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Organophosphorus Compounds (incl. RO-P and RN-P)
Free Phosphinidenes
other
Author(s):
J. C. Slootweg
,
K. Lammertsma
Publication date
(Online):
2009
Publisher:
Georg Thieme Verlag KG
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Book Chapter
Publication date (Print):
2009
Publication date (Online):
2009
Page
: 1
DOI:
10.1055/sos-SD-042-00003
SO-VID:
ae2aa4ea-bfee-41d4-a323-31950bd32900
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Book chapters
pp. 1
Phosphorous Acid Monoester Dihalides
pp. 1
Sugar Nucleoside Diphosphates via a Reactive Zwitterionic Phosphoramidate Intermediate
pp. 1
Halogenation of Bis(fluoroalkyl) Phosphites
pp. 1
By Reaction with Methanol
pp. 1
Phosphorodithious Acid Diester Monohalides
pp. 1
Ligand-Exchange Reactions of Phosphorous Acid Derivatives
pp. 1
Isomerization of Dialkylphosphinites
pp. 1
Reduction of Dialkylphosphine Oxides, Dialkylphosphinates, or Alkylphosphinates with Silanes
pp. 1
Sulfurization of Trialkyl Phosphites
pp. 1
Synthesis of Product Subclass 2
pp. 1
Synthesis from Metal Organophosphides and Esters
pp. 1
Alcoholysis of Alkylphosphonites
pp. 1
Halogenation of Alkylphosphinates
pp. 1
Coupling of Dialkylphosphine Derivatives
pp. 1
Modification of Heterophosphonium Salts
pp. 1
Synthesis of Product Subclass 5
pp. 1
Direct Synthesis from Phosphorus Pentachloride
pp. 1
Phosphate Esterification Promoted by Silver(I) Oxide
pp. 1
Transformation of Phosphonium Salts with Anionic Sulfur Nucleophiles
pp. 1
From Phosphorous Triamides
pp. 1
Hydrolysis of Alkylphosphonic Acid Esters
pp. 1
From Phosphaalkenes or Phosphacumulenes and Carbenes or Carbenoids
pp. 1
Partial Aminolysis of Alkyl(dihalo)phosphines
pp. 1
Catalytic Reaction of Diphenyl Diselenide and Tributylphosphine under Microwave Irradiation
pp. 1
Reaction of Unsaturated Precursors
pp. 1
Ring Opening of a 5′-(1-Sulfidocyclotriphosphate) with Lithium Sulfide
pp. 1
Enzymatic Phosphorylation
pp. 1
Oxidation Reactions
pp. 1
Alkylation of Bis(trimethylsilyl) Phosphonite
pp. 1
Synthesis via 1,3,2-Oxathiaphospholane 2-Selenides
pp. 1
The Aza-Morita–Baylis–Hillman Reaction
pp. 1
Fluorination of P—N Imidazole Derivatives
pp. 1
Synthesis from Primary Alkylphosphines and Disulfides
pp. 1
Treatment with Trifluoroacetic Anhydride
pp. 1
Reactions of Phosphenium Cations with Unsaturated Hydrocarbons
pp. 1
Alkylphosphonic Acids from Alkylphosphonic Acid Esters
pp. 1
,-Dialkyl/,-Diaryl Hydrogen Phosphorothioates
pp. 1
Oxidation or Sulfuration of Dialkylphosphinous Anhydrides
pp. 1
Reaction of Alkylphosphonic Dihalides with Alcohols
pp. 1
Addition of Dialkylphosphine Oxides to Ketones or Aldehydes
pp. 1
Synthesis from Phosphorous Acid Monoester Dihalides by P—C Bond Formation
pp. 1
Halogenation of Tetraalkyldiphosphine Disulfides
pp. 1
Alkylphosphonic Dihalides from Alkylphosphonic Acids and Their Derivatives
pp. 1
Addition of Phosphines to Aldehydes or Ketones
pp. 1
From Phosphine and Alkyl Halides
pp. 1
Cyclization onto Phosphorus
pp. 1
Synthesis of Product Subclass 1
pp. 1
Dehydrohalogenation/Ligation
pp. 1
Reaction of Alkyl/Aryl Alkylphosphonohalidodithioates with Alcohols
pp. 1
5′-Phosphorylation of Solid-Supported Oligonucleotides by -Butyl 2-Cyanoethyl Diisopropylphosphoramidite
pp. 1
Heteroatom-Substituted Diphosphenes
pp. 1
Reaction of Dialkyl Amidophosphites with Alkyl Halides
pp. 1
Silylation of Alcohols
pp. 1
Phosphoramidite [P(O,O,N)] Ligands
pp. 1
Reactions with Other Halogenating Reagents
pp. 1
Aminolysis of Phosphorous Acid Derivatives
pp. 1
Catalysis with Polymer-Supported Phosphines
pp. 1
Reaction of Ylides with Miscellaneous Electrophiles
pp. 1
Diaryl Ether Synthesis
pp. 1
Synthesis of Product Subclass 10
pp. 1
Applications of Product Subclass 3 in Organic Synthesis
pp. 1
Preparation of Dialkylphosphinoselenothioic -Acids
pp. 1
Reductive Cleavage of Quaternary Phosphonium Salts
pp. 1
Selection of Enantiotopic Faces of an Achiral Alkenic Substrate
pp. 1
Reaction of Dialkylphosphinic Halides with Thiols
pp. 1
Dialkylphosphinous Acid Esters
pp. 1
Formation of Alkenylphosphorus Compounds
pp. 1
Other Syntheses from Phosphorous Acid Derivatives
pp. 1
By Reaction with a Ketone
pp. 1
Electrochemical Fluorination of Secondary Phosphines
pp. 1
Synthesis from Tetracoordinate Phosphorus Compounds
pp. 1
P-Alkylation of Primary Phosphines
pp. 1
Dialkyl Dihydrogen Diphosphates
pp. 1
From Dichlorophosphines or Phosphinic Acid ,-Diesters and α,ω-Di-Grignard or Dilithium Reagents
pp. 1
Synthesis of Product Class 18
pp. 1
Reaction of -Alkyl/Aryl Alkylphosphonothioic Acids with Carbodiimides
pp. 1
Halogenation of Dialkylphosphinothioic Amides and -Amino Derivatives of Dialkylphosphinodithioic Acids
pp. 1
Phospholane-Based Chiral Ligands
pp. 1
Synthesis of Product Subclass 2
pp. 1
Reactions of Chlorophosphine Oxides with Grignard Reagents
pp. 1
Nucleophilic Phosphinidene Complexes
pp. 1
Oxidative Cleavage of Tetraalkyldiphosphine Disulfides
pp. 1
Synthesis of Product Subclass 7
pp. 1
Addition/Elimination
pp. 1
Synthesis of Product Subclass 21
pp. 1
Oxidation of Primary Alkylphosphines
pp. 1
,,-Trialkyl Phosphoroselenoates
pp. 1
Anionic Hexacoordinated Phosphorus Derivatives with P—O and P—C Bonds
pp. 1
Applications of Product Subclass 1 in Organic Synthesis
pp. 1
Synthesis of Product Subclass 4
pp. 1
Elimination and/or Condensation Reactions
pp. 1
Reaction of -Alkyl/Aryl Alkylphosphonohalidothioates with Amines
pp. 1
Rhodium-Promoted Hydrogenation of Alkenes
pp. 1
Conversion of Trialkylphosphine Ylides into Trialkylphosphine Oxides
pp. 1
Thioxophosphines and Selenoxophosphines
pp. 1
Addition of Phosphine and Primary Phosphines to 1,4-Dien-3-ones
pp. 1
Formation of C—O Bonds
pp. 1
Redox Reaction of a Phosphite with Tellurium Tetrachloride
pp. 1
Reaction of Phosphorus Trihalides with Aliphatic Hydrocarbons
pp. 1
Tetraalkyl/Tetraaryl Diphosphates
pp. 1
Alkylation of -Carbonylphosphines with Alkyl Halides or Sulfonates
pp. 1
Anhydrides of Dialkylphosphinic Acids and Their Sulfur and Selenium Analogues
pp. 1
Oxidation of -Alkylphosphonous Diamides
pp. 1
Of Transition Metal Phosphides
pp. 1
Oxidation of -Alkyl Hydrogen Phosphonodithioates
pp. 1
Thiophosphorylation and Subsequent Reaction with Pyrophosphate
pp. 1
Synthesis of Product Subclass 14
pp. 1
Phospha-Wittig Reagents
pp. 1
Condensation of Dialkylphosphinic Acid Esters with Dialkylphosphinic Halides and Their Sulfur Analogues
pp. 1
Hydrolysis of -Alkyl Alkylphosphonochloridothioates
pp. 1
Phosphinopyridine and Phosphinoquinoline Ligands
pp. 1
Reduction Reactions
pp. 1
Hydrolysis of 1-Aryl-1-[(4-tolylsulfinyl)amino]methylbis(diethylamino)phosphine–Boranes
pp. 1
Addition to Tetracoordinated Phosphorus Compounds
pp. 1
Elimination
pp. 1
Ring Opening of Tetrahydrofuran
pp. 1
Reaction of Proazaphosphatranes with Bis(trimethylsilyl) Peroxide
pp. 1
