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Acetals: Hal/X and O/O, S, Se, Te
Oxidation of Chloroalkenes
other
Author(s):
T. Benneche
Publication date
(Online):
2007
Publisher:
Georg Thieme Verlag KG
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Book Chapter
Publication date (Print):
2007
Publication date (Online):
2007
Page
: 1
DOI:
10.1055/sos-SD-029-00166
SO-VID:
81aa6fbf-f6a1-4ad3-a349-1995138beb9e
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Book chapters
pp. 1
Fluorination of Lithium, Sodium, or Potassium Salts
pp. 1
By Exchange of Both Alkoxy Groups
pp. 1
Applications of Product Subclass 6 in Organic Synthesis
pp. 1
From Monoprotected 1,3-Diols
pp. 1
Addition of Nonstabilized Carbanions to Weinreb Amides
pp. 1
Oxidation of Glycosylsulfenamides
pp. 1
Deprotection Reactions
pp. 1
Applications of Product Subclass 5 in Organic Synthesis
pp. 1
Elimination Reactions from Selanyl Acetals
pp. 1
α-Halo Selenides by Seleno-Pummerer Rearrangements
pp. 1
By Fluorodesulfurization of Thioketones
pp. 1
Desulfonylation of Aryloxymethanesulfonyl Chlorides
pp. 1
Fluorination at the α-Carbon of Imines and Nitriles and at the β-Carbon of Enamines
pp. 1
Cl/I Acetals
pp. 1
Reactions of Free Pyranoses
pp. 1
Addition of Alcohols to Nitroalkenes
pp. 1
With Alkylating Agents
pp. 1
Synthesis from Haloalkanes
pp. 1
Synthesis of Product Subclass 5
pp. 1
Iodomethyl Sulfoxides from Chloromethyl Sulfoxides by the Finkelstein Reaction
pp. 1
From Enol Ethers with Acetals
pp. 1
Synthesis from Enol Derivatives
pp. 1
Ring Expansion
pp. 1
Reactions of 1,3-Dioxolanes
pp. 1
Bromination of Aldehydes or Ketones
pp. 1
Synthesis from 1,2-Epoxides
pp. 1
Synthesis from Aldehydes or Ketones and Alcohols
pp. 1
Formation of Carbonyl Ylides
pp. 1
Synthesis Using Acetals Derived from Lactones
pp. 1
Applications of Product Subclass 7 in Organic Synthesis
pp. 1
Oxidative Halogenation of Oximes
pp. 1
Reaction of 1,1-Dihalo Compounds with 1,2-Diols
pp. 1
Synthesis from α-Chlorooxiranes
pp. 1
From Enolates or Enol Esters and Alcohols
pp. 1
OR/SeR Acetals
pp. 1
Glycosyl Bromides
pp. 1
Synthesis of Product Subclass 9
pp. 1
Reactions with Carboxylic Acids
pp. 1
Formation of the Sulfur—Halogen Bond by Substitution of Carbon
pp. 1
1--Acetyl Glycosides
pp. 1
Halogenation of Nitroalkenes
pp. 1
Metathesis Processes
pp. 1
Sulfone Alkylation
pp. 1
Sulfone–Lactone Coupling Reactions
pp. 1
1-Halogenation of 1--Acetyl Glycosides
pp. 1
Synthesis from Alkylidenecarbene Complexes
pp. 1
From Monoprotected 1,2-Diols
pp. 1
-(α-Haloalkyl)sulfoximides by the Halogenation of Sulfoximides
pp. 1
Synthesis of Product Subclass 4
pp. 1
From Acyclic Enol Ethers and Alcohols
pp. 1
Substitutions in which the Pent-4-enyloxy Unit Acts as a Leaving Group
pp. 1
Conversion of Methyl Glycosides into Glycosyl Halides
pp. 1
Hydrolysis of 1--Acetyl Glycosides
pp. 1
Chiral 1,3-Dioxolan-4-ones in Asymmetric Synthesis
pp. 1
1--Pent-4-enyl Glycosides
pp. 1
Glycosylsulfenamides
pp. 1
From β-Oxo Nitriles and Related Compounds
pp. 1
Using Xenon Difluoride
pp. 1
Nucleophilic Substitution Reactions of Halogenated O/O Acetals with a Cobalt-Centered Anion
pp. 1
From Titanium or Antimony Alkoxides
pp. 1
Synthesis of Product Subclass 3
pp. 1
OR/SR Acetals
pp. 1
Halogenation of S/N Acetals
pp. 1
Synthesis by Ligand Exchange
pp. 1
Electrophilic Halogenation
pp. 1
Formation of α-Silyl, α-Germyl, α-Stannyl, and α-Plumbyl Ethers
pp. 1
Formation of α-Alkoxy Sulfur Compounds
pp. 1
Applications of Product Subclass 9 in Organic Synthesis
pp. 1
Substitution of Thiosulfonates
pp. 1
Halogenation of Alkanes
pp. 1
From But-2-ene-1,4-diols and Ketones
pp. 1
Miscellaneous Reactions
pp. 1
Synthesis from CH-Acidic Compounds
pp. 1
From 1,1-Bis(trifluoromethylsulfonyloxy) Compounds
pp. 1
OR/SOR Acetals
pp. 1
Reactions of Glycosyl Esters or Thioesters in the Presence of Lewis Acids
pp. 1
Fluorination
pp. 1
From Substitution at the 4-Position of 1,3-Dioxanes
pp. 1
Reactions at the Double Bond of 1--Pent-4-enyl Glycosides
pp. 1
From Dialkoxytriphenylphosphoranes
pp. 1
Halogenation of Nitroalkanes
pp. 1
Samarium(II) Iodide Based Reactions
pp. 1
I/I Acetals
pp. 1
Reactions with Aryl Fluorides
pp. 1
Synthesis of Product Subclass 1
pp. 1
α-Dichlorination of Imines
pp. 1
Using Stabilized Carbanions
pp. 1
α-Dichlorination of Aldehydes
pp. 1
From 1,1-Difluoroalkenes
pp. 1
By Fluorination of Alkenylboron Derivatives and Alkenylsilanes
pp. 1
Conversion into Monofunctionalized 1,2-Diols
pp. 1
Synthesis from Hemiacetals
pp. 1
Isomerization of 1--Allyl Glycosides
pp. 1
Formation of α-Alkoxy Radicals
pp. 1
Using -Chlorosuccinimide and Chlorotrimethylsilane
pp. 1
Reactions of 1-Hydroxy Pyranoses with Trichloroacetonitrile
pp. 1
Synthesis Using Hemiacetals Derived from Oxidation of Furans
pp. 1
Addition of Nucleophilic Phosphorus to 1,1-Dihaloalkanes
pp. 1
Synthesis from Cyclic Vinyl Ethers
pp. 1
Synthesis of Product Subclass 7
pp. 1
F/I Acetals
pp. 1
Synthesis from Heterosubstituted Alkanes
pp. 1
-Glycosyl/Alkyl Glycosylthiosulfinates and -Glycosyl Alkane-/Arene-/Glycosylthiosulfonates
pp. 1
Applications of Product Subclass 2 in Organic Synthesis
pp. 1
Protecting Group Chemistry
pp. 1
Cleavage of O/S(O) Acetals with Acetyl Chloride or Thionyl Chloride
pp. 1
Synthesis of Product Subclass 11
pp. 1
Halogenation of Phosphonium Ylides
pp. 1
Deprotection Reactions
pp. 1
Addition of Halophosphorus(III) Derivatives to Carbonyl Compounds
pp. 1
F/F Acetals
pp. 1
