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Ethers
Alkaline Hydrolysis of Dianhydrohexitols
other
Author(s):
I. Robina
,
P. Vogel
Publication date
(Online):
2008
Publisher:
Georg Thieme Verlag KG
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Book Chapter
Publication date (Print):
2008
Publication date (Online):
2008
Page
: 1
DOI:
10.1055/sos-SD-037-00487
SO-VID:
b2254525-ebc6-4912-bd9f-a3a41655c54b
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Book chapters
pp. 1
Total Asymmetric Synthesis
pp. 1
C-Glycosylation Using Activated Pyranosyl Cation Precursors
pp. 1
Acetal-Initiated Cyclizations of Vinylsilanes
pp. 1
Synthesis Mediated by Group 6 Metals
pp. 1
Synthesis Using Hydrides as Base
pp. 1
Synthesis Using Alkoxides as Base
pp. 1
Synthesis from Vicinal Hydroxy Sulfides and Selenides
pp. 1
Substitution of an α-Hydrogen with Carbon
pp. 1
Applications of Product Subclass 1 in Organic Synthesis
pp. 1
1,3-Anhydroalditols
pp. 1
Reaction with Saturated Sodium Iodide, Boron Tribromide, and 15-Crown-5
pp. 1
Addition of an α-Selanylmethyl Anion
pp. 1
Alkylation/Acetal/Aldol Ring-Closing Metathesis Strategy
pp. 1
Addition of a Bismuthonium Ylide
pp. 1
Ring-Closing Metathesis of Diallyl Ethers and Subsequent Alkene Functionalization
pp. 1
Using 4-(Dimethylamino)pyridine
pp. 1
Synthesis from Alcohols Using a Catalytic Amount of Base
pp. 1
Synthesis of Polysubstituted Dihydropyrans via Trimethylsilyl Trifluoromethanesulfonate Mediated Condensation of ()-Trimethyl[4-(trimethylsilyl)but-3-enyloxy]silanes with Aldehydes or Acetals
pp. 1
Ring Expansion
pp. 1
Hydrogenolysis with Palladium
pp. 1
Synthesis from Carbonates
pp. 1
Deprotection of 4-Methoxybenzyl Ethers
pp. 1
Synthesis from Alcohols Using Brønsted Acids
pp. 1
Using -Tosylimidazole
pp. 1
Addition of Allylstannane Reagents
pp. 1
Synthesis from 1,3-Diols
pp. 1
Synthesis via Ribofuranosylacetylenes
pp. 1
Addition of an α-Sulfanylmethyl Anion
pp. 1
C—O Bond Insertion of Diazo Compounds into Acyclic Ethers
pp. 1
Tandem Tebbe–Claisen Rearrangement
pp. 1
Enantioselective Synthesis of Sulfinyl Dihydropyrans by Base-Promoted Intramolecular Cyclization of 2-Sulfinyl Dienols
pp. 1
Oxetan-3-ones
pp. 1
Nucleophilic Addition to Oxoglucal Derivatives
pp. 1
Addition of Organoaluminum Reagents
pp. 1
Induced by -(Phenylselanyl)phthalimide
pp. 1
Photochemical Alkoxylation
pp. 1
Silyl-Modified Sakurai Reaction
pp. 1
Using Silver(I) Oxide
pp. 1
Platinum-Mediated Asymmetric Epoxidation
pp. 1
Diastereoselective Reaction Controlled by Resident Stereogenicity of the Alkene
pp. 1
Enantioselective Desymmetrization
pp. 1
By Deprotonation of an Arsonium Salt
pp. 1
Synthesis by a Two-Step Procedure from an Acetal
pp. 1
Anomeric Cationic Reduction
pp. 1
C-Glycosylation Using Methyl Pyranosides