Synthesis of Product Subclass 15
pp. 1
Reduction with Sodium Bis(2-methoxyethoxy)aluminum Hydride
pp. 1
,,-Trialkyl/,,-Triaryl Phosphoroselenoates
pp. 1
Phosphorothious Acid -Monoesters
pp. 1
Synthesis of Product Subclass 14
pp. 1
Phosphino-4,5-dihydrooxazole Ligands
pp. 1
Phosphorylation of an -Alkyl Phosphorothioate
pp. 1
Synthesis from Poly(dialkylphosphino)methanides and Dialkylhalophosphines
pp. 1
Reaction of an Azide with a Trialkylphosphine (The Staudinger Reaction)
pp. 1
Enantioselective C—H Bond-Forming Reactions
pp. 1
Addition of Phosphonodithioyl and Phosphonotrithioyl Radicals to Alkenes
pp. 1
Oxidative Coupling of (Dialkylphosphino)methanides
pp. 1
Conjugate Addition Reactions
pp. 1
Self-Condensation of Dialkylphosphinic Halides and Their Sulfur Analogues
pp. 1
Reaction of -(Alkylsulfanyl)phthalimides with Phosphinates in the Presence of Hexamethyldisilazane
pp. 1
Selective Hydrolysis of Triesters of Phosphoric Acid
pp. 1
Synthesis of Product Subclass 17
pp. 1
Transamination of -Alkylphosphonic Diamides
pp. 1
Addition of Dialkylphosphine Oxides to Imines
pp. 1
Hydrophosphination of Alkenes and Alkynes
pp. 1
Applications of Product Subclass 3 in Organic Synthesis
pp. 1
Polyphosphonium Salts
pp. 1
Reaction of Tetraalkyldiphosphine Disulfides or Phosphine Sulfides
pp. 1
Synthesis by Nucleophilic Substitution
pp. 1
Synthesis via a Reactive Pyrrolidinium Phosphoramidate Zwitterion Intermediate
pp. 1
Alkylation of -Alkyl Alkylphosphinothioates
pp. 1
Metal-Promoted Catalysis with Polymer-Supported Phosphines
pp. 1
Intramolecular Morita–Baylis–Hillman Allylic Alkylation
pp. 1
-Alkyl Tetrahydrogen 1,1-Dithiotriphosphates
pp. 1
Insertion into P—P Bonds
pp. 1
Addition of O- and N-Nucleophiles to Alkynes
pp. 1
Synthesis via 2-Sulfido-1,3,2-Dithiaphospholanes
pp. 1
Synthesis of Product Subclass 24
pp. 1
Recursive Synthesis from a Phosphine
pp. 1
Alkylthiophosphonous Acid Monohalide Monoesters
pp. 1
Synthesis from Dialkylhalophosphines and Dimetalated Alkanes, Alkenes, or Alkynes
pp. 1
Reduction of Trialkylphosphine Oxides with Lithium Aluminum Hydride
pp. 1
P=S Phosphorothioates
pp. 1
Trialkyl/Triaryl Phosphates
pp. 1
Dialkylphosphinic Halides
pp. 1
Formation of C—P Bonds
pp. 1
Dealkylation of Dialkyl Methylphosphonates with Diphenylguanidine
pp. 1
From 2-Chloro-1,3,2-dithiaphospholane
pp. 1
Thioalcoholysis of Alkyl(dihalo)phosphines
pp. 1
Reaction of Phosphorodichloridates with Alkane- or Arenethiols
pp. 1
Phosphorylation
pp. 1
Phosphorylation of 5′-Tosyl Nucleosides
pp. 1
Reaction of Alkylphosphonic Dihalides with Thiols
pp. 1
Rearrangement of Allyl Dialkylphosphoramidochloridites
pp. 1
Alkylation of (β-Hydroxyalkyl)phosphines or Derivatives
pp. 1
Sulfurization of Alkyl Phosphonothioates
pp. 1
Sulfuration of Aminophosphines
pp. 1
Reduction of Bis(dialkylphosphoryl)alkanes with Lithium Aluminum Hydride
pp. 1
Ligand Exchange of Alkyl(dihalo)phosphines
pp. 1
Applications of Product Subclass 2 in Organic Synthesis
pp. 1
From Dichlorophosphines, Alkenes, and Organometallic Reagents
pp. 1
Applications of Product Subclass 25 in Organic Synthesis
pp. 1
Hydrolysis of Phosphorous Acid Derivatives
pp. 1
Alcoholysis of Phosphorous Acid Derivatives
pp. 1
Reaction of Electrophiles with Tetracoordinate Phosphorus Derivatives
pp. 1
Metal-Catalyzed Addition of Organometallic Reagents to Unactivated Alkenes
pp. 1
Reaction of Phosphines with α,β-Unsaturated Carbonyl Species
pp. 1
Alkylation of Phosphines with Bis(sulfanyl)- or Bis(selanyl) Alkyl Halides, or Cationic Derivatives
pp. 1
Reaction of Alkylphosphonic Acids with Carbodiimides
pp. 1
Solid-Phase Synthesis of Symmetrical Nucleoside Phosphodiesters
pp. 1
Alkyl/Aryl Alkylphosphonohalidates
pp. 1
Alcoholysis of Monothiophosphonic Anhydrides
pp. 1
Oxidation with Sulfur(VI) Oxides
pp. 1
Phosphorothious Acid Triesters
pp. 1
Synthesis of α-Sulfanyl and α-Selanylphosphonium Salts and Derivatives
pp. 1
From Chlorophosphines and Other Organometallic Reagents
pp. 1
Base-Induced Ionization
pp. 1
Sulfurization with 1,1′,1′′,1′′′-[Disulfanediylbis(carbonothioylnitrilo)]tetraethane
pp. 1
Synthesis from Phosphorous Acid Derivatives by P—C Bond Formation
pp. 1
Phosphorous Acid Diester Monohalides
pp. 1
Phosphorodithious Acid -Monoesters
pp. 1
Approaches to Chiral Cyclic Phosphines
pp. 1
Oxathiaphospholane Approach for the Synthesis of Nucleoside Methylphosphonothioic Acids
pp. 1
Nucleophilic Addition of Phosphines or Derivatives to Alkenes or Alkynes
pp. 1
Synthesis of Product Subclass 7
pp. 1
Anionic Hexacoordinated Phosphorus Derivatives with P—O Bonds Only
pp. 1
Alkylation of Phosphines with α-(Halomethyl)carbonyl Species
pp. 1
Synthesis from Metal Dialkylphosphides and Aliphatic Electrophiles
pp. 1
Formation of C—S Bonds
pp. 1
Synthesis from Dialkylphosphides or Dialkylphosphines and Dialkylhalophosphines
pp. 1
Synthesis of Product Subclass 1
pp. 1
Selective Monodebenzylation of Dibenzyl Phosphonates with Tertiary Amines
pp. 1
Solid-Phase Synthesis of Nucleoside β-Triphosphates
pp. 1
Catalysis with Phosphonium Salts as Ligand Precursors
pp. 1
Phosphinidene-Transfer Reactions
pp. 1
Linear and Cyclic Organophosphazenes
pp. 1
Applications of Product Subclass 15 in Organic Synthesis
pp. 1
Addition of Elemental Tellurium to Trialkylphosphines
pp. 1
1,3-Diphosphetanes
pp. 1
Synthesis of Product Subclass 1
pp. 1
,-Dialkyl/Diaryl Alkylphosphonothioates and Their Sulfur and Selenium Derivatives
pp. 1
,,-Trialkyl/,,-Triaryl Phosphorodithioates
pp. 1
Phosphetanes
pp. 1
Alcoholysis of Alkyl(alkylsulfanyl)(halo)phosphines
pp. 1
Synthesis of Product Subclass 16
pp. 1
Alcoholysis of Dialkylphosphinous Acid Derivatives
pp. 1
Halogenation of Dialkylphosphines and Dialkylphosphinites
pp. 1
-Alkyl/Aryl Alkylphosphonohalidothioates and Sulfur Derivatives
pp. 1
Phosphorodithious Acid ,-Diesters
pp. 1
Metal-Catalyzed Allylic Alkylation (Tsuji–Trost Reaction)
pp. 1
Addition of Selenium to Dialkylhalophosphines
pp. 1
Synthesis from Tetrakis(hydroxymethyl)phosphonium Halides
pp. 1
Synthesis of Product Subclass 11
pp. 1
Preparation of Dialkylphosphinodithioic Acids
pp. 1
Ligand Exchange in Dialkylphosphinous Acid Derivatives
pp. 1
-Alkylphosphonamidic Halides and Their Sulfur and Selenium Derivatives
pp. 1
Triphenylphosphine and Di-2-pyridyl Disulfide as Coupling Agents in One-Pot Syntheses of Symmetrical Dinucleoside 5′,5′′-Pyrophosphates
pp. 1
Hydroxyphosphonium Salts
pp. 1
Alcoholysis of Alkylphosphines
pp. 1
Formation of an Alkynyl—Sulfur Bond
pp. 1
Synthesis of Product Subclass 3
pp. 1
Applications of Product Subclass 1 in Organic Synthesis
pp. 1
Synthesis from a Bis(1-imidazol-1-yl)phosphinothioate
pp. 1
Intramolecular Cyclization of Tertiary Phosphines
pp. 1
Synthesis of -Ethylphosphonamidothioic Acids
pp. 1
Phosphorous Acid Monoester Monoamide Monohalides
pp. 1
Synthesis of β,γ-Methylene Deoxynucleoside Triphosphate Analogues via Morpholidates