Synthesis of Product Subclass 6
pp. 1
Reaction of Lithiated Geminal Dibromoalkanes with Aldehydes
pp. 1
4,5-Dihydroglycopyranoso[2,1-]-1,3-thiazoles
pp. 1
α-Halophosphorus(III) Compounds
pp. 1
By Reaction with Organometallic Compounds
pp. 1
OR/ON Acetals: Open-Chain Compounds
pp. 1
Transition-Metal-Based Reactions
pp. 1
Hetero-Diels–Alder Reactions of Alka-1,3-dienyl Ethers with Carbonyl Compounds
pp. 1
Synthesis from 1,2-Unsaturated Pyranoses
pp. 1
Reductive Elimination of Tungsten/Molybdenum Disulfides
pp. 1
Reaction of Alcohols with Aldehydes in the Presence of Hydrogen Bromide
pp. 1
The Ramberg–Bäcklund Rearrangement
pp. 1
From Monoprotected 1,4-Diols
pp. 1
Synthesis of Product Subclass 1
pp. 1
OR/SH Acetals
pp. 1
O/O Acetals with Alkenyl Functionality
pp. 1
Synthesis from Ethers
pp. 1
Applications of Product Subclass 3 in Organic Synthesis
pp. 1
Synthesis of Product Subclass 1
pp. 1
From S/S Acetals
pp. 1
Silicon-Tethered Metathesis
pp. 1
Synthesis of Product Subclass 12
pp. 1
α-Halo Selenides by Addition Reactions
pp. 1
Addition of Chlorine to Enol Ethers
pp. 1
Addition of Amines to 1,1-Dihaloalkanes
pp. 1
Deoxofluorination of Carbonyl Compounds and Their Derivatives
pp. 1
Reactions of 1,6-Lactones with Either Phenol or Trimethylsilyl Phenoxide
pp. 1
Synthesis from Chloroform
pp. 1
Enolate Addition to an Aldehyde
pp. 1
Oxidative Insertion Reactions
pp. 1
Ring-Closing Metathesis
pp. 1
Synthesis from C—O Compounds
pp. 1
Synthesis of 1-Chloro-1-fluorocyclopropanes
pp. 1
Addition of an Alcohol to a 1,2-Dialkoxyalkene
pp. 1
With Carbonyl Compounds
pp. 1
Hetero-Diels–Alder Reactions
pp. 1
Halogenated O/O Acetals
pp. 1
1-O-Alkylation of 1--Nitro Glycosides
pp. 1
From Thioketones through [4+2] Cycloadditions
pp. 1
Synthesis from N—OH Compounds
pp. 1
Synthesis from Sulfonyl Derivatives
pp. 1
Anodic Fluorination of Ethers
pp. 1
1-Halogenation of 2-Azido-1--nitro Glycosides
pp. 1
α,β-Dihalosulfonamides by the Addition of Halogens to α,β-Unsaturated Sulfonamides
pp. 1
Modification of 1-Halo-1-nitroalkenes
pp. 1
Synthesis of 1-Selenopyranoses from 1--Acetyl Glycosides
pp. 1
Formation of the Glycosyl—S/Se/Te Bond
pp. 1
Acid-Catalyzed Michael Addition–Cyclization
pp. 1
From Enol Ethers via Wittig Alkenation
pp. 1
With Acid Derivatives
pp. 1
Rearrangement of Methylene-1,3-dioxanes
pp. 1
Synthesis Using Dichloromethyl Methyl Ether
pp. 1
Using Phenyl Sulfones
pp. 1
Formation of the Glycosyl—Sulfur/Selenium Bond by Addition of Selenocarboxylic -Acids to Glycals
pp. 1
Michael-Type Conjugate Addition
pp. 1
The Chloromethylsulfonyloxy Group in the Inversion of Secondary Alcohols
pp. 1
Applications of Product Subclass 6 in Organic Synthesis
pp. 1
Ozonolysis
pp. 1
Synthesis from Thiolactones
pp. 1
Oxidation of Glycosyl Disulfides
pp. 1
Addition of Phosphorus Trihalides
pp. 1
Synthesis of Product Subclass 7
pp. 1
1,3-Dioxolanes
pp. 1
Reactions with Alcohols
pp. 1
Reactions of Hal/S Acetals with Carbon Nucleophiles
pp. 1
Synthesis of Product Subclass 7
pp. 1
Applications of Product Subclass 2 in Organic Synthesis
pp. 1
Hal/S Acetals
pp. 1
α-Halo Sulfones by Michael Addition to Halovinyl Sulfones
pp. 1
Glycosylsulfinates and Glycosylsulfonates
pp. 1
1-O-Acetylation of 1--Nitro Glycosides
pp. 1
Glycosylsulfenyl Halides
pp. 1
Use as Nitric Oxide Releasing Compounds
pp. 1
Synthesis from Acetals with Other Heteroatoms
pp. 1
Applications of Product Subclass 6 in Organic Synthesis
pp. 1
Radical Halogenation
pp. 1
Halogenation of C=N Compounds
pp. 1
Synthesis from Other O/O Acetals
pp. 1
Cleavage of O/S(O) Acetals with Bromotrimethylsilane
pp. 1
From O/S Acetals
pp. 1
Nitration of 1,2-Deoxy Pyranoses with Ammonium Cerium(IV) Nitrate
pp. 1
OR/OS Acetals: 1-Alkoxysulfonates
pp. 1
From Hydroxylamines
pp. 1
Addition of Arenesulfenyl Chlorides to Enol Ethers
pp. 1
Synthesis Using Enamines
pp. 1
Peracid Oxidation of Bromoalkenes
pp. 1
In the Presence of Carbonyl Compounds
pp. 1
Synthesis by Formation of One C—O Bond
pp. 1
Organometallic Reagents Derived from α-Halo Sulfides, Sulfoxides, and Sulfones
pp. 1
Synthesis from Hal/OR Acetals
pp. 1
Applications of Product Subclass 3 in Organic Synthesis
pp. 1
By Cyclization of 2-Hydroxyalkyl Hal/O Acetals and 2-Haloalkyl Hemiacetals
pp. 1
Reactions of Pyranoses with Organometallic Vinyl Group Carriers
pp. 1
Halogenation of O/N and N/N Acetals
pp. 1
Electrochemical Halogenation
pp. 1
Oxidation of (-Butyldimethylsilyl)hydrazones with Iodine
pp. 1
Cycloaddition
pp. 1
From 5-Methylene-1,3-dioxanes
pp. 1
Synthesis from Thioglycosides
pp. 1
α-Haloammonium Salts
pp. 1
Intramolecular Radical Reactions
pp. 1
Fluorination of C=N Compounds
pp. 1
Carbonyl Cascade Processes
pp. 1
Hydrogenation of the Double Bond of an Allyl Group
pp. 1
Acid Hydrolysis
pp. 1
Cl/Br Acetals
pp. 1
Functionalization of 1-Halo-1-nitroalkanes
pp. 1
Formation of 1--Phenyl Glycosides
pp. 1
Hal/Se and Hal/Te Acetals
pp. 1
Metal-Catalyzed Processes
pp. 1
Synthesis from Vinyl Thioethers
pp. 1
Halogenation of Imines
pp. 1
Miscellaneous Methods
pp. 1
Synthesis from Glycals
pp. 1
From Amines and Other Nitrogen Derivatives
pp. 1
α-Halo Sulfides and α-Halosulfenyl Compounds
pp. 1
Acetylation of 1-Halo Pyranoses with Metal Acetates
pp. 1
Synthesis by Formation of Two C—O Bonds
pp. 1
α-Halo Selenides from Enolates
pp. 1
Synthesis from Ketenes and Ketene Acetals
pp. 1
Synthesis from Oxathiolium Salts
pp. 1
From Reactions of Carbonyl Compounds with 1,3-Diols
pp. 1
Alkyl/Aryl Thioglycosides, Selenoglycosides, and Telluroglycosides