pp. 1
Derivation of 2,5-Anhydropentoses
pp. 1
Reaction of Aldehydes
pp. 1
Ring-Closing Metathesis of Allylic Acetals
pp. 1
Synthesis of Acyclic Ethers by Alkylation of α-Halo Ethers
pp. 1
C-Glycosylation Using Pyranosyllithium Reagents
pp. 1
Transition-Metal-Catalyzed Addition of Diazo Compounds
pp. 1
Cyclopropanation of Glycals and Subsequent Ring Opening
pp. 1
Sigmatropic Rearrangements of Sugar Derivatives
pp. 1
Nucleophilic Addition of C2
pp. 1
Synthesis Using a Metal Hydride and a Methylating Agent
pp. 1
Thermal Cyclization of Methiodides of 2-[2-(Aminomethyl)phenyl]ethanols to 3,4-Dihydro-1-2-benzopyrans
pp. 1
Cyclization of Allenic Hydroxy Esters by Treatment with Hydrogen Chloride in Chloroform
pp. 1
4-Methoxybenzyl Ethers
pp. 1
Using 4-Toluenesulfonates
pp. 1
Induced by Bis(collidine)bromonium
pp. 1
Aryl Iodide Coupling Reactions
pp. 1
Using Peroxycarbonic Acids
pp. 1
Synthesis from 3-Halopropanols (The Williamson Synthesis)
pp. 1
De Novo Synthesis of -Pyranosides
pp. 1
Addition of an Ammonium Ylide
pp. 1
[4 + 3] Cycloadditions of Furans
pp. 1
Diastereoselective Reaction Controlled by Resident Stereogenicity of the Alcohol
pp. 1
Synthesis from Alcohols under Mitsunobu Conditions
pp. 1
Reaction of Di--butyl Peroxide with Grignard or Organolithium Reagents
pp. 1
Anomeric Cationic Reduction of Pentopyranosides
pp. 1
Reaction with Carbon Tetrabromide under Reflux
pp. 1
The Abushanab Modification
pp. 1
Diastereoselective Reaction Achieved by Selective Protonation
pp. 1
Reaction of Fluorinated Carbonyl Compounds
pp. 1
Larger-Ring Oxacycloalk-3-enes
pp. 1
Synthesis of Product Class 5
pp. 1
Claisen Rearrangement of 2,2-Dichlorovinyl Ethers
pp. 1
Organometallic Additions to Aldonolactones
pp. 1
Synthesis of Oxacycloalk-3-enes by Diels–Alder Reactions
pp. 1
Using 3-Chloroperoxybenzoic Acid
pp. 1
Alkylation of Silyl Enol Ethers with Epoxides
pp. 1
Total Asymmetric Syntheses Starting from Furan
pp. 1
With Iodotrimethylsilane
pp. 1
In Situ Prepared Reduced Titanium Ethylidenes for the Synthesis of Six- to Eight-Membered Rings
pp. 1
Rearrangement of Oxiranylalkyl Ethers
pp. 1
Epoxidation of Aldoses
pp. 1
Organocuprate Addition
pp. 1
Reduction of Hexopyranosyl Cyanides and Subsequent Deamination
pp. 1
Palladium-Catalyzed Reaction of Cyclic Alkynyl Carbonates with Electron-Deficient Alkenes
pp. 1
Synthesis from Pentose Derivatives
pp. 1
Formation of Cyclic Ethers from Other Ethers
pp. 1
Synthesis of Methyl Ethers
pp. 1
Synthesis Using Powdered Potassium Hydroxide in Neat Benzyl Chloride at High Temperature
pp. 1
Synthesis from Vicinal Siloxy Sulfonates
pp. 1
Chromium-Mediated Asymmetric Epoxidation
pp. 1
By Reaction of an Ylide Generated from a Metal Carbenoid and a Sulfide
pp. 1
Synthesis Using Base
pp. 1