pp. 1
,-Dialkyl Phosphoroselenoates
pp. 1
Dialkylphosphinoselenoic Halides
pp. 1
S-Alkylation of Phosphorothioic Acid
pp. 1
Synthesis from Phosphonium Salts
pp. 1
Treatment with Phosgene
pp. 1
Reaction of Triethylphosphine with a (Phosphonio)(phosphoranylidene)methanethiolate
pp. 1
Phosphorylation of Activated 5′-Nucleoside Monophosphates
pp. 1
Thiophosphorylation of 4-Toluenesulfonates or Bromides
pp. 1
Phosphorylation with Diphenyl Phosphorochloridate
pp. 1
Synthesis from Dialkylphosphines
pp. 1
Alkylation of Phosphines
pp. 1
Synthesis of Product Subclass 15
pp. 1
Formation of an Alkenyl—Sulfur Bond
pp. 1
Synthesis of Product Subclass 2
pp. 1
Trost Ligands
pp. 1
Reaction of Phosphines with Heteroatomic Electrophiles
pp. 1
Reaction of Alkylphosphonothioic Dihalides with Amino Alcohols
pp. 1
7-Phosphanorbornenes from [4+2] Cycloaddition of Phosphole Derivatives with Dienophiles
pp. 1
Sulfurization with Dibenzoyl Tetrasulfide
pp. 1
Applications of Product Subclass 13 in Organic Synthesis
pp. 1
Synthesis via Phosphoramidites
pp. 1
Alkylphosphonous Acid Monoester Monoamides
pp. 1
Synthesis of Product Subclass 4
pp. 1
Addition of Selenium to Alkyldihalophosphines
pp. 1
Hydrogenation of Tertiary Arylphosphine Oxides
pp. 1
Synthesis of Product Subclass 16
pp. 1
Acylation and Kinetic Resolution of Alcohols
pp. 1
Reaction with α,β-Unsaturated Carbonyl Compounds
pp. 1
Cheletropic Elimination
pp. 1
Reaction of Alkylphosphonothioic Dihalides with Alcoholates
pp. 1
Insertion Reactions
pp. 1
Applications of Product Subclass 3 in Organic Synthesis
pp. 1
Dehydrative Condensation
pp. 1
Phosphoramidites as Phosphorylating Agents
pp. 1
Interconversion of Alkylpolyphosphines
pp. 1
Synthesis of Product Subclass 12
pp. 1
,,,-Tetraalkyl/,,,-Tetraaryl Thiodiphosphates
pp. 1
Applications of Product Subclass 8 in Organic Synthesis
pp. 1
Hydrophosphination of Alkynes
pp. 1
Alkylation of Alkyl Alkylphosphinates
pp. 1
Reaction of Proazaphosphatranes with Sulfur
pp. 1
Oxidation of Phosphonium Salts
pp. 1
Stereodefined Diphosphenes
pp. 1
Reaction of Phosphines with 1,1,2-Trimethyldisulfanium or 1-Methyl-1,2-diphenyldisulfanium Salts
pp. 1
Hydrolysis of Alkyl(alkylsulfanyl)(halo)phosphines
pp. 1
Synthesis from Diamino(halo)phosphines
pp. 1
Synthesis of Alkylphosphonoselenoic Dihalides
pp. 1
Reduction
pp. 1
Photolytic Generation
pp. 1
Reaction of Dialkylphosphinothioic Halides with Alcohols or Phenols
pp. 1
From 7-Phosphanorbornadienes
pp. 1
Applications of Product Subclass 1 in Organic Synthesis
pp. 1
Addition of Tricoordinated Organophosphorus Derivatives to Unsaturated Systems
pp. 1
Synthesis of Product Class 3
pp. 1
Alkylation Reactions of Tri- and Tetracoordinated Phosphorus-Containing Precursors
pp. 1
-Alkylphosphonic Diamides and Their Sulfur and Selenium Derivatives
pp. 1
Catalysis with Polyether Phosphines
pp. 1
Coupling Reactions
pp. 1
Synthesis from Dialkylphosphides or Dialkylphosphines and Polyhaloalkanes
pp. 1
Sulfurization of Tricoordinated Alkylphosphonous Acid Diesters
pp. 1
Reaction of Alkylphosphonic Dihalides with Alcohols and Thiols, or Sulfanyl Alcohols
pp. 1
Thioalcoholysis of Phosphorous Acid Derivatives
pp. 1
Schwesinger Bases
pp. 1
Reactions of Alkyl/Aryl Alkylphosphonohalidates and ,,-Trialkylphosphonamidic Halides
pp. 1
Synthesis of Product Subclass 4
pp. 1
Synthesis of β,γ-Methylene Nucleoside Triphosphate Analogues through Activation by Trihaloacetic Anhydrides and 1-Methylimidazole
pp. 1
Applications of Product Subclass 13 in Organic Synthesis
pp. 1
Synthesis of γ-Hydroxyphosphonium Salts and Derivatives
pp. 1
Sulfurization with Lawesson's Reagent
pp. 1
Base-Promoted Addition
pp. 1
Trialkylphosphine Tellurides
pp. 1
Intramolecular Amination Reactions
pp. 1
Alkylphosphonic Dihalides by Miscellaneous Procedures
pp. 1
Synthesis of Product Subclass 30
pp. 1
Palladium-Promoted Cross-Coupling Reactions
pp. 1
Successive Alkylation of Phosphines, Phosphides, or Polyphosphines
pp. 1
Sulfurization with 3-1,2-Benzodithiol-3-one 1,1-Dioxide (Beaucage's Reagent)
pp. 1
Formation of Alkylphosphorus Compounds
pp. 1
Oxidation/Deprotonation
pp. 1
Sulfurization with Phenylacetyl Disulfide
pp. 1
Reaction of Alkylphosphonic Dihalides with Alcohols or Phenols
pp. 1
Alcoholysis of Quaternary Phosphonium Salts
pp. 1
Oxidation of ,-Dialkyl -Phosphonates with Triphenylphosphine Selenide
pp. 1
Chloride Abstraction
pp. 1
Oxophosphines
pp. 1
Reduction of Trialkylphosphine Sulfides and P-Chiral Phosphine–Borane Complexes Bearing an Alkylsulfanyl Group
pp. 1
Reaction of Phosphines with Various Carbonyl Electrophiles
pp. 1
Catalysis with Carbohydrate-Derived Phosphines
pp. 1
Using 1,3-Symmetrically Substituted Allylic Ligands
pp. 1
Reaction of Elemental Phosphorus with Benzenethiol
pp. 1
Oxygenation of Trialkylphosphine Sulfides
pp. 1
Synthesis of Product Subclass 25
pp. 1
Synthesis of Alkylphosphonothioic Acids
pp. 1
Selection of Enantiotopic C=C Bonds of an Achiral Substrate
pp. 1
Dialkylphosphinothioic -Acids and Their Sulfur and Selenium Analogues
pp. 1
Enantioselective C—C Bond-Forming Reactions
pp. 1
Addition of an Iodonium Ylide to Tributylphosphine
pp. 1
Using 1,3-Dissymmetrically Disubstituted Allylic Substrates
pp. 1
Of Metal Hydrides
pp. 1
Esterification of Dialkylphosphinic Acids and Transesterification of Alkyl Dialkylphosphinates
pp. 1
Reaction with α-Diketones
pp. 1
Mannich-Type Reactions of Phosphines, Formaldehyde, and Amines
pp. 1
Alkyl/Aryl Dialkylphosphinates
pp. 1
Hydrophosphination of Double Bonds
pp. 1
Synthesis of Product Subclass 7
pp. 1
Disproportionation of Dialkylphosphine Oxides
pp. 1
-Alkyl Tetrahydrogen Thiotriphosphates
pp. 1
Phosphorous Acid Monoester Monohalides
pp. 1
Hydrolysis of Tetra- and Pentacoordinated Phosphorus-Containing Precursors
pp. 1
Trapping Reactions
pp. 1
From Phosphites
pp. 1
Synthesis of Multiphosphonium Salts
pp. 1
Synthesis of Product Subclass 11
pp. 1
Synthesis from Sulfidodithiaphospholanes
pp. 1
Modification of Phosphonium Salts by Reaction of Ylides
pp. 1
Synthesis of Product Subclass 17
pp. 1
Oxygenation of Trialkylphosphine Imides
pp. 1
Applications of Product Subclass 2 in Organic Synthesis
pp. 1
Reaction of Phosphaalkenes
pp. 1
Reaction of Dialkylphosphinothioic Halides with Amines
pp. 1
Alkylation of Phosphines with Sulfur- or Selenium-Substituted Alkyl Halides or Related Compounds
pp. 1
Alkylation of Tertiary Phosphines Using Alcohols or Derivatives
pp. 1
Reaction of Tetraalkyldiphosphine Disulfides with Disulfides and Diselenides
pp. 1
Applications of Product Subclass 30 in Organic Synthesis
pp. 1
Synthesis of Product Subclass 5
pp. 1
-Alkylphosphonamidic Acids and Their Sulfur and Selenium Derivatives
pp. 1
Synthesis of β-Hydroxyphosphonium Salts and Derivatives
pp. 1
Alkylation of Dialkylphosphinodithioic Acids or Their Salts
pp. 1
Synthesis of Product Subclass 19
pp. 1