pp. 1
α-Halo Carbonyl Compounds by Isomerization of 2-Bromooxiranes
pp. 1
Bromomethylation of Aromatic Compounds
pp. 1
Reaction with Enolates or Enolate Equivalents
pp. 1
1,4-Addition of Alcohols to β-Halo- or β-Alkoxy-α,β-Unsaturated Carbonyl Compounds
pp. 1
Applications of Product Subclass 1 in Organic Synthesis
pp. 1
Addition of Hydrogen Bromide to Enol Ethers
pp. 1
α-Halo Sulfones by the Reaction of α-Halo Sulfone Anions with Carbon Electrophiles
pp. 1
Reduction of OR/SOR Acetals Using Tebbe's Reagent
pp. 1
Reaction of Orthoformates with Alkynylmagnesium Compounds
pp. 1
Iodination of Hydrazones
pp. 1
Samarium(II) Iodide Mediated Barbier Reactions
pp. 1
From Hal/OR Acetals
pp. 1
Silyl-Modified Sakurai Reactions
pp. 1
Nucleophilic Addition to Aldehydes
pp. 1
Synthesis from 1,1-Bis(trifluoromethylsulfonyloxy) Compounds
pp. 1
Cleavage To Give Carbonyl Compounds and 1,3-Diols
pp. 1
Azidophenylselanylation
pp. 1
Other Synthetic Applications
pp. 1
Synthesis of Carbohydrates
pp. 1
Synthesis of Product Subclass 2
pp. 1
1,3-Dioxepanes
pp. 1
Synthesis from OH/SOR Acetals
pp. 1
Using Boron Compounds
pp. 1
Synthesis from Nitroso Compounds and N—OH Derivatives
pp. 1
Formation of the Acyl—Sulfur/Selenium Bond by Substitution of Carbon
pp. 1
By Fluorodesulfurization of Dithioacetals or Dithioketals
pp. 1
From Enol Ethers via Cycloaddition
pp. 1
Synthesis of Product Subclass 8
pp. 1
Free-Radical Additions
pp. 1
Glycosyl Iodides
pp. 1
Decarbonylation of Alkoxy- and (Aryloxy)acetyl Chlorides
pp. 1
α-Halophosphonium Salts
pp. 1
Cleavage of O/O Acetals with Iodotrimethylsilane
pp. 1
Substitution Reactions of the Phenyl Group
pp. 1
From Vinyl Sulfides by Cycloaddition Reactions
pp. 1
Reactions with Thiols
pp. 1
By Oxidation with Alkyl Nitrites
pp. 1
Synthesis of Product Subclass 6
pp. 1
Alkylation of a Lithioferrocene
pp. 1
From 2-Lithio-1,3-dioxane
pp. 1
Decarboxylative Chlorination of -Acyl Thiohydroxamates (Barton–Borodin–Hunsdiecker Reaction)
pp. 1
Cleavage To Give Monoprotected 1,4-Diols
pp. 1
Claisen Condensation
pp. 1
α-Halophosphorus(V) Compounds
pp. 1
From Alcohols without Removal of Water
pp. 1
Stereoselective Ketal-Tethered Intramolecular Diels–Alder Reaction
pp. 1
Synthesis from Other Glycosyl Halides
pp. 1
Synthesis from Dichloroalkanes
pp. 1
Halogenation of Sulfones under Basic Conditions
pp. 1
Alternative Routes to β-Hydroxy Ketones
pp. 1
Chiral 1,3-Dioxolanes in Asymmetric Synthesis
pp. 1
Synthesis from N—O Containing Compounds
pp. 1
Nitration of 1-Bromo Pyranoses with Silver(I) Nitrate
pp. 1
From Ketones
pp. 1
Formation of the Glycosyl—Sulfur Bond by Substitution of Oxygen: In Situ Activation of Anomeric Alcohols
pp. 1
Halogenation of C—O Compounds
pp. 1
Halogenation of α-Hydroxyphosphonium Salts
pp. 1
Halomethyl Sulfoxides by the Addition of Diazomethane to Sulfinyl Halides
pp. 1
Chalcogenated O/O Acetals
pp. 1
Halogenation of Vinylphosphorus(V) Derivatives
pp. 1
Synthesis from Glycosyl Halides
pp. 1
Addition to Alkenes
pp. 1
1,2--Methylene Pyranoses
pp. 1
Synthesis through Cycloaddition Reactions
pp. 1
From Sulfides
pp. 1
From Aryl Ethers by Oxidation
pp. 1
Reaction of α-Chloro Ethers with Lithium Bromide, Hydrogen Bromide, or Bromine
pp. 1
From Alkynes
pp. 1
α-Halosulfenyl Halides by Addition Reactions
pp. 1
Enzymatic Hydrolysis
pp. 1
Hydroboration of Alkyne-α,ω-diols
pp. 1
In Unconventional Media
pp. 1
From Reactions of 1,4-Diols with Enol Ethers
pp. 1
From Tungsten-Coordinated Selenoaldehydes by [2+2] Cycloaddition
pp. 1
Use as Protecting Groups
pp. 1
Photooxygenation
pp. 1
From Hal/S Acetals
pp. 1
Halogenation of Hydrazones
pp. 1
Formation of the S—Aglycone Bond by Substitution of Hydrogen
pp. 1
Synthesis of Product Subclass 3
pp. 1
F/Br Acetals
pp. 1
Via Dichloro(metallo)alkanes
pp. 1
Using Sulfone-Stabilized Carbanions
pp. 1
Formation of 1-Azido Pyranoses
pp. 1
Synthesis of -Bromo(chloro)cyclopropanes
pp. 1
From Trialkyl Orthoformates
pp. 1
Synthesis from Aldehydes and Ketones
pp. 1
Synthesis of Product Subclass 2
pp. 1
α-Halo Sulfones and -(α-Haloalkyl)sulfoximides
pp. 1
Synthesis of Product Subclass 6
pp. 1
From Reactions of Acetals with 1,4-Diols
pp. 1
Synthesis of -Chloro(iodo)cyclopropanes
pp. 1
Synthesis of Product Subclass 4
pp. 1
Using Nitro-Stabilized Anions
pp. 1
Fluorination of Hydrazones, Azines, Oximes, or Oxime Ethers
pp. 1
By Electrochemical Oxidation
pp. 1
From Reactions of 1,3-Diols with 1,1-Dihaloalkanes
pp. 1
Using Glycosyltransferases
pp. 1
Formation of 1--Allyl Glycosides
pp. 1
Reactions of 1,6-Anhydro Pyranoses with Allyl Alcohol Derivatives
pp. 1
Synthesis from Carbonyl Compounds
pp. 1
Synthesis of 1-Bromo-1-fluorocyclopropanes
pp. 1
Carbonyl Alkenations with an Alkoxychloromethane/Titanocene(II) System
pp. 1
Synthesis of Product Subclass 3
pp. 1
Displacement of Halide from Hal/Hal Acetals by an Organothiol or an Organothiolate
pp. 1
Other Methods
pp. 1
Formation of the S/Se—H Bond by Substitution of Carbon
pp. 1
Alkylation of Phenyl Sulfones
pp. 1
Self-Condensation of Lactones
pp. 1
Thiolysis of 1--Methyl Glycosides
pp. 1
Applications of Product Subclass 1 in Organic Synthesis
pp. 1
Reactions of Metalated OR/SOR Acetals
pp. 1
Mercury-Mediated Addition of Alcohols to Enynes
pp. 1
Oxidation of 1,3-Thiazolidines
pp. 1
By Fluorination of Alkenes and Fluoroalkenes
pp. 1
From Phenols
pp. 1
Oxidation of Chloroalkenes
pp. 1
Chalcogenoetherification of Alkenes
pp. 1
Synthesis from α-Chloro Sulfoxides