Synthesis of Acyclic Ethers by Alkylation of Aldehydes or Ketones
pp. 1
Lewis Acid Mediated Prins-Type Reactions
pp. 1
Amide Derivatization
pp. 1
Intermolecular Radical C-Glycosidation
pp. 1
Using Metal Alkoxides
pp. 1
1,4-Anhydrotetritols
pp. 1
Synthesis Using Dioxiranes
pp. 1
Cyclization of α-Allenic Alcohols Using Benzeneselenenyl Chloride as Electrophile
pp. 1
Iron-Mediated Epoxidation of Alkenes
pp. 1
Reaction with 2,3-Dichloro-5,6-dicyanobenzo-1,4-quinone
pp. 1
Electrophilic Alkoxymercuration
pp. 1
Dianhydroalditols
pp. 1
Lewis Acid Catalyzed Coupling of Allylsilanes and Allylstannanes
pp. 1
Reaction with Diazo(diphenyl)methane and Tin(II) Chloride (the Petursson Monodiarylmethylation of Vicinal Diols)
pp. 1
Alkaline Hydrolysis of Dianhydrohexitols
pp. 1
Hydrogenation
pp. 1
Synthesis by Acid-Promoted Ring Closure of 1-Substituted 2-(Hydroxymethyl)phenylethanols
pp. 1
-Pentofuranosides and -Nucleosides
pp. 1
Ring Opening of Cyclopropanes
pp. 1
Reduction of 2,5-Anhydrohexoses
pp. 1
Synthesis from Cyclic Acetals
pp. 1
Formation of the C—C Bond at Other Carbons
pp. 1
Using Selenonium Ylides Generated by Deprotonation
pp. 1
Radical Alkoxylation of Alkenes
pp. 1
Organozinc Addition
pp. 1
Using Benzyl Halides and Silver(I) Oxide
pp. 1
With Zinc(II) Borohydride
pp. 1
Synthesis Using Diazomethane
pp. 1
C-Glycosylation Using Sugar-Derived Phosphoranes
pp. 1
1,3-Dihydroisobenzofurans
pp. 1
Dehydration with -(Dimethoxymethyl)-,-dimethylamine
pp. 1
Synthesis of 3-(Alkoxymethyl)-2,5-Dihydrofurans via Alkylidenecarbene Insertion Reactions
pp. 1
Of α,β-Unsaturated Carbonyl Compounds
pp. 1
Addition of an α-Alkoxyallyl Anion
pp. 1
1,2:3,4-Dianhydrotetritols
pp. 1
Selenium Alkylation
pp. 1
Xanthate Deoxygenation
pp. 1
Hydrosilylation
pp. 1
Synthesis from Other Cyclic Ethers
pp. 1
Synthesis of Oxacycloalk-3-enes by Sigmatropic Rearrangement
pp. 1
Using Bis(tributyltin) Oxide
pp. 1
1,2-Anhydroalditols
pp. 1
From Diazo(trimethylsilyl)methane
pp. 1
Synthesis of Acyclic Ethers by Alkylation of Acetals
pp. 1
Base-Catalyzed Conjugate Addition of Alcohols to Electron-Deficient Alkenes
pp. 1
Synthesis from Functionalized Enolates
pp. 1
Synthesis of Acyclic Ethers by Alkylation of Esters
pp. 1
Vinylsilane-Terminated Cyclizations of Ester-Substituted Oxycarbenium Ion Intermediates
pp. 1
Intramolecular Cyclization of Grignard Reagents Derived from 2-(Chloromethyl)-1-iodobenzenes
pp. 1
Deprotection of Diarylmethyl Ethers
pp. 1
Reduction of Pentopyranosyl Halides, Isothiocyanates, and Thiopyranosides
pp. 1
Reaction of -Butyl Peroxybenzoates with Grignard Reagents
pp. 1
Vanadium-Mediated Epoxidation with Alkyl Hydroperoxides
pp. 1
2,3-Anhydroalditols
pp. 1
Using Selenonium Ylides Generated by Addition to (Arylethynyl)diphenylselenonium Trifluoromethanesulfonate