Thioalcoholysis of Phosphorus Trihalides
pp. 1
Synthesis from Alkyl(alkoxy)(halo)phosphines
pp. 1
Heterophosphonium Salts
pp. 1
Hydrolysis of ,-Dialkylphosphinic Amides
pp. 1
-Alkyl/-Aryl Phosphorodihalidothioates
pp. 1
Nucleophilic Interception at the α-Position
pp. 1
The Ludwig–Eckstein Procedure
pp. 1
Interconversion of Poly(alkylphosphino)alkanes
pp. 1
Approaches to Ligands Bearing P—O and P—N Bonds
pp. 1
Miscellaneous Methods
pp. 1
Sulfuration of Alkylphosphonic Dihalides
pp. 1
Reaction of Phosphites with Sulfur Dichloride
pp. 1
Reaction of Alkylphosphonic Acids and Their Sulfur Analogues with Carbodiimides
pp. 1
Dialkylphosphinous Acids
pp. 1
Amination of Aryl and Hetaryl Halides or Trifluoromethanesulfonates
pp. 1
Phosphorothious Acid Diester Monohalides
pp. 1
Synthesis of Product Subclass 5
pp. 1
Phosphinite–4,5-Dihydrooxazole Ligands
pp. 1
Applications of Product Subclass 5 in Organic Synthesis
pp. 1
Ring Opening of 1-Functionalized Aziridines with Alkylphosphonic Dihalides
pp. 1
Phosphiranes
pp. 1
Reaction of Dialkylphosphinoselenoic Halides with Alcohols
pp. 1
,-Dialkylphosphinic Amides
pp. 1
Synthesis of -Alkyl Hydrogen Alkylphosphonothioates from Alkylphosphonothioic Dichlorides
pp. 1
Synthesis of Product Subclass 1
pp. 1
Alkyl/Aryl Phosphorohalidates
pp. 1
Transformation of β-Functionalized Phosphonium Salts
pp. 1
Reaction of ,,′,′-Tetraalkylphosphorodiamidic Chlorides with Organometallic Reagents
pp. 1
Catalytic Condensation of Phosphoric Acid with Alcohols
pp. 1
Synthesis of Product Subclass 22
pp. 1
Mixed Anhydrides of Phosphoric Acid and Esters of Phosphoric Acid with Non-Phosphorus-Containing Acids
pp. 1
Sulfurization of Disubstituted Phosphonodithioates
pp. 1
Alkylphosphonous Acid Monoester Monohalides
pp. 1
Dialkyl/Diaryl Hydrogen Phosphates
pp. 1
Addition of Dialkyl Phosphites to Alkenes, Allenes, and Alkynes
pp. 1
Michaelis–Becker Reaction
pp. 1
Oxidative Coupling of Dialkylphosphines by Transition-Metal Complexes
pp. 1
Thioalcoholysis of Alkyl(diamino)phosphines
pp. 1
Reaction of Alkylphosphinic Acids with Alkenes
pp. 1
From ,-Diisopropyl-1,3,2-dithiaphospholan-2-amine
pp. 1
Iridium-Promoted Hydrogenation of Nonfunctionalized Alkenes
pp. 1
Phosphorodithious Acid Diester Monoamides
pp. 1
Reaction of a Diselenide with Elemental Phosphorus
pp. 1
Hydrolysis of Alkyl(halo)phosphines
pp. 1
Synthesis of Product Subclass 1
pp. 1
Reduction of Phosphine Oxides
pp. 1
Reactions of ,,-Trialkylphosphonamidic Halides with Nucleophiles
pp. 1
Reaction of Aminesulfenamides with Alkylphosphonic Dichlorides
pp. 1
Reaction of Aluminum Halide Complexes of Alkyltetrachlorophosphoranes with Alcohols
pp. 1
Acidification of Sodium Dialkylphosphinodiselenoates
pp. 1
Hydrolysis of Alkylphosphonic Dihalides
pp. 1
Phosphorylation of Homoallylic 4-Toluenesulfonates or Allylic Halides
pp. 1
Addition of Base to Aminophosphonium Salts
pp. 1
Intermolecular Cyclization of Tertiary Phosphines
pp. 1
Chlorination of ,-Dialkyl Alkylphosphonothioates
pp. 1
Dialkylthiophosphinous Acids
pp. 1
Synthesis of Product Subclass 12
pp. 1
Synthesis from Bis(halophosphino)alkanes and Organometallic Compounds
pp. 1
Reactions of Dialkylphosphine Oxides with Alkyl Halides
pp. 1
Additions of Dialkyl(chloro)phosphines to Enones
pp. 1
Addition of Phosphines to C—X Multiple Bonds
pp. 1
Reaction of Phosphines with Acetals, Ketals, or Hemiacetals
pp. 1
Synthesis of Product Subclass 2
pp. 1
From Phosphines or Metal Phosphides and 1,2-Dihalides or 1,2-Bis(toluenesulfonates)
pp. 1
,-Dialkylphosphinothioic Amides
pp. 1
Addition of Sulfur to Alkyl Alkylphosphinates
pp. 1
Alkyl Tetrahydrogen Triphosphates
pp. 1
Hydrolysis of Dialkyl Phosphonites and Related Compounds
pp. 1
Reaction of a 1,2,3-Selenadiazole with a Trialkylphosphine
pp. 1
Tandem Phosphorylsilylation/Ireland–Claisen Rearrangement
pp. 1
-Alkyl/Aryl Dialkylphosphinoselenoates
pp. 1
Alkylphosphonous Acid Dihalides
pp. 1
Synthesis from Metal Organophosphides and Alkyl Halides
pp. 1
Consecutive Alcoholysis and Aminolysis of Phosphorus Trihalides
pp. 1
Addition of 1,3-Dipoles to Phosphorus Ylides
pp. 1
Alkylation of Polyphosphide Anions
pp. 1
Alkylation or Protonation of Diphosphenes
pp. 1
Disproportionation of Alkylphosphonous Acids
pp. 1
Phosphetane-Based Chiral Ligands
pp. 1
Reaction of Dialkylphosphinoselenoic Halides with Amines
pp. 1
Reactions of Alkyl/Aryl Alkylphosphonohalidates with Nucleophiles
pp. 1
Applications of Product Subclass 10 in Organic Synthesis
pp. 1
Synthesis from Halophosphines
pp. 1
Oxidation of ,-Dialkyl -Phosphonates with 3-(Phthalimidoselanyl)propanenitrile
pp. 1
Miscellaneous Reactions
pp. 1
Applications of Product Subclass 4 in Organic Synthesis
pp. 1
Dialkylphosphinothioic Halides
pp. 1
Catalysis with Phosphines Bearing Ammonium Groups
pp. 1
Hydrolysis of Dialkylphosphinothioic Halides
pp. 1
Functionalization of Polymeric Backbones
pp. 1
Synthesis of Product Subclass 23
pp. 1
Formation of Alkynylphosphorus Compounds
pp. 1
Reaction of Alkyl Phosphorodiamidothioites with Alkyl Halides
pp. 1
Phosphinite [P(C,C,O)] Ligands
pp. 1
Synthesis of Product Subclass 8
pp. 1
Modification of Phosphonium Salts
pp. 1
Selanylation of Phosphorous Acid Diester Monohalides
pp. 1
P-Alkylation of Phosphines
pp. 1
By Treatment with an Oxidizing Agent
pp. 1
Reaction of Alkyl/Aryl Hydrogen Phosphonates with Alcohols
pp. 1
Chlorination of Phosphites with 1,3,5-Trichloro-1,3,5-triazinane-2,4,6-trione or -Butyl(chloro)cyanamide
pp. 1
Sulfurization of a Bis(trimethylsilyl) Phosphite Ester
pp. 1
The Phosphoramidite Approach
pp. 1
Reaction of -Alkyl/Aryl Alkylphosphonohalidothioates with Alcohols
pp. 1
Sulfurization of Phosphorochloridothioates
pp. 1
Synthesis by Oxidation
pp. 1
Alkylation of Tricoordinate Reagents
pp. 1
Other Protocols
pp. 1
- and -Alkyl/Aryl -Alkylphosphonamidates and Their Sulfur and Selenium Derivatives
pp. 1
Phosphorodithious Acid Triesters
pp. 1
Phosphorothious Acid -Monoester Dihalides
pp. 1
Applications of Product Subclass 4 in Organic Synthesis
pp. 1
Alkylation of Phosphines with β-Hydroxyalkyl Halides or Derivatives
pp. 1
Cycloaddition Reactions
pp. 1
Synthesis of Product Subclass 5
pp. 1
P-Alkylation of Dichlorophosphines
pp. 1
Lewis Acid Catalysis
pp. 1
C-Substitution of Protected Phosphetanes and Subsequent Deprotection
pp. 1
Phosphorylation by Tris(tetrabutylammonium) Hydrogen Pyrophosphate
pp. 1
Synthesis of -Alkyl Hydrogen Alkylphosphonothioates from -Alkyl Alkylphosphonochloridates
pp. 1
Reaction of Phosphonothioic Dihalides with Organometallic Reagents
pp. 1
Reaction of Dialkylhalophosphines with Hydroxylamine Derivatives
pp. 1
Hydrolysis of Dialkylphosphinic Halides
pp. 1
Synthesis of Product Subclass 29
pp. 1
Cycloaddition of Alkyl(dichloro)phosphines with Dienes
pp. 1
Applications of Product Subclass 2 in Organic Synthesis
pp. 1
Addition to Double Bonds
pp. 1