pp. 1
Silyl Enol Addition
pp. 1
By Oxidation of Benzenes
pp. 1
Cl/Cl Acetals
pp. 1
OR/ON Acetals: 1,3,4-Dioxazolidines and Related Cyclic Compounds
pp. 1
Cleavage To Give Monoprotected 1,3-Diols
pp. 1
Synthesis Using Lewis Acids or Chlorinating Agents
pp. 1
From Metalated Dioxolanes
pp. 1
F/Cl Acetals
pp. 1
From Reactions of Acetals with Diols
pp. 1
Synthesis from 1,1-Dihaloalkanes
pp. 1
Synthesis of -Glycosides from 1--Acetyl Glycosides
pp. 1
Synthesis of Product Subclass 8
pp. 1
Addition of Hydrogen Chloride to Enol Ethers
pp. 1
Reactions of 1-Hydroxy Pyranoses with Phenols
pp. 1
Fluorination Using Palladium Complexes
pp. 1
Synthesis from Heterosubstituted Alkenes
pp. 1
Synthesis of Product Subclass 2
pp. 1
From Ortho Esters
pp. 1
Anionic Acylation Reactions
pp. 1
Using Bromotrimethylsilane
pp. 1
Nitrated O/O Acetals
pp. 1
Reactions of Dihydrooxazole Derivatives
pp. 1
Dehydrobromination
pp. 1
Fluorination α to a Phosphonyl or Sulfonyl Group
pp. 1
Peracid Oxidation of Fluoroalkenes
pp. 1
Synthesis of Carbonyl Compounds
pp. 1
Applications of Product Subclass 3 in Organic Synthesis
pp. 1
Formation of the Glycosyl—S/Se/Te Bond by Substitution of Oxygen
pp. 1
Of Alkynes
pp. 1
Asymmetric Oxyselanylation
pp. 1
1--Allyl Glycosides
pp. 1
Reactions of 1--Silyl Pyranoses with Silyl Ethers
pp. 1
With Reduction of Dichalcogenides In Situ
pp. 1
Synthesis Using Hydrogen Chloride
pp. 1
Formation of the Glycosyl—Sulfur Bond by Substitution of Halides
pp. 1
Glycosyl Sulfoxides and Selenoxides
pp. 1
Reactions of 1-Halo Pyranoses with Pent-4-en-1-ol
pp. 1
Stereocontrolled Aldol Addition
pp. 1
Synthesis of Product Subclass 5
pp. 1
Synthesis of Product Subclass 2
pp. 1
Synthesis of Cyclic Ethers from 1,3-Dioxanes
pp. 1
Synthesis of Product Subclass 4
pp. 1
Radical Addition to Enol Ethers
pp. 1
Synthesis from Diiodo(metallo)methanes
pp. 1
Synthesis of Product Subclass 9
pp. 1
α-Halo Sulfoxides by Michael Addition to α-Halovinyl Sulfoxides
pp. 1
1--Phenyl Glycosides
pp. 1
Synthesis of Product Subclass 3
pp. 1
Synthesis from Alkanes
pp. 1
Synthesis from Glycosyl Phosphites
pp. 1
Reactions of 1--Trichloroacetimidyl Pyranoses with Pent-4-en-1-ol
pp. 1
By Oxidation of Electron-Rich Arenes and Hetarenes and Cyclization
pp. 1
Synthesis from Alkenes
pp. 1
From Cyclic Ether Phenyl Sulfones as Precursors
pp. 1
Synthesis from Other -Glycosides
pp. 1
Metalated O/O Acetals
pp. 1
Reactions of 1--Acetyl Pyranoses with Phenoxides
pp. 1
With Other Acetals
pp. 1
OR/ON Acetals: 6-Alkoxy-3-1,2-oxazines and Related Compounds
pp. 1
Applications of Product Subclass 1 in Organic Synthesis
pp. 1
Acylation
pp. 1
Using Acyl Anion Equivalents
pp. 1
Glycosyl Chlorides
pp. 1
Synthesis from Bromo(chloro)methane
pp. 1
Acetylation of 1--Methyl Pyranoses
pp. 1
Trapping of Vinylcopper Reagents
pp. 1
From Reactions of Carbonyl Compounds with 1,4-Diols
pp. 1
Functionalization of α-Halo Phosphorus(V) Compounds
pp. 1
Formation of Enol Ethers
pp. 1
Synthesis of Product Subclass 5
pp. 1
Synthesis of Product Subclass 6
pp. 1
From Oximes
pp. 1
From Nitrile Oxides
pp. 1
Synthesis by Cycloaddition Reactions
pp. 1
Reaction of Metalated Geminal Dichloroalkanes with Ketones
pp. 1
Glycosyl Thioesters and Selenoesters
pp. 1
Cyclization of Dihydroxy Ketones
pp. 1
Decarboxylation with Xenon Difluoride
pp. 1
Applications of Product Subclass 2 in Organic Synthesis
pp. 1
Using -Iodosuccinimide and ,-Diethylaminosulfur Trifluoride
pp. 1
Br/I Acetals
pp. 1
Reaction of Alkylphosphorus(III) Compounds with Carbon Tetrahalides
pp. 1
Synthesis of Product Subclass 1
pp. 1
Synthesis from -Glycosides
pp. 1
1--Nitro Glycosides
pp. 1
Vicarious Nucleophilic Substitution Reactions
pp. 1
Reaction of α-Halo Sulfoxide Anions with Carbon Electrophiles
pp. 1
Radical Epimerization
pp. 1
Synthesis from OR/SR Acetals by Oxidation
pp. 1
α-Halo Sulfones by Addition Reactions
pp. 1
Reagents Derived from α-Halo Sulfoxides
pp. 1
Glycosylation with Imides
pp. 1
Synthesis of Product Subclass 2
pp. 1
Synthesis from 1-Thioglycosides
pp. 1
From Alcohols and Alkylating Agents
pp. 1
Deprotection to Carbonyl Compounds and 1,2-Diols
pp. 1
Dichalcogenide Exchange
pp. 1
From Other Acetals
pp. 1
Reactions of 2-Deoxy Pyranoses with Pent-4-en-1-ol
pp. 1
Synthesis from Organomercury Carbene Precursors
pp. 1
Glycosyl Sulfones
pp. 1
Fluorination of 2-Azirines
pp. 1
From Alkoxysilanes
pp. 1
Cleavage of O/S Acetals with Bromine
pp. 1
Additions to the Vinylic Double Bond
pp. 1
Synthesis of Product Subclass 16
pp. 1
Substitution of Halide Ion from Glycosylselenenyl Halides Generated In Situ
pp. 1
Radical Cyclizations in the Total Synthesis of Natural Products
pp. 1
Trapping of Dichloroketene
pp. 1
Cyclopropanation (The Simmons–Smith Reaction)
pp. 1
Synthesis of Product Subclass 5
pp. 1
OR/OO Acetals: 1,2,4-Trioxolanes
pp. 1
Synthesis of Product Subclass 7
pp. 1
Applications of Product Subclass 3 in Organic Synthesis
pp. 1
Reactions of Epoxides with Ketones
pp. 1
Formation of 1-Hydroxy Pyranoses
pp. 1
Synthesis of Product Subclass 5
pp. 1
Synthesis of -Dibromocyclopropanes
pp. 1
Cyclization Reactions
pp. 1
Using Nonstabilized Carbanions
pp. 1
From Stable Acyclic Hemiacetals Derived from Allylic Alcohols
pp. 1
Synthesis of 1,3-Diols
pp. 1
Intramolecular Epoxide Ring Opening
pp. 1
Synthesis of Product Subclass 6
pp. 1
1--Trichloroacetimidyl Glycosides
pp. 1
Synthesis by Formation of One C—O Bond
pp. 1
Applications of Product Subclass 4 in Organic Synthesis
pp. 1
Iridium-Catalyzed Reactions