pp. 1
Reaction with Aluminum Trichloride and Tetrabutylammonium Iodide
pp. 1
Substitution Reactions
pp. 1
Addition of Trimethylsilyl Cyanide
pp. 1
Palladium-Mediated Coupling
pp. 1
-Disaccharides through Carbonylative Stille Cross Coupling
pp. 1
Cyclization of Enitols
pp. 1
Pentofuranose Alkenation
pp. 1
Lewis Acid Catalyzed Coupling of Trimethylsilyl Cyanide and Allylic Acetates
pp. 1
Suzuki Coupling
pp. 1
Via Triethyloxonium Tetrafluoroborate
pp. 1
Acid-Catalyzed Addition of Alcohols to Isolated Alkenes
pp. 1
Isomerization–Acidic Hydrolysis
pp. 1
Synthesis from Oxalate Esters
pp. 1
Using Dimethyldioxirane
pp. 1
Substitution of Allylic Ethers
pp. 1
1,3-Elimination of Sulfonic Esters
pp. 1
Selenoxide Elimination
pp. 1
Formation of Six-Membered Rings Using Molybdenum Catalysts
pp. 1
Using Benzyl Halides and Aqueous Potassium Hydroxide Under Phase-Transfer Conditions
pp. 1
Synthesis Using Arylzinc Reagents
pp. 1
Applications of Product Class 6 in Organic Synthesis
pp. 1
C-Glycosylation Using Anomeric Glycalmetals
pp. 1
Claisen Rearrangement of Vinyl Ethers
pp. 1
Synthesis Using Organic Peroxy-Containing Compounds
pp. 1
1,4:2,3-Dianhydrotetritols
pp. 1
Rearrangement of Glycals
pp. 1
Synthesis of Product Class 6
pp. 1
Nitrilium Ion Formation
pp. 1
Synthesis Using Oxaziridines and Oxaziridinium Salts
pp. 1
With Diisobutylaluminum Hydride
pp. 1
Epoxidation of But-2-ene-1,4-diols
pp. 1
Selective Hydrogenolysis with Raney Nickel
pp. 1
Synthesis Using Disilazanides as Base
pp. 1
Addition of Organometallic Reagents
pp. 1
Glycal Derivatives as Electrophiles: Ferrier Rearrangement
pp. 1
With Brønsted Acid Catalysis
pp. 1
Using Peroxyimidic Acids
pp. 1
2,5-Anhydropentitols
pp. 1
Double 1,3-Elimination of Disulfonic Esters
pp. 1
Synthesis by Photochemical [2+2] Cycloaddition
pp. 1
Ring-Closing Metathesis of Allylic Ethers
pp. 1
Reduction of Furanosyl Bromides by Titanocene Borohydride
pp. 1
Addition of Alka-2,3-dienyl- and Propargylsilanes
pp. 1
Deprotection of Methyl Ethers
pp. 1
Anhydroalditols
pp. 1
Synthesis Using Alkyllithium Reagents
pp. 1
Rearrangement of (Hydroxyethyl)oxiranes
pp. 1
Synthesis of Diarylmethyl Ethers
pp. 1
Reduction of Anhydrohexoses
pp. 1
Heterocyclic Aromatic N-Alkylation
pp. 1
Synthesis by Modification of Oxetanes at the Ring
pp. 1
Dehydrative Cyclization of ()-Alk-2-ene-1,4-diols
pp. 1
Metal-Promoted Reaction of Allylsilanes
pp. 1
Epoxidation of Alkenediols
pp. 1
Aryllithium Addition to γ-Pentonolactone Derivatives
pp. 1
Reaction of Carboxylic Acid Derivatives and Quinones
pp. 1
Reaction with Palladium on Charcoal
pp. 1
Acid-Catalyzed Reaction with Phosphates
pp. 1
Thioacetal Cleavage
pp. 1
With Triethylsilane
pp. 1
Intramolecular Cyclization of 1,2-Bis(halomethyl)benzenes or 1,2-Phenylenedimethanol