Synthesis of Product Subclass 4
pp. 1
Synthesis of Product Subclass 7
pp. 1
Addition to Alk-1-enes or Cyclic Alkenes
pp. 1
Reaction of Dialkyl Alkylphosphonates with Halogenating Agents
pp. 1
Synthesis of -Carbonylphosphonium Salts and Derivatives
pp. 1
Hydrolysis of Dialkyl/Diaryl Alkylphosphonothioates
pp. 1
Dialkylphosphinous Acid Amides
pp. 1
Nucleophilic Alkylation of Phosphorus Trihalides by Organometallic Reagents
pp. 1
Synthesis from Other Phosphorous Acid Derivatives
pp. 1
Hydrolytic (or Other) Decompositions of Aluminum Halide Complexes of Alkyltetrahalophosphoranes
pp. 1
Alkylphosphonous Acid Diamides
pp. 1
Synthesis from Tricoordinate Phosphorus Compounds
pp. 1
Aminolysis of Alkylphosphonous Acid Derivatives
pp. 1
Michael Addition
pp. 1
Synthesis of β-Sulfanyl- and β-Selanylphosphonium Salts and Derivatives
pp. 1
Hydrolysis of Alkyltetrachlorophosphoranes
pp. 1
Dealkylation of Alkyl Dialkylphosphinates
pp. 1
Solid-Phase Synthesis of ,-Dialkyl Phosphorodithoates
pp. 1
Oxidation of Aminophosphines
pp. 1
Synthesis of Product Subclass 4
pp. 1
Anhydrides of Phosphoric Acid: Nucleoside Triphosphate Analogues
pp. 1
Formation of an Aryl—Sulfur Bond
pp. 1
Addition of Alcohols to Phosphoranes
pp. 1
Synthesis from [(Dialkylphosphino)methyl]silanes or -stannanes and Dialkylhalophosphines
pp. 1
Alkylation of (α-Hydroxyalkyl)phosphines or Derivatives
pp. 1
Hydrolysis of Alkyl/Aryl Alkylphosphonochloridates
pp. 1
Reaction of Dialkyl Alkylphosphonates with Halides of Oxoacids of Phosphorus
pp. 1
Synthesis of α,β-Methylene Deoxynucleoside Triphosphate Analogues by Enzymatic Phosphorylation of the Corresponding α,β-Methylene Deoxynucleoside Diphosphate Analogues
pp. 1
Palladium-Catalyzed Arylation of Alkenes (Heck Reaction)
pp. 1
Alkylation of Phosphines with Sulfur- or Selenium-Containing Alkyl Halides or Sulfonates
pp. 1
Reaction of Halophosphines
pp. 1
Fluorination of ,-Dialkyl Phosphonothioates
pp. 1
Synthesis of Product Subclass 1
pp. 1
Dialkylphosphinoselenoic -Acids and Dialkylphosphinodiselenoic Acids
pp. 1
Metal-Catalyzed 1,4-Addition of Organometallic Reagents to Activated Alkenes
pp. 1
Oxidation of Secondary Dialkylphosphines
pp. 1
Insertion of Tricoordinated Phosphorus
pp. 1
Reaction of Methylenephosphonium Ions
pp. 1
Dealkylation of Dialkyl Phosphonates with Sodium Iodide
pp. 1
Conjugate Addition Reactions
pp. 1
Reaction of Phosphites with α-Halo Ketones
pp. 1
Oxidation of Dialkylphosphine Disulfides
pp. 1
Cationic Electrophilic Phosphinidene Complexes
pp. 1
Synthesis of Product Subclass 8
pp. 1
Sulfurization of Bis(dialkylamino)phosphines
pp. 1
Transesterification Reactions
pp. 1
Synthesis of Product Subclass 3
pp. 1
Tetraphosphenes
pp. 1
Oxidative Conversion of Aminochlorophosphines
pp. 1
Synthesis from H-Phosphonates by Substitution
pp. 1
Hydrolysis of Phosphorous Acid Esters
pp. 1
Oxidation and Fluorination of Thio- and Dithiophosphonates
pp. 1
Oxidation with Hydrogen Peroxide
pp. 1
Addition of Amines to Halophosphoranes
pp. 1
Synthesis from Metal Phosphinomethanides and Electrophiles Containing Phosphino Groups
pp. 1
Alkylation of -Alkyl/Aryl Alkylphosphonothioate Anions
pp. 1
Applications of Product Subclass 12 in Organic Synthesis
pp. 1
Reduction of Alkylphosphonates with Lithium Aluminum Hydride
pp. 1
Addition of Selenium to Alkyl(chloro)(dialkylamino)phosphines
pp. 1
Dealkylation of Dialkyl Alkylphosphonates
pp. 1
Sulfurization of Trialkylphosphine Oxides
pp. 1
Applications of Product Subclass 11 in Organic Synthesis
pp. 1
,-Dialkyl/,-Diaryl Phosphorofluoridothioates
pp. 1
Reductive Coupling of Dialkylhalophosphines by Alkali Metals
pp. 1
Rhodium-Catalyzed Asymmetric 1,4-Addition of Organoboron Reagents
pp. 1
Rhodium-Promoted Hydroformylation of Alkenes
pp. 1
Activation by Conversion into Phosphorodichloridates
pp. 1
Oxidation of ,-Dialkyl Phosphonates with Potassium Selenocyanate
pp. 1
With Alkali Metals
pp. 1
Formation of C—Sn Bonds
pp. 1
Reaction of Vinylphosphonium Salts with Sulfur Dioxide, Thiols, or Associated Anions
pp. 1
Synthesis of Product Subclass 6
pp. 1
Diels–Alder Reaction of Triphenyl(vinyl)phosphonium Salts with 1,4-Dienes
pp. 1
Addition of Phosphines to Polyenes and Their Heteroatom Analogues
pp. 1
Trialkylphosphine Selenides
pp. 1
Non-Heteroatom-Substituted Alkylphosphonium Salts
pp. 1
Addition of Sulfur to Alkyl(dialkylamino)halophosphines
pp. 1
-Alkyl/Aryl Dialkylphosphinoselenothioates
pp. 1
Perkov-Type Reaction
pp. 1
From Primary Phosphines and Alkyl Halides
pp. 1
Stepwise Synthesis from Phosphorus(III) Compounds
pp. 1
Synthesis of Product Subclass 1
pp. 1
Stereocontrolled Synthesis via 3′--Oxazaphospholidines
pp. 1
Anhydrides of Alkylphosphonic Acids and Their Derivatives
pp. 1
Alkylphosphonous Acid Monoesters
pp. 1
Addition to Phosphonium Salts
pp. 1
Addition of Dialkylphosphine Sulfides to Alkenes
pp. 1
Synthesis from (Dialkylphosphino)methanides and Dialkylhalophosphines
pp. 1
Alkylation of γ-Hydroxyphosphines and Derivatives with Alkyl Halides
pp. 1
Hydrolysis of Dialkyltrihalophosphoranes
pp. 1
Catalysis with Sulfonated and Carboxylated Phosphines
pp. 1
Synthesis of Product Subclass 8
pp. 1
Ligand Exchange Using Alkylphosphines as Substrates
pp. 1
Electrophilic Alkylation of Phosphorus Trihalides
pp. 1
Dealkylation of Dialkyl Phosphonates with Sodium Azide
pp. 1
,-Dialkyl/,-Diaryl Hydrogen Phosphorodithioates
pp. 1
Addition of Selenium to Dialkylphosphinothioites
pp. 1
Salt Metathesis/Elimination
pp. 1
Phosphorous Acid Triamides
pp. 1
Phosphorothious Acid Monoester Monoamide Monohalides
pp. 1
Synthesis from Quaternary Phosphonium Salts
pp. 1
Transformation of Isocyanates into Carbodiimides
pp. 1
Ruthenium-Promoted Hydrogenation of Ketones
pp. 1
Synthesis of Product Subclass 10
pp. 1
Synthesis from (Dialkylphosphino)methanides and Polyhaloalkanes or Analogues
pp. 1
Dialkylselenophosphinous Acid Esters
pp. 1
Reduction of Dialkylphosphine Oxides, Dialkylphosphinates, or Alkylphosphonates with Aluminum Derivatives
pp. 1
Amine–Halogen Exchange in Phosphorothious Acid Diester Monoamides
pp. 1
Synthesis of Product Subclass 14
pp. 1
Alkylphosphonous Acid Monohalides
pp. 1
The Morita–Baylis–Hillman Reaction Using Air-Stable Phosphine Reagents
pp. 1
Synthesis of Product Subclass 1
pp. 1
Stepwise Esterification of Phosphoryl Chloride
pp. 1
Synthesis of Product Subclass 3
pp. 1
Oxidation of Alkyldihalophosphines
pp. 1
Synthesis of Product Subclass 12
pp. 1
-Alkyl/-Aryl Trihydrogen Thiodiphosphates
pp. 1
From Phosphiranes
pp. 1
Approaches to Ferrocenylphosphines with Planar Chirality
pp. 1
Phosphoroselenous Acid ,-Diesters
pp. 1
Synthesis of -Alkyl Hydrogen Alkylphosphonoselenoates
pp. 1
Elimination Reactions
pp. 1
Reaction of Phosphorus Pentachloride with Ammonium Chloride or Tris(trimethylsilyl)amine
pp. 1
Reaction of Phosphonic Acids with Halogenating Reagents
pp. 1
Michaelis–Arbuzov Reaction
pp. 1