pp. 1
Glycosyl Fluorides
pp. 1
Sequential 1,4-Addition of Alcohols to Electron-Deficient Alkynes
pp. 1
From S/S Acetals
pp. 1
With Thiols and Selenols under Biphasic Conditions
pp. 1
Applications of Product Subclass 8 in Organic Synthesis
pp. 1
F/O Acetals
pp. 1
With (Alkylsulfanyl)- and (Arylsulfanyl)tributylstannanes and Trimethylsilanes
pp. 1
Reactions with Silyl Enol Ethers
pp. 1
Reactions of 1--Trichloroacetimidyl Pyranoses with Allyl Alcohol
pp. 1
Claisen Rearrangement
pp. 1
Synthesis from Thio-, Seleno-, and Telluroglycosides
pp. 1
Other Transformations
pp. 1
Synthesis from Enol Ethers
pp. 1
Formation of α-Alkoxy Phosphorus Compounds
pp. 1
Chiral 1,3-Dioxanes in Asymmetric Synthesis
pp. 1
Glycosylsulfimides
pp. 1
From Reactions of Dihaloalkanes with Diols
pp. 1
Reactions of Acetals and Ketals with 1,2-Diols
pp. 1
OR/OSi Acetals: Alkyl Silyl Acetals
pp. 1
From Hal/Hal Acetals
pp. 1
OR/ON Acetals: 1-Aminooxy Carbohydrates and Related Compounds
pp. 1
Formation of the Glycosyl—S/Se/Te Bond by Substitution of Halides
pp. 1
Synthesis of Product Subclass 3
pp. 1
α-Halo Sulfides by Substitution
pp. 1
Direct Halogenation of Activated Sulfones
pp. 1
Synthesis from -Alkyl Glycosides
pp. 1
Synthesis of Product Subclass 1
pp. 1
Synthesis from C=N Compounds
pp. 1
Formation of 1--Glycosides from Azido Nitrates
pp. 1
Chlorination of Alkanes
pp. 1
Synthesis from Pyranoses
pp. 1
Halogenation of α-Hydroxy Amides and Related Compounds
pp. 1
Synthesis from Vinyl Ethers
pp. 1
Synthesis by Bond Disconnection
pp. 1
Formation of the Glycosyl—Sulfur Bond by Displacement of Halides
pp. 1
Halogenation of O/N Acetals
pp. 1
Synthesis from 1--Acetyl Glycosides
pp. 1
Using Weinreb Amides Involving Acetylide Addition Followed by Reduction
pp. 1
Addition of (Benzyloxy)fluorocarbene to Acrylonitrile
pp. 1
Acid-Catalyzed Carbonyl Cascade Process
pp. 1
Glycosyl Thiols, Glycosyl Selenols, and Glycosyl Tellurols
pp. 1
Synthesis from Chloroalkanes
pp. 1
α-Halo Amides, α-Halo Imides, α-Halocarbamates, and α-Halo Sulfonamides
pp. 1
Synthesis of Product Subclass 15
pp. 1
Oxidation of 4,5-Dihydroglycopyranoso[2,1-]-1,3-thiazoles and Thioacetates
pp. 1
Metalation of OR/SR Acetals
pp. 1
OR/OSi Acetals: Oxasilacycles and Related Compounds
pp. 1
Oxidation of Thioglycosides
pp. 1
Synthesis from Imines, Oximes, and Related Compounds
pp. 1
Synthesis of Product Subclass 4
pp. 1
α-Halosulfinyl Halides by the Oxidation of α-Halosulfenyl Halides
pp. 1
Synthesis from [Chloro(iodo)methyl]lithium
pp. 1
In Protic and Nonparticipating Solvents
pp. 1
Reaction of α-Halosulfonamide Anions with Carbon Electrophiles
pp. 1
Synthesis from -Acyl Glycosides
pp. 1
Synthesis from Organometallic Compounds
pp. 1
Synthesis from Bromo(chloro)(metallo)alkanes
pp. 1
Formation of the Glycosyl—S/Se/Te Bond by Addition to Glycals
pp. 1
α-Halo Selenides and α-Halo Tellurides by Substitution
pp. 1
Reactions of 1--Nitro Pyranoses with Pent-4-en-1-ol
pp. 1
Applications of Product Subclass 7 in Organic Synthesis
pp. 1
From Silyl Enol Ethers
pp. 1
Applications of Product Subclass 4 in Organic Synthesis
pp. 1
From Hal/O Acetals
pp. 1
α-Halosulfonyl Chlorides, α-Halosulfonates, and α-Halosulfonamides
pp. 1
Synthesis of Product Subclass 2
pp. 1
Synthesis from Free Sugars
pp. 1
Addition of Other Chlorocarbonyl Reagents
pp. 1
Synthesis from Hal/O, Hal/Se, or O/O Acetals
pp. 1
Reactions of Carbonyl Compounds with 1,2-Bis(trimethylsilyl) Ethers
pp. 1
1-O-Phosphorylation of 1--Nitro Glycosides
pp. 1
Synthesis of -Dichlorocyclopropanes
pp. 1
Using Acetylide Anions Followed by Hydrogenation and Oxidation
pp. 1
Synthesis of Product Subclass 3
pp. 1
Fluorination α to a Carbonyl Group
pp. 1
Halogenation of Ketazines
pp. 1
Applications of Product Subclass 2 in Organic Synthesis
pp. 1
Formation of Glycosyl Nitrates
pp. 1
Applications of Product Subclass 1 in Organic Synthesis
pp. 1
Synthesis of Product Subclass 3
pp. 1
Reaction of Enolates or Enamines with Orthoformates
pp. 1
Hydrolysis
pp. 1
Halogenation of Acyl Enamines
pp. 1
Removal of the Allyl Group and the Synthesis of 1-Hydroxy Pyranoses
pp. 1
Glycosyl Isothiouronium and Isoselenouronium Salts
pp. 1
Synthesis from Unsaturated Sulfones
pp. 1
Synthesis from Hal/OR, Hal/SOR, or OR/OR Acetals
pp. 1
Using Glycosidases (Hydrolases)
pp. 1
Acetylation of Pyranoses with Acetic Anhydride
pp. 1
Deprotection Reactions of 1,3-Dioxanes
pp. 1
Reaction of Alcohols with Aldehydes in the Presence of a Chlorinating Agent
pp. 1
Rearrangement of Bicyclic Acetals
pp. 1
Reactions of Enol Ethers with 1,2-Diols
pp. 1
Selective Dehalogenation of α,α-Dihalophosphorus(V) Compounds
pp. 1
Formation of 1-Halo Pyranoses
pp. 1
Oxidation of α-Halo Sulfoxides
pp. 1
Exchange of Ligands on Existing Acetals
pp. 1
1--Methyl Glycosides
pp. 1
Oxidation of Sulfides
pp. 1
Reactions of Carbonyl Compounds with 1,2-Diols
pp. 1
Synthesis via the Pummerer Reaction
pp. 1
From Enol Ethers
pp. 1
Radical Reactions of Trichloroalkanes
pp. 1
From O/O Acetals
pp. 1
Synthesis by Reduction
pp. 1
Hydrolysis of 1--Phenyl Glycosides
pp. 1
OR/ON Acetals: 5-Alkoxyisoxazoles and -isoxazolidines
pp. 1
From Nitrones
pp. 1
Direct Silylation of Alcohols
pp. 1
Halogenation of N/N Acetals
pp. 1
From Organosilanes
pp. 1
Dimerization of Enol Ethers
pp. 1
From Organomagnesium Compounds
pp. 1
Applications of Product Subclass 4 in Organic Synthesis
pp. 1
By Exchange of One Alkoxy Group
pp. 1
Cyclization of Hydroxy Diketones
pp. 1
From Vinylacetylenes
