosphonium Salts
pp. 1
1,3-Dipolar Cycloaddition of Mesoionic Thiazolium-4-olates to Nitroalkenes
pp. 1
A 2-Phosphabicyclo[3.1.0]hex-3-ene 2-Oxide by Intramolecular Cyclopropanation of a 1-(Iodomethyl)phospholium Salt
pp. 1
Nucleophilic Attack on Nitriles
pp. 1
Palladium-Catalyzed Cyclization of α-Propargyl α-Amino Esters
pp. 1
Synthesis by Ring-Closure Reactions
pp. 1
Hydrophosphination of Alkynes with Primary or Secondary Phosphines
pp. 1
Addition of Nucleophiles to Sulfines
pp. 1
Nucleophilic Substitution by Thiolate Anions and Their Analogues
pp. 1
C—S Bond Cleavage of Alkenyl Sulfides
pp. 1
Synthesis from Alkylphosphonochloridoates and Vinylic Organometallic Compounds
pp. 1
Modification of Phosphoranes or Phosphonium Salts
pp. 1
From 4,4-Dibromo-3-methylbut-3-ene-1-thiol
pp. 1
Nitrosation of Alkynes
pp. 1
1,4-Dihydrophosphinine 1-Oxides by Isomerization of λ-Phosphinines
pp. 1
1,2-Dihydrophosphetes by Titanium–Phosphorus Exchange of a Titanacyclobutene
pp. 1
Two-Carbon-Atom Ring Expansion with Dimethyl Acetylenedicarboxylate
pp. 1
Via Benzotriazole Aminals
pp. 1
Oxidation of Alk-1-enyl Selenides
pp. 1
Applications of Product Subclass 13 in Organic Synthesis
pp. 1
Alk-1-enyl Polyselenides
pp. 1
Intramolecular Trapping Reactions of Enethiols Functionalized by a Silyl Group
pp. 1
Substitution of Hydrogen
pp. 1
Condensation of Amines with Dialdehydes
pp. 1
Sulfinylation of Nucleophilic Alkenyl Reagents
pp. 1
Condensation of Sulfonimidoyl Carbanions with Carbonyl Compounds
pp. 1
Hydroaminomethylation
pp. 1
Addition of Grignard Reagents
pp. 1
Miscellaneous Procedures
pp. 1
Base-Catalyzed Hydrophosphorylation
pp. 1
Isomerizing Heck Reactions of 2,5-Dihydropyrroles
pp. 1
Radical-Catalyzed Hydrophosphination
pp. 1
Synthesis through Cross-Coupling Reactions
pp. 1
Reaction of 6-Acyl-3,6-dihydro-2-thiopyrans with Zinc/Chlorotrimethylsilane
pp. 1
Synthesis of a 1,2-Dihydro-2-benzothiepin by Cathodic Reduction of a Benzyl Dithiopivaloate
pp. 1
Reaction of β-Alkoxy Michael Acceptors with Sulfoximides and Sulfodiimines
pp. 1
Elimination from β-Heteroatom-Substituted Alkylphosphinic Esters
pp. 1
Elimination Reactions of β-Substituted Nitro Compounds
pp. 1
Metal–Tellurium Exchange
pp. 1
Alk-1-eneselenols
pp. 1
Addition of Selenium Compounds to Alkynes
pp. 1
Elimination from β-Heteroatom-Substituted Alkylphosphine Oxides
pp. 1
Wadsworth–Emmons Alkenation Reactions
pp. 1
Addition of Sulfenyl Halides or Sulfenamides to Alkynes
pp. 1
Addition of Tellurium Compounds to Alkynes or Allenes
pp. 1
Horner–Wadsworth–Emmons Alkenation of α-Sulfonyl Phosphonates
pp. 1
Synthesis of Product Subclass 3
pp. 1
Synthesis of Product Subclass 1
pp. 1
Elimination of Hydrogen
pp. 1
1,4-Addition of Nucleophiles to Alk-1-ynylphosphonates
pp. 1
Elimination Reactions
pp. 1
Elimination from α-Nitro Selenoxides and β-Nitro Selenoxides
pp. 1
Coupling Reactions of Lactam-Derived Vinyl Trifluoromethanesulfonates
pp. 1
Deprotonation of Methylenebis(phosphonates)
pp. 1
Sulfanylbuta-1,3-dienes via Elimination Reactions
pp. 1
Synthesis of Product Subclass 15
pp. 1
Additions to Alkynyl Tellurides
pp. 1
Synthesis from α-Nitro Ketones
pp. 1
A 4-Methylene-1,4-dihydrophosphinine 1-Oxide by a Lewis Acid Catalyzed Rearrangement of a 4-Methyl-λ-phosphinine
pp. 1
Halogenation of Enamides
pp. 1
Acidic Hydrolysis of -Alk-1-enylphosphinous Amides