Synthesis of Product Subclass 3
pp. 1
Reaction of Ylides with Epoxides and 3-Oxaalkyl Halides
pp. 1
Synthesis of Product Subclass 2
pp. 1
Iridium-Promoted Hydrogenation of Imines
pp. 1
Reaction of Dithiocarboxylic Acids with Dialkyl Chlorophosphites
pp. 1
Applications of Product Subclass 6 in Organic Synthesis
pp. 1
Synthesis of Product Subclass 9
pp. 1
Sulfurization of Trivalent Phosphorus Compounds
pp. 1
Conjugate Addition to Cyclohexa-2,5-dienones
pp. 1
Addition of Dialkylphosphine Sulfides to Aldehydes or Ketones
pp. 1
Treatment with 7-Oxabicyclo[4.1.0]heptane and Trifluoroacetic Acid
pp. 1
Addition of Selenium to Aminophosphines
pp. 1
Michael Addition Reactions
pp. 1
From Phosphorus Trihalides or Trialkyl Phosphites and Organometallic Alkali Metal Compounds or Grignard Reagents
pp. 1
Reaction of Phosphates with Anhydrides of Carboxylic Acids
pp. 1
Synthesis of Product Subclass 13
pp. 1
Phosphorous Acid Triesters (Tertiary Phosphites)
pp. 1
Synthesis of Product Subclass 11
pp. 1
Phosphorylation with Phosphoryl Chloride
pp. 1
Sulfuration of Alkyl Dialkylphosphinites
pp. 1
Synthesis with Catalyst Recycling
pp. 1
Treatment with Dimethyldioxirane
pp. 1
Asymmetric Morita–Baylis–Hillman Reactions
pp. 1
Alkyldithiophosphonous Acid Diesters
pp. 1
Synthesis of Product Subclass 8
pp. 1
Synthesis from Halophosphines and Organometallic Compounds
pp. 1
Phosphorylation with 2-Chloro-4-1,3,2-benzodioxaphosphinin-4-one and Subsequent Reaction with Pyrophosphate
pp. 1
Alkyldiselenophosphonous Acid Diesters
pp. 1
Phosphorothious Acid Diester Monoamides
pp. 1
Synthesis of Dialkyl Dihydrogen Diphosphates by Morpholidate Coupling
pp. 1
Condensation Reactions
pp. 1
Reaction with Dihalogens
pp. 1
Addition of Selenium to Dialkylphosphinites
pp. 1
Free-Radical-Initiated Addition
pp. 1
Dialkyl/Diaryl Phophorohalidates
pp. 1
Reaction of Phosphonium Monomers
pp. 1
Alcoholysis of Phosphorus Trihalides
pp. 1
With Lithium Aluminum Hydride
pp. 1
Selenation of ,-Dialkyl/Diaryl Alkylphosphonites
pp. 1
Synthesis of Product Subclass 16
pp. 1
Aminolysis of Phosphorus Trihalides
pp. 1
Reaction of -Alkylphosphonamidic Halides with Alcohols
pp. 1
Partial Hydrolysis of Alkyl(dihalo)phosphines
pp. 1
Synthesis of Product Subclass 1
pp. 1
Neutral Electrophilic Phosphinidene Complexes
pp. 1
Sulfurization of a Difluoridophosphite
pp. 1
Fluorination of Alkyl or Aryl Phosphorodichloridates
pp. 1
Reaction of Phosphate Esters with Anhydrides of Strong Carboxylic Acids
pp. 1
Reaction of Alkylphosphonothioic Dihalides with Amines
pp. 1
Enzymatic Approaches
pp. 1
Phosphorylation of Alcohols with Phosphoryl Chloride
pp. 1
Alkylthiophosphonous Acid Monoester Monoamides
pp. 1
Applications of Product Subclass 2 in Organic Synthesis
pp. 1
Halogenation of Dialkylhalophosphines
pp. 1
Applications of Product Subclass 7 in Organic Synthesis
pp. 1
Thiophosphorylation with Thiophosphoryl Chloride
pp. 1
Phosphite Oxidation in the Presence of Alcohols
pp. 1
Oxidation of ,-Dialkyl -Phosphonates with 3-1,2-Benzothiaselenol-3-one
pp. 1
Alkyl/Aryl Hydrogen Alkylphosphonates by Miscellaneous Methods
pp. 1
Reaction of Dialkyl(vinyl)phosphine Sulfides with Nucleophiles
pp. 1
Synthesis of Product Subclass 7
pp. 1
Cyclic Phosphines with Seven-Membered and Larger Rings
pp. 1
From Dialkylhalophosphines and Organometallic Alkali Metal Compounds or Grignard Reagents
pp. 1
Phosphorous Acid Monoesters
pp. 1
Reaction of Alkyldichlorophosphines with Sulfenyl Chlorides
pp. 1
Desulfurization of Phosphorodithioates
pp. 1
Direct Thiophosphorylation of the Hydroxy Group
pp. 1
Addition to Carbonyl Groups
pp. 1
The Ludwig One-Pot, Three-Step Procedure
pp. 1
Halogenation of Pentavalent Phosphinothioic Precursors
pp. 1
[4+2]-Cycloaddition Reactions
pp. 1
Sulfanylation of Phosphorous Acid Derivatives
pp. 1
Reduction of Halophosphines, Phosphinic Acids, Phosphinic Acid Esters or Halides, and Trialkyl- and Dialkylphosphine Oxides
pp. 1
Trialkylphosphine Oxides
pp. 1
Selenation of Bis(dialkylamino)phosphines
pp. 1
Phosphorylation of Other Alcohols
pp. 1
Alkylthiophosphonous Acid -Monoesters
pp. 1
Formation of Arylphosphorus Compounds
pp. 1
-[Chloro(dimethylamino)methylene]--methylmethanaminium Chloride as the Condensing Reagent
pp. 1
Borane Reduction of Ketones
pp. 1
Addition of Phosphines to Carbonyl Compounds
pp. 1
Synthesis of Product Subclass 13
pp. 1
α-Arylation of Enones with Hypervalent Bismuth Reagents
pp. 1
-Alkyl/-Aryl Phosphorofluoridothioates
pp. 1
Phosphorous Acid Monoester Monoamides
pp. 1
Addition of Dialkylphosphine Oxides to Alkenes
pp. 1
Dialkyltrihalophosphoranes and Other Heteroatom-Containing Analogues
pp. 1
Ring Opening of a 5′-(1-Thiocyclotriphosphate) with Ethane-1,2-diamine
pp. 1
Halogenation of Dialkylphosphinothioic Acids
pp. 1
2,5-Dihydrophospholes from Diallylphosphines via Alkene Metathesis
pp. 1
Copper-Catalyzed Asymmetric 1,4-Addition of Organozinc Reagents
pp. 1
Synthesis from Bis(alkylphosphides) and Alkyl Halides
pp. 1
,-Dialkyl/,-Diaryl Hydrogen Thiophosphates
pp. 1
Alkylphosphonous Acid Monoamides
pp. 1
-Alkyl/Aryl Dialkylphosphinothioates
pp. 1
Reaction of Alkyl/Aryl Alkylphosphonohalidates with Amines
pp. 1
Addition of Hydrogen Chloride to Vinyl Phosphates
pp. 1
Synthesis of Product Subclass 2
pp. 1
-Alkyl Phosphorodifluoridothioates
pp. 1
Rearrangement Reactions
pp. 1
Reduction of Bis(dialkylphosphoryl)alkanes with Silanes
pp. 1
,-Dialkylphosphinoselenoic Amides
pp. 1
Alkylation of Phosphines with β-Carbonyl-Substituted Alkyl Halides
pp. 1
Synthesis from Dialkyltrihalophosphoranes
pp. 1
Hydrophosphination of Alkenes
pp. 1
Stepwise Synthesis from Phosphorus(V) Adducts
pp. 1
Reaction of Alkylphosphonothioic Dihalides with Alkane-/Arenethiols
pp. 1
Di- and Oligomerization of Phosphino Alcohols
pp. 1
Of Alkali Metal Phosphides
pp. 1
Dialkylselenophosphinous Acids
pp. 1
Esterification of Phosphorous Acid
pp. 1
α-Hydrogen Migration
pp. 1
Addition of Dialkyl Phosphite Anions to Imines
pp. 1
Synthesis of Poly(dichlorophosphazene)
pp. 1
Synthesis from Alkylphosphonic Dichlorides
pp. 1
Applications of Product Subclass 1 in Organic Synthesis
pp. 1
-Alkynylation of Potassium ,-Dialkyl Phosphorodithioates
pp. 1
Phosphorotriselenous Acid Triesters
pp. 1
Free Phosphinidenes
pp. 1
S-Alkylation of Dialkylphosphinothioic -Acids
pp. 1
Phosphorylation with (2-Oxo-5,5-diphenyloxazolidin-3-yl)phosphonates
pp. 1
Sulfuration of Alkyldihalophosphines
pp. 1
Alkylation of β-Carbonylphosphines with Alkyl Halides
pp. 1
Arbuzov Reaction of Trialkyl Trithiophosphites with Alkyl Halides
pp. 1
Other Protocols Based on the Use of Phosphorus Trichloride
pp. 1
,,-Trialkyl/,,-Triaryl Phosphorothioates
pp. 1
Proazaphosphatrane Sulfides
pp. 1
Baylis–Hillman Reaction
pp. 1
Alkyl/Aryl Hydrogen Alkylphosphonates and Their -Alkyl/Aryl Sulfur and Selenium Derivatives
pp. 1
Reaction of Phosphines with Enol Ethers
pp. 1