pp. 1
From Reactions of Enol Ethers with 1,3-Diols
pp. 1
Synthesis of Product Subclass 1
pp. 1
O/O Acetals with Alkynyl Functionality
pp. 1
Synthesis from Aldehydes or Ketones and Alcohol Derivatives
pp. 1
Reactions of 1-Thioglycosides with Trichloroacetonitrile
pp. 1
Via 1,2-Anhydroglycopyranoses
pp. 1
α-Elimination from Bromoform
pp. 1
From Alcohols with Removal of Water by Physical Methods
pp. 1
From Dimethyl Sulfoxide
pp. 1
1-O-Alkylation/Arylation of 1--Acetyl Glycosides
pp. 1
Synthesis from Alkenes
pp. 1
Synthesis from Haloalkanes and Haloalkenes
pp. 1
By Oxidation with Thallium(III) Salts
pp. 1
Synthesis of Product Subclass 3
pp. 1
Synthesis from Metalated OR/SR Acetals
pp. 1
Synthesis of Product Subclass 1
pp. 1
Synthesis from Weinreb Amides via Acetylide Addition Followed by Hetero-Michael Addition
pp. 1
Formation of 1-Thioglycosides
pp. 1
Metalation of OR/SOR Acetals
pp. 1
α-Haloamines
pp. 1
α-Halo Sulfoxides by the Addition of Halogens to Vinylic Sulfoxides
pp. 1
Alkoxymercuration of Alk-1-enyl Ethers
pp. 1
Alkenylation of Free Pyranoses in the Presence of Palladium(0) Complexes
pp. 1
Using Acetylide Anions Followed by Reoxidation and β-Oxo-1,3-dithiane Formation
pp. 1
Applications of Product Subclass 5 in Organic Synthesis
pp. 1
Cleavage of O/S(O) Acetals with ,-Diethylaminosulfur Trifluoride
pp. 1
Synthesis of Product Subclass 2
pp. 1
[2+2] Cycloaddition of Dichloroketene
pp. 1
Bromination of Enol Ethers
pp. 1
Addition of Carbon Tetrachloride to Enol Ethers
pp. 1
Synthesis of 1,2-Ortho Esters from 1--Acetyl Glycosides
pp. 1
Substitution of α-Halosulfenyl Halides with Nucleophiles
pp. 1
Nucleophilic Substitution with Fluoride Ions
pp. 1
Synthesis of Product Subclass 7
pp. 1
α-Halosulfonamides by Halogenation of Sulfonamides
pp. 1
Synthesis of Product Subclass 3
pp. 1
Cleavage of O/O Acetals
pp. 1
1,3-Dioxanes
pp. 1
Synthesis of Product Subclass 3
pp. 1
By Addition to Alkenes
pp. 1
Synthesis from Alkynes
pp. 1
Ferrier Rearrangement
pp. 1
Reactions of 1-Halo Pyranoses with Phenol
pp. 1
Synthesis by Formation of One C—O Bond
pp. 1
From Hal/SOR Acetals
pp. 1
Synthesis of Product Class 6
pp. 1
Synthesis from Haloalkanes by Halogen Exchange
pp. 1
Synthesis by Formation of Two C—O Bonds
pp. 1
α-Dibromination of Carbonyl Compounds
pp. 1
Synthesis of Difluorocyclopropanes
pp. 1
Synthesis from Fluorinated Alkenes
pp. 1
Synthesis from Diazenium Diolates
pp. 1
Synthesis from Glycals
pp. 1
From 2-(Alkylsulfanyl)- or 2-(Arylsulfanyl)furans through Cycloadditions
pp. 1
Synthesis of Product Subclass 7
pp. 1
I/O Acetals
pp. 1
By Intramolecular Transacetalization
pp. 1
Chlorination, Bromination, and Iodination
pp. 1
Double Heteroatom Addition to Weinreb Amides
pp. 1
Synthesis of Product Subclass 4
pp. 1
Hydroboration–Cyclization
pp. 1
Halogenation of Silyl-Stabilized Carbanions
pp. 1
Substitution of Alkyl with Alkenyl Substituents
pp. 1
Using α,β-Unsaturated Ketones
pp. 1
α-Halosulfonates by the Substitution of Dihalomethanes
pp. 1
From Organoaluminum and Organozinc Compounds
pp. 1
Formation of Disaccharides
pp. 1
O/O Acetals with Carbonyl Functionality
pp. 1
Synthesis of 1-Thioglycosides from 1--Acetyl Glycosides
pp. 1
Reaction with Enolates
pp. 1
α-Halo Sulfoxides
pp. 1
Chlorination of Alkynes
pp. 1
Double Allylboration of Aldehydes
pp. 1
Synthesis by [3+2]-Cycloaddition Reactions
pp. 1
Bromination of Alkanes
pp. 1
Synthesis of Artemisinin and Related Compounds
pp. 1
Synthesis from Thiones
pp. 1
Cyclization of Hydroperoxides
pp. 1
Intramolecular Substitution of Oxygen by a Thioacetamido Group
pp. 1
Palladium(0)-Catalyzed Allylation
pp. 1
Synthesis from 1--Trichloroacetimidyl Pyranoses
pp. 1
Synthesis from Alkynes
pp. 1
Cleavage of α-Alkoxy Stannanes with Bromine
pp. 1
Synthesis from -Dihaloalkanes
pp. 1
Synthesis from 1-Halo-2--acyl Pyranoses
pp. 1
Fragmentation and Bromination of a 2-Deoxy-2-fluoro Carbohydrate Derivative
pp. 1
Addition of Phosphines to 1,1-Dihaloalkanes
pp. 1
Formation of α-Metalated Ethers
pp. 1
Carbenes/Carbenoid Formation
pp. 1
Synthesis from 1,2-Halohydrins
pp. 1
Formation of Alkenes
pp. 1
From Reactions of Alkenes with 1,3-Diols
pp. 1
From Furans and Alcohols
pp. 1
Synthesis of Product Subclass 14
pp. 1
Synthesis of Product Subclass 6
pp. 1
Synthesis of Product Subclass 6
pp. 1
Synthesis of Product Subclass 4
pp. 1
By Oxidation with Ozone
pp. 1
Fluorodecarboxylation of Carboxylic Acids
pp. 1
Formation of the S/Se/Te—Aglycone Bond by Additions to Alkenes
pp. 1
Synthesis from Dibromo(metallo)alkanes
pp. 1
As Chiral Reagents
pp. 1
From Alkyl- and Arylalkynes
pp. 1
Chlorination of Ethers
pp. 1
Synthesis of Product Subclass 1
pp. 1
Synthesis of Product Subclass 1
pp. 1
Synthesis from Aldehydes or Ketones
pp. 1
From Thiones through Dipolar Cycloadditions
pp. 1
Formation of the Glycosyl—Sulfur/Selenium Bond by Substitution of -Esters
pp. 1
Reaction with Main-Group Organometallic Compounds
pp. 1
Reactions of 1--Acetyl Pyranoses with Pent-4-en-1-ol
pp. 1
Palladium-Catalyzed Cycloisomerization
pp. 1
Reduction of Phosphorus(V) Derivatives
pp. 1
α-Halonitro and Related Compounds
pp. 1
Formation of O/O Acetals: Protection of Alcohols
pp. 1
Use as Synthetic Intermediates
pp. 1
Preparation of α-Halonitro Compounds
pp. 1
Polymer-Supported Ketal Protection
pp. 1
Reduction of Dichalcogenides
pp. 1
Synthesis with Migration
pp. 1
From Homoallylic Alcohols
pp. 1
α-Halosulfonyl Halides by Halogenation
pp. 1
Synthesis from Compounds of Higher Oxidation State