pp. 1
Dehydrohalogenation of Haloalkyl Sulfides
pp. 1
Substitution of Hydrogen or Metals
pp. 1
Asymmetric Two-Component Hantzsch Reaction
pp. 1
Addition/Cyclization of Nitrogen Nucleophiles to Dicarbonyl Compounds
pp. 1
Oxidation of Alk-1-enyl Sulfides and Sulfoxides
pp. 1
Manganese(IV) Oxide Promoted Reactions of Sulfides with Acetyl Chloride
pp. 1
Wittig–Horner-Type Alkenation
pp. 1
Alkylation of Alk-1-enyl Tellurides
pp. 1
Alk-1-enyl-λ-tellanes
pp. 1
Addition of Selenols
pp. 1
Alk-1-enyl Telluroxides
pp. 1
4-Methylene-1,4-dihydrophosphinine 1-Oxides via Enolization of a λ-Phosphinine-4-carbaldehyde
pp. 1
Substitution of a Trifluoromethylsulfonyloxy Group by a Metal
pp. 1
Nitrosation Reactions
pp. 1
Oxidation of Alkenyl Sulfides
pp. 1
Ring Enlargement of Three-Membered Rings
pp. 1
A 3-Substituted 2,3-Dihydro-1-phosphole 1-Oxide by Reaction of a 6-Oxa-3-phosphabicyclo[3.1.0]hexane with a Malonic Ester Derivative
pp. 1
Electrochemical Reduction
pp. 1
Reaction of 1,2-Bis[()-2-lithiovinyl]benzene Derivatives and [(1,3)-1-Lithio-4-(2-lithiophenyl)buta-1,3-dienyl](trimethyl)silane with Tellurium Tetrachloride
pp. 1
Cope Rearrangement of Thiocarbonyl Compounds
pp. 1
By the Action of Titanium(IV) Chloride as a Promoter
pp. 1
Iodosulfonylation of Alkenes Followed by Dehydroiodination
pp. 1
From Trithioorthoformates
pp. 1
Coupling of Organoselenenyl Halides or Diorgano Diselenides with Alk-1-enyl Heteroatom Derivatives
pp. 1
Intramolecular Cyclization of an Amide and an Aldehyde or Acetal
pp. 1
Reactions of Heterocycles Bearing β-Acceptor-Substituted Enamine Moieties with Triarylphosphines
pp. 1
Elimination of a Hydrogen Halide or Water
pp. 1
2-Phosphabicyclo[3.1.0]hex-3-ene 2-Oxides by Cyclopropanation of 1-Phospholes with Diazomethane
pp. 1
Synthesis of Product Subclass 19
pp. 1
Addition of Thiols to But-1-en-3-ynes
pp. 1
Intramolecular Wittig Reactions of Thioesters
pp. 1
Aldol-Type Condensation and Dehydration
pp. 1
Hydride Reduction of Pyridines and Dihydropyridines
pp. 1
Elimination Reactions
pp. 1
Synthesis by Ring-Closure Reactions
pp. 1
Reactions with Nucleophiles
pp. 1
3-Methylene-2,3-dihydro-1-phosphole Sulfides by Isomerization of 3-Methyl-1-phosphole 1-Sulfides
pp. 1
Displacement of Stannanes, Boronic Acids, and Iodophenyl Groups
pp. 1
Using (Trimethylsiloxy)alkenes
pp. 1
3,4-Dihydro-2-thiopyrans from 2,3-Dihydrothiophenium Methylides
pp. 1
Nitrosation of Allenes
pp. 1
Reaction of Organotellurenyl Halides with Alk-1-enyl Zirconocenes
pp. 1
Peterson Alkenation
pp. 1
Reaction of Areneselenenyl Halides and Related Compounds with Alk-1-enylzirconocenes
pp. 1
Addition of Organometallic Reagents to Nitriles
pp. 1
Nucleophilic 1,4-Addition to Alk-1-ynylphosphine Oxides
pp. 1
Synthesis from 2-Chloroalkanesulfonic Acid Derivatives
pp. 1
Lithiation of 3,4-Dihydro-2-thiopyrans, 2-Thiopyrans, and 4-Thiopyrans
pp. 1
Coupling of Organotellurenyl Halides or Diorganoditellanes with Alk-1-enyl Anions or Radical Equivalents
pp. 1
Functionalization of Alkenyl Sulfoxides and Derivatives
pp. 1
Reaction of Benzyne with Thiiranes
pp. 1
Addition to Alk-1-ynylselenium Compounds
pp. 1
Metal-Catalyzed Reaction of Dialkyl Phosphonates and Vinyl Halides
pp. 1
Pummerer Reaction of Cyclic Sulfoxides
pp. 1
Alk-1-enyl Selenides
pp. 1
Photochemical Conversion of a 2-Thiopyran into a 4-Thiopyran
pp. 1