Miscellaneous Procedures
pp. 1
Synthesis from Halophosphonites
pp. 1
Phosphino-4,5-dihydro-1-imidazole Ligands
pp. 1
Synthesis of Phosphorothioates Containing an α,β-Unsaturated Carbonyl Moiety
pp. 1
Synthesis of α-Carbonylphosphonium Salts and Derivatives
pp. 1
Activation of White Phosphorus
pp. 1
2,5-Dihydrophospholes from Dihalophosphines and Dienes via [4+1] Cycloaddition and Reduction
pp. 1
Solid-Phase Synthesis of Dinucleoside and Nucleoside–Carbohydrate Phosphodiesters
pp. 1
-Alkyl Tetrahydrogen 1,2,3-Trithiotriphosphates
pp. 1
Tetraalkyldiphosphines and Polyalkylpolyphosphines with a P—P Bond
pp. 1
Catalysis with Water-Soluble Phosphines
pp. 1
Proazaphosphatrane Oxides
pp. 1
Reaction with Peroxides
pp. 1
Alcoholysis of Phosphorous Acid Monoamide Dihalides
pp. 1
Synthesis of Product Class 4
pp. 1
Addition of Diphosphines to Alkynes
pp. 1
-Alkyl/-Aryl Dihydrogen Phosphorodithioates
pp. 1
Synthesis via Imidazolides
pp. 1
Selenophosphorylation of Silyl Enol Ethers
pp. 1
Alkylthiophosphonous Acid Diesters
pp. 1
,-Dialkyl/Diaryl Alkylphosphonates and Their Sulfur and Selenium Derivatives
pp. 1
Thiophosphorylation of Tributylstannyl Ethers
pp. 1
Dialkylphosphinous Acid Halides
pp. 1
Heteroatom-Substituted Iminophosphines
pp. 1
Alkylation of Hypophosphorous Acid Salts
pp. 1
Addition of Carbonyl Compounds to Phosphorus Ylides
pp. 1
Synthesis of Product Subclass 4
pp. 1
Phosphepin-Based Chiral Ligands
pp. 1
Oxidation by Nitrous Oxide
pp. 1
Hydrolysis of Alkylphosphonic Acid Amides
pp. 1
Alkylation of ,-Dialkyl Phosphorodithioates
pp. 1
Cycloreversion Reactions
pp. 1
Reaction of Alkoxy- or Aminosilanes with Halophosphoranes
pp. 1
Alkyl Dihydrogen Phosphates
pp. 1
Synthesis of Product Subclass 2
pp. 1
Phosphorous Acid Diester Monoamides
pp. 1
Thermal Generation
pp. 1
Transformation of Cyclic Phosphines
pp. 1
Iminophosphines
pp. 1
Synthesis of Product Subclass 1
pp. 1
Disodium 2-({2-[Bis(4-methoxyphenyl)(phenyl)methoxy]ethyl}sulfonyl)ethyl Phosphate as a Phosphorylating Agent for Primary and Secondary Alcohol Functions in Nucleosides
pp. 1
Hydrolysis of Alkyl(diamino)phosphines
pp. 1
Transformation of γ-Functionalized Phosphonium Salts
pp. 1
Cyclization between Two Phosphorus Substituents
pp. 1
Enantioselective Allylation Reactions
pp. 1
Stereocontrolled Synthesis via 2-Sulfido-1,3,2-oxathiaphospholanes
pp. 1
Isomerization of Activated Alkynes to Dienes
pp. 1
Oxygenation of a Trialkylphosphine Selenide
pp. 1
From Phosphines and 1,3-Dihalides or Derivatives of 1,3-Diols
pp. 1
Sulfurization of Trialkylphosphines with Elemental Sulfur
pp. 1
Synthesis of Nucleoside 3′--Phosphorodithioates
pp. 1
Synthesis of Diaryl Ethers and Sulfides
pp. 1
Ligand Exchange in Alkyl(amino)phosphine Derivatives
pp. 1
From Secondary Phosphines and Alkyl or Acyl Halides
pp. 1
Direct Sulfurization of Dialkyl -Phosphonates
pp. 1
Synthesis of Product Subclass 3
pp. 1
Addition of Phosphorous Acid to Alkenes, Carbonyl Compounds, Imines, and Nitriles
pp. 1
Oxidation of Alkylphosphonamidous Acid Esters
pp. 1
Arbuzov-Type Alkylation of Alkylphosphonotrithioates
pp. 1
Cyclodimerization of Phosphaalkenes
pp. 1
Reaction of Phosphorus Trichloride with Carbonyl Compounds or Carboxylic Acid Derivatives Followed by Hydrolysis
pp. 1
Asymmetric Aldol Reactions
pp. 1
Applications of Product Subclass 17 in Organic Synthesis
pp. 1
Exchange Reactions of Alkylphosphonic Diamides
pp. 1
Phosphorotrithious Acid Triesters
pp. 1
Synthesis from a Phosphorochloridate
pp. 1
Solid-Phase Phosphoramidites for Selective Monophosphorylation of Carbohydrates and Nucleosides
pp. 1
Activation of Arene—Silicon Bonds
pp. 1
Synthesis of Product Subclass 9
pp. 1
Synthesis from Phosphorous Halides by P—C Bond Formation
pp. 1
Regioselective Allylic Displacement
pp. 1
Phosphine-Mediated Reductive Condensation of Acyloxybutynoates
pp. 1
Alkylation of Sulfur in Phosphorothioate Derivatives
pp. 1
Rhodium-Promoted Hydroboration of Alkenes
pp. 1
Approaches to Enantioselective Catalysts
pp. 1
Lewis Acid Induced Cyclization of Dichlorophosphines with Alkenes and Subsequent Reduction
pp. 1
Decomposition of Phosphonium Salts
pp. 1
Metal-Catalyzed Addition of Organometallic Reagents to Carbonyl Compounds
pp. 1
Halogen Abstraction of Halophosphines
pp. 1
Miscellaneous Protocols Leading to ,-Dialkyl/Diaryl Alkylphosphonothioates
pp. 1
Synthesis of Product Subclass 27
pp. 1
From Phosphirenes
pp. 1
Oxidative Coupling of Polyphospholides
pp. 1
Aminolysis of Dialkyl Alkylphosphonates
pp. 1
Addition of Potassium Selenocyanate to Trialkylphosphines
pp. 1
Hydrolysis of Dialkylphosphinous Acid Derivatives
pp. 1
Coupling Reaction of Alkylphosphonic Acids with Thiols
pp. 1
Oxidation of Tricoordinated Phosphorus Compounds
pp. 1
Oxidation with an Iodosylaryl Sulfone
pp. 1
Addition of a 1,3-Diene to an Alkyl(chloro)(methylsulfanyl)phosphine
pp. 1
Addition of Dialkyl Phosphites to Carbonyl Groups
pp. 1
Phosphorous Acid Diesters (Secondary Phosphites)
pp. 1
Halogenation of -Alkyl Dialkylphosphinoselenothioates
pp. 1
Synthesis of Product Subclass 3
pp. 1
Transformation of Phosphonium Salts
pp. 1
Oxidation of Alkyl/Aryl Dialkylphosphinites
pp. 1
The Dithiaphospholane Method
pp. 1
Chiral Nucleophilic Addition Reactions
pp. 1
Synthesis of Nucleoside 5′--Phosphorodithioates
pp. 1
Enantioselective Cleavage of a P—C Bond in Alkyldimethylphosphine–Borane Complexes
pp. 1
Synthesis from Metal Organophosphides and Electrophiles
pp. 1
-Alkyl Dihydrogen Phosphorothioates
pp. 1
Synthesis of Product Subclass 20
pp. 1
Reaction of Phosphonic Acid Diesters with Halogenating Reagents
pp. 1
Addition of Dialkylphosphines to Vinyl- or Allylphosphines
pp. 1
Sulfurization of Peptide Analogues
pp. 1
Aminolysis of Substituted Alkylphosphines
pp. 1
P=O Phosphates
pp. 1
Sulfanylation of Phosphorous Acid Diesters
pp. 1
Selection of Enantiotopic Sites of an Achiral Alkenic Substrate
pp. 1
Esterification of Alkylphosphonic Acids
pp. 1
Halogen–Zinc Exchange Reactions of Aryl Iodides
pp. 1
Addition Reactions of Unsaturated Tertiary Vinylphosphines
pp. 1
Synthesis of Product Subclass 4
pp. 1
Methanolysis of Phosphoramidothioates
pp. 1
Activation by Imidazolides
pp. 1
Synthesis of Product Subclass 3
pp. 1
Synthesis of Product Subclass 3
pp. 1
-Alkyl/Aryl Hydrogen Alkylphosphonothioates and Their Sulfur and Selenium Derivatives
pp. 1
Reaction of Alkylphosphonic Dichlorides with Amino Alcohols or with an Alcohol and an Amine
pp. 1
Addition of a Dialkylphosphine Selenide to an Aldehyde
pp. 1
From Diphosphinomethanides
pp. 1
Synthesis of Product Subclass 6
pp. 1
From Alkyldihalophosphines and Organometallic Alkali Metal Compounds or Grignard Reagents
pp. 1
Synthesis of Product Subclass 6
pp. 1
Sulfurization of Deoxynucleotide Analogues
pp. 1
Nucleophilic Addition Reactions at Nonactivated Positions
pp. 1
[3+2]-Cycloaddition Reactions
pp. 1
Phosphorothious Acid ,-Diesters
pp. 1