pp. 1
1,2-Anhydrohexitols
pp. 1
Acid-Catalyzed Dehydration
pp. 1
Synthesis by Ring Contraction
pp. 1
Synthesis of 3,4-Dihydro-1-2-benzopyrans via Lewis Acid Promoted Cyclization of Acetals of 2-Phenylethanols
pp. 1
Cyclization of 2-(Phenylsulfanyl)buta-2,3-dien-1-ol Derivatives Using Various Electrophiles
pp. 1
Triarylmethyl Ethers
pp. 1
Synthesis from α-Hydroxy Ketones and Triphenyl(vinyl)phosphonium Salts
pp. 1
Reaction with Trityl Chloride and 4-(Dimethylamino)pyridine
pp. 1
Synthesis Mediated by Group 7 Metals
pp. 1
Reductive Polymerizations of Vinylic Ethers
pp. 1
Glycallithium Addition to Benzoquinones
pp. 1
Indium(III) Chloride Mediated Tandem Carbonyl Allylation–Prins Cyclization of Tributyl[3-(trimethylsilyl)allyl]stannane with Aldehydes
pp. 1
Diastereoselective, Alkene-Controlled Alkoxyselanylation
pp. 1
Acid-Catalyzed Dehydration
pp. 1
Synthesis of Oxacycloalk-3-enes by Palladium-Mediated Reactions
pp. 1
Synthesis Mediated by Group 8 Metals
pp. 1
Ylide Generation by Electrochemical Reduction of a Sulfonium Salt
pp. 1
Uncatalyzed Addition of Alcohols
pp. 1
Synthesis Using Sodium Hydroxide, Dimethyl Sulfate, and Tetrabutylammonium Iodide
pp. 1
Alkenation of Aldose Derivatives
pp. 1
The Mitsunobu Procedure
pp. 1
Manganese-Mediated Asymmetric Epoxidation
pp. 1
Synthesis Using Allyl Bromide, Dibutyltin Oxide, and Tetrabutylammonium Iodide
pp. 1
Formation of the C—O Bond
pp. 1
Synthesis from Vicinal Hydroxy Sulfonates
pp. 1
Using Selenium-, Phosphorus-, or Sulfur-Containing Oxidants
pp. 1
Eschenmoser–Claisen Rearrangement
pp. 1
Electrocyclization/Diels–Alder Cycloaddition
pp. 1
Alcohol Alkylation
pp. 1
Radical Reduction of Anomeric Thiobenzoates and Thiofuranosides
pp. 1
O-Alkylation of Metal Complexes
pp. 1
Additions to Glycals
pp. 1
Reaction of Ketones and α-Oxo Esters
pp. 1
Synthesis Using Allyl Bromide and Sodium Hydride
pp. 1
Alkene Metathesis Routes
pp. 1
Ring Expansions and Contractions of Cyclic Ethers
pp. 1
Synthesis of Seven-Membered Oxacycloalk-3-enes
pp. 1
Palladium Catalyzed Intramolecular Allylic Alkylation Cyclizations to Eight-, Nine-, and Ten-Membered Oxacycloalk-3-enes
pp. 1
Lithiation
pp. 1
[2 + 2 + 2] Cycloaddition of Acetylene -Glycosides
pp. 1
2,5-Dihydrofurans
pp. 1
Addition of Grignard Reagents
pp. 1
Electrochemical Alkoxylation of Alkenes
pp. 1
Synthesis of Cyclic Tertiary Ethers and Spirocycles
pp. 1
Addition of Heteroatom-Substituted Anions
pp. 1
The Tandem Tebbe/Claisen Approach
pp. 1
Regioselective Activation and Cyclization
pp. 1
Nucleophilic Additions to Aldoses
pp. 1
Synthesis from Alcohols Using Carbodiimides
pp. 1
To Conjugated Alkenes
pp. 1
Synthesis Using Carbonates as Base
pp. 1
With Other Oxidants
pp. 1
Synthesis Using a Thallium Alkoxide and Iodomethane
pp. 1