Of Chlorides
pp. 1
Knoevenagel-Type Condensations
pp. 1
6π-Electrocyclization of 1-Azatrienes
pp. 1
Reduction of Enamides
pp. 1
Elimination from β-Nitro Sulfides and Sulfoxides
pp. 1
Synthesis from Bis-silylated Methylphosphonates
pp. 1
Addition of Other Compounds Containing a Selenium—Heteroatom Bond
pp. 1
Elimination of Acids from β-Nitro Esters
pp. 1
Miscellaneous Methods
pp. 1
Synthesis from Alkylphosphonates by In Situ Silylation
pp. 1
Synthesis from a 5,5-Dibromopent-4-enethiol or a 5,5-Dibromopent-4-enyl Sulfide
pp. 1
Synthesis of Product Subclass 13
pp. 1
Thermal Hydrophosphination
pp. 1
A 1,2-Dihydrophosphete 1-Oxide by Ring Contraction of a 2,3-Dihydro-1,2-thiaphosphole Using Ethanol
pp. 1
Synthesis from Hydroxylamines and Aldehydes or Ketones
pp. 1
1-Phenyl-2,3-dihydro-1-phospholes by Intramolecular Cyclization of But-3-enylchloro(phenyl)phosphines
pp. 1
Synthesis of Fused 2,3-Dihydro-1-phospholes by Cyclopropanation of 1-Phospholes
pp. 1
Reaction of Organoselenenyl Halides with Alk-1-enylmagnesium Halides
pp. 1
Dialk-1-enylditellanes
pp. 1
Ring Enlargement of Acyldihydrothiophenes
pp. 1
Synthesis from Organometallic Intermediates Generated from Alk-1-ynylphosphonates
pp. 1
Palladium-Induced Intramolecular Cyclization of an ω-Alkenic Tosylamide
pp. 1
Catalytic Asymmetric Reissert Reaction
pp. 1
Synthesis by Substituent Modification
pp. 1
Cyclopalladation of Benzyl Methyl Sulfide
pp. 1
Substitution of β-Functionalized Alk-1-enyl Sulfones
pp. 1
Synthesis of Product Subclass 20
pp. 1
By the Action of Boron Trifluoride–Diethyl Ether Complex as a Catalyst
pp. 1
From (1-Hydroxyalkyl)phosphine Oxides
pp. 1
Reaction between Halophosphines and Vinylic Organometallic Derivatives
pp. 1
Aldol Condensations of Sulfides Bearing an Electron-Withdrawing α-Substituent
pp. 1
Dehydration of β-Nitro Alcohols
pp. 1
Addition to Chiral Nicotinic Acid Derivatives
pp. 1
Synthesis of Product Subclass 11
pp. 1
Cyclization of -Acyl-2-cyano-1-azabutadienes
pp. 1
Synthesis of Product Subclass 3
pp. 1
Synthesis by Ring Transformation
pp. 1
Photolysis Reactions
pp. 1
Dehydrohalogenation of α-Halooximes
pp. 1
Synthesis from 2- or 3-Hydroxy-, 3-Bromo-, or 2-(Alkylsulfanyl)tetrahydrothiophenes
pp. 1
Alk-1-enyl(halo)phosphines by the Reaction of Tungsten–Phosphinidene Complexes and Chloroalkenes
pp. 1
Conjugate Addition/Elimination
pp. 1
Addition of Organocopper Reagents to Alkynyl Sulfides
pp. 1
Direct Silylation of Imines or Enamines
pp. 1
Sulfonylation of Nucleophilic Alkenyl Reagents
pp. 1
1,4-Dihydrophosphinines by Reaction of 1,4-Diynes with Arylphosphines
pp. 1
Addition of Metal Complexes Containing Selenium Ligands to Alkynes
pp. 1
Applications of Product Subclass 3 in Organic Synthesis
pp. 1
Substitution of Halogens
pp. 1
Condensations of the Carbanions of Sulfonic Acid Derivatives with Carbonyl Compounds
pp. 1
Reduction/Elimination of a Lactam
pp. 1
Intramolecular Cyclization of Enamino Esters, Ketones, or Sulfones
pp. 1
Reduction of Alkynyl Tellurides
pp. 1
Conjugate Addition Reactions of Hydroxylamines
pp. 1
Synthesis of Product Subclass 10
pp. 1
Hydrolysis of Alk-1-enyl Thiolacetates
pp. 1
Reaction of Areneselenenyl Halides with Alk-1-enyl(trialkyl)stannanes and Related Reactions
pp. 1
Metal-Catalyzed Phosphorus–Carbon Cross-Coupling Reactions
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