pp. 1
Formation of the S/Se/Te—Aglycone Bond by Reduction of Dichalcogenides and Alkylation of the Products In Situ
pp. 1
Synthesis from Trichloroacetates
pp. 1
Synthesis of Product Subclass 2
pp. 1
Formation of the S/Se/Te—P Bond
pp. 1
Glycosylsulfinamides and Glycosylsulfonamides
pp. 1
Synthesis from 1-Phosphoramidates
pp. 1
Using Sulfuryl Chloride
pp. 1
From Double Addition to Ethyl Formate
pp. 1
Bromination of Ethers
pp. 1
Formation of 1--Acetyl Pyranoses
pp. 1
Using Acetylide Anions Followed by Reoxidation and Metal-Catalyzed Reduction
pp. 1
From Alcohols and Ethers
pp. 1
Synthesis of Product Subclass 1
pp. 1
Glycosyl Dichalcogenides
pp. 1
Synthesis by Formation of One C—O and One C—C Bond
pp. 1
Applications of Product Subclass 7 in Organic Synthesis
pp. 1
Reactions of Ketones and 2-Halo Alcohols
pp. 1
Synthesis of Product Subclass 9
pp. 1
Synthesis of Product Subclass 2
pp. 1
Rhodium(II)-Catalyzed Reaction of Diazo Dicarbonyl Compounds with Dibromomethane
pp. 1
Synthesis of Product Subclass 4
pp. 1
Formation of the S—S Bond: Reactions between Glycosylsulfenyl Bromides and Water
pp. 1
Acetylide Anion Addition
pp. 1
From Alkyl Alcohols by the Mitsunobu Reaction
pp. 1
Deoxofluorination of Aldehydes and Ketones
pp. 1
Using Boron Trichloride
pp. 1
-Alkyl -Glycosyl Dithiocarbonates and -Glycosyl ,-Dialkyldithiocarbamates
pp. 1
Radical Reactions
pp. 1
Modification of α-Haloalk-1-enylphosphorus(V) Compounds
pp. 1
Synthesis of Product Subclass 2
pp. 1
Transformation of Benzyl Alcohols into (Fluoromethoxy)benzenes Using Xenon Difluoride
pp. 1
Reactions of 1--Acetyl Pyranoses with Trichloroacetonitrile
pp. 1
Applications of Product Subclass 1 in Organic Synthesis
pp. 1
Synthesis from Alkynes
pp. 1
Organoselenium-Mediated Cyclization
pp. 1
Halogenation of α-Hydroxyphosphorus(V) Derivatives
pp. 1
Reactions of Pyranoses with Pent-4-en-1-ol
pp. 1
From Alkynes with Electron-Withdrawing Substituents
pp. 1
Synthesis from -Dihaloalkanes
pp. 1
Dehalogenation of 1,2-Dihalo Ethers
pp. 1
Applications of Product Subclass 2 in Organic Synthesis
pp. 1
Synthesis from Haloalkenes
pp. 1
Applications of Product Subclass 2 in Organic Synthesis
pp. 1
Synthesis from OR/SR Acetals
pp. 1
Deprotonation and Halogenation α to Nitrogen
pp. 1
Formation of 1,6-Anhydro Pyranoses
pp. 1
Synthesis from Thionolactones
pp. 1
Chloromethylation of Aromatic Compounds
pp. 1
Norrish Type II Photochemical Reactions
pp. 1
α-Halo Sulfides by the Addition of Organosulfenyl Halides to α-Diazo Carbonyl Compounds
pp. 1
Substitution of α-Halosulfonyl Halides with Heteroatom Nucleophiles
pp. 1
Applications of Product Subclass 9 in Organic Synthesis
pp. 1
From Reduction of Dioxins
pp. 1
Chlorination of Hydrazones
pp. 1
From Reactions of Carbonyl Compounds and Diols
pp. 1
Preparation of α-Halonitroso Compounds
pp. 1
Synthesis from Haloalkanes
pp. 1
1--Vinyl Glycosides
pp. 1
Synthesis of Product Subclass 8
pp. 1
From Allylic and Homoallylic Alcohols
pp. 1
-Dialkyl -/-/-Glycosyl Phosphorothioates/-selenoates/-telluroates/-thioselenoates/-dithioates
pp. 1
As Chiral Auxiliaries
pp. 1
Radical Cyclization of Pyran Derivatives Using Hypervalent Iodine
pp. 1
Oxidation of OR/SR Acetals
pp. 1
Synthesis from Other Precursors
pp. 1
Reactions of 1,2-Anhydro Pyranoses with Phenols
pp. 1
α-Halo Sulfides from Sulfoxides by Pummerer Rearrangement
pp. 1
From O/N Acetals
pp. 1
Reactions with Phosphoric Acid Derivatives
pp. 1
1-O-Denitration of 1--Nitro Glycosides
pp. 1
Reactions with Phenols
pp. 1
Base-Mediated Rearrangement of -Dihalocyclopropyl Ethers Followed by Elimination
pp. 1
Synthesis from Vinyl Sulfides
pp. 1
Halogenation of -Acyl O/N Acetals and Analogues
pp. 1
Synthesis by Carbene Insertions
pp. 1
Synthesis from 1-Selenopyranoses
pp. 1
Synthesis of Product Subclass 4
pp. 1
From Hydroxamic Acids and Imides
pp. 1
Synthesis of Product Subclass 13
pp. 1
α-Halo Sulfones by the Halogenation of Sulfones
pp. 1
Displacement of an Organosulfanyl Substituent from Dithioacetals by Halogen
pp. 1
Carbanion Addition to Lactones
pp. 1
Pummerer Reaction
pp. 1
Substitution of Sulfur in Disulfides and Thiosulfonates
pp. 1
β-Lactone Ring-Opening Spirocyclization
pp. 1
Applications of Product Subclass 1 in Organic Synthesis
pp. 1
Addition of Phosphites
pp. 1
[3,3]-Sigmatropic Rearrangement of Ylides Derived from Dichloroketene
pp. 1
By Oxidation with Molecular Oxygen
pp. 1
Reaction of Orthoformates with Alk-1-ynes under Zinc Salt Catalysis
pp. 1
Displacement of Monothioacetals by Halides
pp. 1
α-Halo Selenides and α-Halo Tellurides by Addition of Selenenyl Halides to Diazoalkanes
pp. 1
Oxidation of α-Halo Sulfides
pp. 1
Formation of Ethers
pp. 1
OH/SR Acetals
pp. 1
Reactions of Reducing Sugars with Tertiary Alkanethiols in 90% Trifluoroacetic Acid
pp. 1
Synthesis from 3,4,6-Tri--acetyl-2--(alkoxycarbonyl)-α-D-glucopyranosyl Bromides
pp. 1
From Ortho Esters
pp. 1
Synthesis of Product Subclass 2
pp. 1
From Reactions of Phenols and 1,3-Diketones with Aldehydes
pp. 1
α-Halo Sulfoxides by the Halogenation of Alkyl Sulfoxides
pp. 1
O-Acetylation of 1-Hydroxy Pyranoses
pp. 1
From Methylenedioxolanes
pp. 1
Synthesis from Carboxylic Acids
pp. 1
From Hal/SeR Acetals
pp. 1
Enyne Cross Metathesis
pp. 1
Cleavage of 1,2--Methylene Pyranoses
pp. 1
Cleavage To Give 1,4-Diols
pp. 1
Acetylation of 1--Nitro Glycosides
pp. 1
[4+1]-Cycloaddition Reactions
pp. 1
Formation of O/O Acetals
pp. 1
α-Halo Sulfides by Addition to Alkenes
pp. 1