Synthesis of Product Subclass 13
pp. 1
From Phosphorochloridites
pp. 1
Synthesis of Product Subclass 1
pp. 1
Addition to Alkylated Iminophosphoranes
pp. 1
Synthesis from Dialkylphosphides and Cyclic Sulfates
pp. 1
Halogenation of Dialkylphosphinic Acids and Derivatives
pp. 1
Reaction of Alkyl/Aryl Alkylphosphonohalidates with Alcohols
pp. 1
P-Substitution of -Halophosphetanes
pp. 1
Polymerization Catalyzed by Uranyl Ion
pp. 1
Synthesis of β-Carbonyl-Substituted Phosphonium Salts and Derivatives
pp. 1
Synthesis of Product Subclass 2
pp. 1
Reduction of Halophosphines with Lithium Aluminum Hydride or Other Metal Hydrides
pp. 1
Phosphorous Acid Diamide Monohalides
pp. 1
From Metal Phosphides and Oxiranes
pp. 1
Applications of Product Subclass 5 in Organic Synthesis
pp. 1
Alkylation of Dichlorophosphines or Phosphinic Acid ,-Diesters
pp. 1
Synthesis from Dialkylphosphides and (Dialkylphosphino)alkyl Sulfonates
pp. 1
Selenoalcoholysis of Alkyl(dihalo)phosphines
pp. 1
Sulfurization of Phosphorofluoridites
pp. 1
Nucleophilic Substitution on Pentacoordinated Phosphoranes
pp. 1
Reaction of Unsaturated Compounds with Halophosphoranes
pp. 1
Synthesis of Product Subclass 5
pp. 1
Synthesis from Elemental Phosphorus and Alkyl Halides, Alcohols, or Alkenes
pp. 1
Hydrolysis of Dialkylphosphinoselenoic Halides
pp. 1
Phosphorous Acid Diamides
pp. 1
Reaction of Carbonyl Compounds with Tricoordinated Phosphorus
pp. 1
Bis(alkylphosphino)- and Poly(alkylphosphino)alkanes
pp. 1
Synthesis of Product Subclass 26
pp. 1
Horner–Wadsworth–Emmons Reaction of Phosphonamidates and Thiophosphonamidates
pp. 1
Diphosphenes
pp. 1
Phosphorous Acid Monoester Diamides
pp. 1
Reaction of Stabilized Ylides with Other Electrophiles
pp. 1
Transesterification of Phosphorous Acid Triesters
pp. 1
Alkyl Aryl Ether Synthesis
pp. 1
From Phosphaalkenes and Diazoalkanes
pp. 1
Catalysis with Fluorinated Phosphines
pp. 1
Salt Metathesis
pp. 1
Synthesis from Phosphine, or Primary or Secondary Phosphines, and Alkyl Halides
pp. 1
Sulfurization with Thiirane
pp. 1
Halogenation of Tri- and Tetracoordinated Phosphorus-Containing Precursors
pp. 1
Oxidation of O,S-Disubstituted Phosphonothiolates
pp. 1
Alkyl Trihydrogen Diphosphates
pp. 1
Di- and Oligomerization by Interaction of Functional Groups of Phosphines
pp. 1
Trialkylphosphine Sulfides
pp. 1
Metal-Catalyzed Coupling Reactions
pp. 1
Synthesis of Product Subclass 2
pp. 1
Alkylphosphonic Dihalides from Phosphorus Trihalides
pp. 1
In Situ Oxidation of Alkylphosphonous Acids
pp. 1
Reaction of Phosphines with Epoxides
pp. 1
Reaction of Alkyl/Aryl Alkylphosphonohalidates with Tertiary Amines
pp. 1
Insertion into the P—H Bond of Hydrophosphoranes
pp. 1
Synthesis from Dialkylphosphines and Polyhaloalkanes, Alkylamines, and Alcohols
pp. 1
Cycloaddition or Metathesis Reactions
pp. 1
-Alkyl Trihydrogen Thiodiphosphates
pp. 1
Alkylphosphonic Dihalides and Their Sulfur and Selenium Derivatives
pp. 1
Reaction of Alkylphosphonoselenoic Dihalides with Amines
pp. 1
Esterification of Monoalkylphosphinic Acids
pp. 1
Enantioselective Synthesis from Lithium (Dialkylphosphino)methanide–Borane Complexes and Alkylhalophosphines
pp. 1
Carbonylphosphonium Salts and Derivatives
pp. 1
Reaction of Phosphates or Phosphate Esters with Amino Acids in the Presence of Diisopropylcarbodiimide or Dicyclohexylcarbodiimide
pp. 1
Alkylphosphonous Acid Diesters
pp. 1
Synthesis of Product Subclass 3
pp. 1
Applications of Product Class 3 in Organic Synthesis
pp. 1
Sulfurization with Bis[3-(triethoxysilyl)propyl] Tetrasulfide
pp. 1
P-Alkylation of Tertiary Phosphines or Diphosphines and Reduction
pp. 1
Synthesis of Product Subclass 4
pp. 1
Hydrolysis of Diesters of Alkylphosphonic Acids
pp. 1
Miscellaneous Reactions
pp. 1
Reduction and Subsequent Sulfurization of ,-Dialkyl Phosphorochloridothioates
pp. 1
Sulfanyl- and Selanylphosphonium Salts and Derivatives
pp. 1
Formation of C—N Bonds
pp. 1
Synthesis of Product Subclass 28
pp. 1
Synthesis of γ-Sulfanyl- and γ-Selanylphosphonium Salts and Derivatives
pp. 1
Pyridylphosphinite and Quinolylphosphinite Ligands
pp. 1
Deprotonation Reactions
pp. 1
Using Monosubstituted Allylic Ligands
pp. 1
Synthesis of Product Subclass 1
pp. 1
Sulfurization of Phosphite Triester
pp. 1
Alkylation of Tertiary Phosphines
pp. 1
Miscellaneous Reactions
pp. 1
Reaction of -Alkyl Phosphorous Diamides with Alkyl Halides
pp. 1
Synthesis of Oligomers of Alkylphosphonic and Alkylphosphonothioic Anhydrides
pp. 1
Dithiophosphorylation of Alcohols and Hydrolysis of the Triester
pp. 1
Preparation of Di- and Trithioesters from Alkylphosphonothioic and Alkylphosphonic Dichlorides
pp. 1
Reaction of Dialkylphosphinic Halides with Alcohols or Phenols
pp. 1
Reaction of Dialkyl Chlorophosphites with Alkyl Halides
pp. 1
Reactions of Dialkylphosphinites with Alkyl Halides
pp. 1
Synthesis of Product Subclass 6
pp. 1
Alkylation of Alkylphosphonothioic Acid Anions with Alkyl Halides
pp. 1
Reaction of Secondary Phosphines or Derivatives with 1,n-Dielectrophiles
pp. 1
Addition of Polyphosphinoalkanes to C=C or C=X Bonds
pp. 1
Reaction of Ylides with Sulfur- or Selenium-Containing Electrophiles
pp. 1
Alkylation of Phosphines with γ-Hydroxyalkyl Halides or Derivatives
pp. 1
Reaction of Secondary Phosphine Oxides or Dialkylhalophosphine Derivatives with Disulfides or Thiocarbonyl Derivatives
pp. 1
Alkylphosphonous Acid Monoamide Monohalides
pp. 1
Solid-Phase Sulfurization of Phosphoramidothioites
pp. 1
Synthesis of Product Subclass 2
pp. 1
Copper-Catalyzed Asymmetric 1,4-Addition of Grignard Reagents
pp. 1
Addition of Sulfur to Dialkylhalophosphines
pp. 1
Alcoholysis of Alkylphosphine Derivatives
pp. 1
Transformation of Phosphetanes
pp. 1
Reaction of Ylides with Carbonylated Electrophiles
pp. 1
Lithiation and Electrophilic Substitution at α-C—H Bonds in Cyclic Phosphine Oxides and Borane Complexes
pp. 1
Thiophosphorylation of Silyl Enol Ethers
pp. 1
Cyclic Phosphonium Salts
pp. 1
Substitution Reactions
pp. 1
Synthesis from Dialkylphosphinous Acid Derivatives
pp. 1
Synthesis of Product Subclass 5
pp. 1
Selective Dealkylation of Triesters Bearing a P—S—C Bond System
pp. 1
,-Dialkyl/Diaryl Alkylphosphonodithioates and Their Sulfur and Selenium Derivatives
pp. 1
Stereocontrolled Synthesis via Cyclic -Acylphosphoramidites
pp. 1
Tandem α- or γ-Addition and Michael Addition Reactions
pp. 1
Applications of Product Subclass 22 in Organic Synthesis
pp. 1
Synthesis of α-Hydroxyphosphonium Salts and Derivatives
pp. 1
Addition of Phosphines to Alkenes
pp. 1
Alcoholysis of Phosphorothious Acid Derivatives
pp. 1
Reaction of Alkyl/Aryl Alkylphosphonohalidates with Alkali Metal Thiolates
pp. 1
Reaction with Multihalides
pp. 1
Phosphonite [P(C,O,O)] Ligands
pp. 1
Synthesis of Product Subclass 9
pp. 1
Direct Oxidation of Phosphorus(III) Adducts
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