Using Perhydrates/α-Hydroperoxy Compounds
pp. 1
Ruthenium-Mediated Epoxidation
pp. 1
Construction of Tricyclic Fused Benzo-3-oxacycles via Intramolecular [2 + 2 + 2] Cyclotrimerization of Triynes
pp. 1
Ketone Deoxygenations
pp. 1
Cyclization of 2,3-Allenols with Various Electrophiles as Catalysts
pp. 1
Synthesis of Benzyl Ethers
pp. 1
Of Conjugated Alkenes
pp. 1
1,4-Anhydropentitols
pp. 1
Proton-Catalyzed Ring Closure
pp. 1
Stereoselective Synthesis of 3,6-Dihydro-2-pyrans by [4 + 2] Annulation between Allylsilanes and Aldehydes
pp. 1
1,3-Elimination from Halohydrins
pp. 1
Synthesis from 3,6-Anhydroheptonic Derivatives
pp. 1
Transetherification
pp. 1
Synthesis of Aldonic Acid Derivatives
pp. 1
Allylstannane Addition
pp. 1
Synthesis of Acyclic Ethers by Reduction of Aldehydes or Ketones
pp. 1
Using Oxone and Non-Carbohydrate-Derived Chiral Ketones
pp. 1
Oxidation of C—H Bonds
pp. 1
Electrolytic Reduction
pp. 1
The Silyl-Prins Reaction
pp. 1
Intramolecular Oxidative Cyclization of Alcohols
pp. 1
Using Trifluoromethanesulfonates
pp. 1
Oxygen Alkylation
pp. 1
Diastereoselective Methods: Alkene Controlled
pp. 1
Using Oxaziridinium Salts
pp. 1
1,4-Elimination of Sulfonic Esters
pp. 1
Sulfur Alkylation
pp. 1
By Reaction of an Ylide Generated by Addition of a Nucleophile to a Vinylsulfonium Salt
pp. 1
Methanolysis Promoted by Resin-Supported 4-Toluenesulfonic Acid
pp. 1
Synthesis of 3-Allyl-2,5-dihydrofurans by Palladium(II) Chloride Catalyzed Coupling–Cyclization Reaction of 2,3-Allenols with Allylic Halides
pp. 1
2,3-Anhydrohexitols
pp. 1
Silver(I)-Catalyzed Ring Closure of 2,3-Allenols
pp. 1
Addition of a Diazo Compound
pp. 1
Synthesis of Product Subclass 1
pp. 1
Vanadium-Mediated Asymmetric Epoxidation
pp. 1
Synthesis Mediated by Group 5 Metals
pp. 1
Double Katsuki–Sharpless Epoxidation
pp. 1
Silver(I)-Catalyzed Rearrangement–Cyclization of 4-Hydroxypropargyl Esters
pp. 1
Lewis Acid Promoted [4 + 2] Annulation between Allylsilanes and Aldehydes
pp. 1
Radical Addition to C2
pp. 1
Reaction of Lactones
pp. 1
Simultaneous Deprotection of a Diphenylmethyl Ester and Ether in the Presence of an -Benzyloxycarbonyl Group
pp. 1
Palladium(0)-Catalyzed C—C Coupling Reactions with Glycal Derivatives
pp. 1
Reaction of Cyclic Acetals
pp. 1
Triphenylphosphine-Induced Ring Contraction of 3,6-Dihydro-1,2-dioxins
pp. 1
C-Glycosylation Using 2-Nitroglycal Derivatives
pp. 1
Deprotection of Allyl Ethers
pp. 1
Synthesis from Sulfonium and Selenonium Salts
pp. 1
Synthesis of Acyclic Ethers by Reduction of Esters
pp. 1
[3 + 2]-Cycloaddition Reactions of Carbonyl Ylides to Alkynes
pp. 1
Pentofuranosyl Cyanides
pp. 1
Addition an α-Halo Anion
pp. 1
Conversion of Pentoses into 2,5-Anhydropentoses
pp. 1
Hydride Addition to 1,2-Anhydropyranoses (Brigl's Anhydrides)
pp. 1