Reactions with Carbanion Nucleophiles
pp. 1
Addition of Alkoxy(chloro)carbenes to Alkenes
pp. 1
Aromatic Anion Addition
pp. 1
Synthesis of Product Subclass 1
pp. 1
Synthesis from Compounds of Lower Oxidation State
pp. 1
Cleavage of α-Acyloxy Ethers with Bromotrimethylsilane
pp. 1
Applications of Product Subclass 4 in Organic Synthesis
pp. 1
From O/S Acetals
pp. 1
Metalation of OR/SeR Acetals
pp. 1
Synthesis of Product Subclass 3
pp. 1
Synthesis of Product Subclass 4
pp. 1
From Reactions of 1,3-Diols with Acetals or Ketals
pp. 1
From 3-Hydroxy Hal/O Acetals
pp. 1
Reactions of -Glycosylphosphine Oxides Generated In Situ
pp. 1
Oxazolidine -Oxide Cycloaddition Reactions
pp. 1
Using Metal–Carbene Complexes
pp. 1
Fluorination of Alkanes
pp. 1
Bromodecarboxylation of α-Fluorocarboxylic Acid Derivatives
pp. 1
Metal-Catalyzed Cross Coupling
pp. 1
Synthesis from Alkanes
pp. 1
By Fluorination of Diazo Compounds
pp. 1
OH/SOR Acetals
pp. 1
Formation of 1-Cyano Pyranoses
pp. 1
Cleavage of O/S Acetals
pp. 1
Formation of the S/Se—Aglycone Bond by Substitution of Carbon
pp. 1
Cl/O Acetals
pp. 1
Synthesis of Product Subclass 4
pp. 1
Synthesis by Formation of Two C—O Bonds
pp. 1
From Allenyl Ethers and Alcohols
pp. 1
α-Dichlorination of Ketones
pp. 1
Synthesis by Formation of One C—C Bond
pp. 1
Applications of Product Subclass 6 in Organic Synthesis
pp. 1
α-Lithiated Hydrazones as Enolate Equivalents
pp. 1
Synthesis from Selenoxides by Seleno-Pummerer-Type Reaction
pp. 1
Reactions of 1-Azido Pyranoses with Allyl Alcohol
pp. 1
Synthesis of Product Class 9
pp. 1
Deprotonation and Halogenation α to Phosphorus
pp. 1
Synthesis from Enolates and Related Compounds
pp. 1
Addition of Nucleophilic Nitrogen to 1,1-Dihaloalkanes
pp. 1
Addition of Acyl Halides
pp. 1
From Reactions of 1,4-Diols with 1,1-Dihaloalkanes
pp. 1
Oxidation of Thioglycosides and Selenoglycosides
pp. 1
Transglycosidation
pp. 1
Fragmentation and Iodination of a 2-Deoxy-2-fluoro Carbohydrate Derivative
pp. 1
Halogenation of Enamines
pp. 1
Synthesis from Hal/Hal, Hal/O, Hal/S, O/O, S/S, or O/S Acetals
pp. 1
Using α,β-Unsaturated Sulfoxides
pp. 1
α-Halo Sulfides by α-Halogenation of Sulfides
pp. 1
Oxidation of Thioglycosides with Chloramine-T
pp. 1
Synthesis of Product Subclass 5
pp. 1
Synthesis by Cycloaddition Reactions
pp. 1
Synthesis from Organometallic Compounds
pp. 1
Formation of α-Alkoxy Nitrogen Compounds
pp. 1
Applications of Product Subclass 3 in Organic Synthesis
pp. 1
α-Halo Sulfones by the α-Oxidation of Halo Sulfides
pp. 1
Nucleophilic Addition to Epoxides
pp. 1
Deprotection to Monoprotected Diols
pp. 1
Bromination of Hydrazones
pp. 1
From Haloalkenes and Alcohols
pp. 1
Fluorodesulfurization of Thioketones, Dithioacetals, or Dithioketals
pp. 1
Br/O Acetals
pp. 1
Addition of Diazoalkanes to Vinyl Halides
pp. 1
By Double Michael Addition of 1,2-Diols to Electron-Deficient Alkynes
pp. 1
Miscellaneous Methods
pp. 1
Applications of Product Subclass 3 in Organic Synthesis
pp. 1
Synthesis of Product Subclass 5
pp. 1
Intermolecular Radical Reactions
pp. 1
Applications of Product Subclass 1 in Organic Synthesis
pp. 1
Formation of the S—H Bond by Substitution of Metals
pp. 1
Applications of Product Subclass 8 in Organic Synthesis
pp. 1
Synthesis of Product Subclass 2
pp. 1
Nucleophilic Substitution with Iodide Ions
pp. 1
Oxidation of Selenides
pp. 1
From OR/OR Acetals
pp. 1
Synthesis of Trioxadispiroketals
pp. 1
Haloetherification
pp. 1
Preparation of α-Haloazo Compounds
pp. 1
Reactions of 1-Halo Pyranoses with Allyl Alcohol
pp. 1
Br/Br Acetals
pp. 1
Synthesis of Product Subclass 1
pp. 1
Lewis Acid Catalyzed Alkylations of Unsaturated Derivatives
pp. 1
Formation of the Glycosyl—Sulfur/Selenium Bond by Substitution of Halides
pp. 1
Synthesis from Compounds of the Same Oxidation State
pp. 1
α-Halosulfenyl Halides by Addition to Disulfides
pp. 1
Reagents Derived from α-Chloro Sulfides
pp. 1
Using Phosphorus-Stabilized Carbanions
pp. 1
Using Acetyl Bromide
pp. 1
Substitution Reactions Using the Oxyvinyl Unit as a Leaving Group
pp. 1
α-Fluoro Carbonyl Compounds by Isomerization of 2-Fluorooxiranes
pp. 1
From Alcohols
pp. 1
By Cyclization of Hydroxy-Substituted Enol Ethers
pp. 1
From Cyclic Enol Ethers and Alcohols
pp. 1
Chlorination of the Carbonyl Group
pp. 1
Transetherification and Related Reactions
pp. 1
Reactions of Sulfenyl/Selenenyl Halides with Thiols/Thiolates
pp. 1
Air Oxidation of Thiols, Selenols, and Tellurols
pp. 1
α-Halo Selenides by Halogenation of Selenium/Chalcogen Acetals
pp. 1
Applications of Product Subclass 4 in Organic Synthesis
pp. 1
Radical Halogenation of Amides and Related Compounds
pp. 1
Synthesis of Product Subclass 1
pp. 1
From Reactions of Carbonyl Compounds with 1,3-Diol Bis(silyl ethers)
pp. 1
Addition of Aromatic Heterocyclic Nitrogen to Aldehydes
pp. 1
Alkene Formation
pp. 1
From Reactions of Diazoalkanes with Diols
pp. 1
Synthesis of Product Subclass 2
pp. 1
Transformation of Epoxy Alcohols into α-Fluoro Ethers
pp. 1
Synthesis of Product Subclass 10
pp. 1
From Alcohols with Removal of Water by Chemical Means
pp. 1
Of Alkenes
pp. 1
Larger-Ring O/O Acetals
pp. 1
Enolate Addition
pp. 1
Using Acid Chlorides
pp. 1
Intramolecular Conjugate Addition
pp. 1
1,3-Dioxetanes
pp. 1
Formation of the Glycosyl—S Bond by Substitution of Oxygen
pp. 1
Use as a N—O Protecting Group
pp. 1
From Reactions of Enol Ethers with Diols
pp. 1
Formation of α-Lithio Ethers
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