Addition of an α-Sulfoximidoylmethyl Anion
pp. 1
Reaction of Fluoroalkenes
pp. 1
From Alkyl Ethers
pp. 1
From Allylic Ethers
pp. 1
From Enolates of β-Carbonyl Ethers
pp. 1
Synthesis from Diazo Compounds
pp. 1
Reaction with Trityl Chloride and 1,8-Diazabicyclo[5.4.0]undec-7-ene
pp. 1
-Furanosides
pp. 1
Synthesis from Alcohols Using Pentavalent Phosphorus Reagents
pp. 1
7-Oxabicyclo[2.2.1]hept-2-enes
pp. 1
Amine Alkylation
pp. 1
Polymerizations of Epoxides
pp. 1
Via 2-(Chloromethyl)oxirane
pp. 1
Asymmetric Enolate Alkylation/Ring-Closing Metathesis Strategy
pp. 1
Under Solvent-Free Conditions
pp. 1
Diol Deoxygenation Using Sodium Naphthalenide
pp. 1
Ring-Opening/Closing Metathesis
pp. 1
Synthesis of Triarylmethyl Ethers
pp. 1
1,2-Anhydropentitols
pp. 1
Using Oxaziridines
pp. 1
Ireland–Claisen Rearrangement
pp. 1
Deamination of 1-Amino-1-deoxyhexitols
pp. 1
Allyl Ethers
pp. 1
Electrophilic Glycosidation of Arene and Hetarene Derivatives
pp. 1
Claisen Rearrangement of Oxazoles
pp. 1
Arenediazonium Coupling Reactions
pp. 1
Ring Opening of Oxetanes
pp. 1
Dissolved-Metal Reduction
pp. 1
Reaction of Trityl Chloride with 2,4,6-Collidine and Tetrabutylammonium Perchlorate
pp. 1
Radical Reduction of Hexopyranosyl Halides
pp. 1
Multiple Cyclizations of Polyepoxides
pp. 1
1,5-Anhydropentitols
pp. 1
Addition of Silyl Enol Ethers and Metal Enolates
pp. 1
Addition of an α-Selenonylalkyl Anion
pp. 1
Sodium Borohydride Reduction
pp. 1
Intramolecular Radical C-Glycosidation
pp. 1
Selenium-Reagent-Catalyzed Tandem Alkoxyselanylation–Oxidative Deselanylation
pp. 1
C-Glycosylation Using Pyranosylsamarium Diiodides
pp. 1
Synthesis by Modification of Oxetanes at the Periphery
pp. 1
Intramolecular Reaction
pp. 1
Addition of a Sulfonium or Sulfoxonium Ylide
pp. 1
Ylide Generation by Decarboxylation of a Sulfonium Salt
pp. 1
Insertion of Methylene into Oxiranes
pp. 1
Using Sodium Hydride and Benzyl Halides with Catalytic Amounts of a Tetraalkylammonium Iodide
pp. 1
Synthesis Using 4-Methoxybenzyl Chloride and Sodium Hydride
pp. 1
Two-Step Reduction Utilizing an -Alkyl Thioester
pp. 1
Reductive Formation of a C—C Bond at the α-Carbon
pp. 1
1,2:4,5-Dianhydropentitols
pp. 1
1,4:2,3-Dianhydrohexitols
pp. 1
Synthesis of Tetra- and Pentasubstituted 4-Halo-3,6-dihydro-2-pyrans by Iron(III) Halide Catalyzed Prins Cyclization of Silylated Homopropargylic Alcohols and Aldehydes
pp. 1
3,4-Dihydro-1-2-benzopyrans
pp. 1
Synthesis by Ring Expansion
pp. 1
Synthesis by Thermal [2+2] Cycloaddition
pp. 1
Synthesis by Ferrier Reaction of Oxacycloalk-2-enes
pp. 1
Fries-Like Rearrangements
pp. 1
-Tetrofuranosides
pp. 1
Synthesis of Product Subclass 2
pp. 1
Furan–Phenyl Ethenesulfonate Cycloadditions
pp. 1
Lactone Functionalization
pp. 1
Synthesis from Vicinal Diols
pp. 1
Tandem Catalytic Ring-Closing Metathesis
pp. 1
2,3-Anhydrotetritols
pp. 1
Other Methods
pp. 1
Synthesis of Allyl Ethers
pp. 1
Using Methanesulfonates
pp. 1
Carbon Alkylation
pp. 1
Synthesis from Sulfonic and Sulfuric Acid Esters
pp. 1
-Disaccharides
pp. 1
Synthesis by Ring-Closure Reactions
pp. 1
Synthesis from Cyclic Acetals and Derivatives
pp. 1
Synthesis Mediated by Group 4 Metals
pp. 1
Lewis Acid Catalyzed Coupling of Propargylsilanes
pp. 1
Mitsunobu Reaction
pp. 1
Lewis Acid Mediated Diels–Alder Cyclizations of Furans and Monoactivated Alkenes
pp. 1
Formation of the C—C Bond at C2
pp. 1
Use of Nonchiral Ruthenium and Molybdenum Catalysts
pp. 1
Addition of Thiazole to γ-Pentonolactones
pp. 1
Addition of an Arsonium Ylide
pp. 1
Diels–Alder Cycloaddition of Furan with Highly Reactive Alkene Dienophiles
pp. 1
C-Glycosylation Using Pyranosyl Halides
pp. 1
Epoxidation of Allylic Alcohols
pp. 1
Hydrogen Chloride Elimination
pp. 1
Ylide Generation by Addition of an Arsine to a Metal Carbenoid
pp. 1
2,3-Anhydropentitols
pp. 1
Ylide Generation by Transylidation of a Phosphonium Ylide
pp. 1
Of Isolated Alkenes
pp. 1
Functional-Group Transformation
pp. 1
Synthesis of 4-Halo-3,6-dihydro-2-pyrans via Lewis Acid Promoted Cyclization of Acetals of Homopropargylic Alcohols
pp. 1
Synthesis of 5-Allyl-3,6-dihydro-2-pyrans via the Palladium-Catalyzed Cyclizative Coupling Reaction of 3,4-Allenols with Allyl Bromide
pp. 1
Transition Metal Complex Catalyzed [2 + 2 + 2] Cyclotrimerization of Alkynes
pp. 1
Synthesis Using Tertiary Amines as Base
pp. 1
With Lithium Aluminum Hydride
pp. 1
1,4-Anhydrohexitols
pp. 1
Synthesis Using Tin Compounds
pp. 1
1,6-Anhydrohexitols (Oxepanes)
pp. 1
Synthesis by Nucleophilic Attack on a Mixed Trialkyloxonium Ion
pp. 1
-Pyranosides
pp. 1
Using Oxone or Hydrogen Peroxide and Fructose-Derived Chiral Ketones
pp. 1
Electrophilic Haloetherification
pp. 1
Rhenium-Mediated Epoxidation with Hydrogen Peroxide
pp. 1
Alkylation of Acetals
pp. 1
Synthesis from Vicinal Halohydrins
pp. 1
Ylide Generation by Desilylation of a Sulfonium Salt
pp. 1
Other Allylation Methods
pp. 1
Carboxylic Acid Esterification
pp. 1
Synthesis from 3-Amino Alcohols
pp. 1
Synthesis Using Silver(I) Oxide as Base
pp. 1
Reductive Formation of a C—H Bond at the α-Carbon
pp. 1
Radical Addition of C2
pp. 1
1,5-Anhydroalditols
pp. 1
Two-Step Reduction Utilizing an α-Acetoxy Ether
pp. 1
Intermolecular Addition of Alcohols
pp. 1
High-Pressure Diels–Alder Cyclizations of Furans and Activated Alkenes
pp. 1
Lewis Acid Catalyzed Coupling of But-2-yne-1,4-diyldisilanes
pp. 1
Using Peroxycarbamic Acids
pp. 1
Synthesis from Ammonium Salts
pp. 1
Dehydration of Hexonolactones and Subsequent Reduction
pp. 1
Stereoselective Photoalkoxylation of Alkenes
pp. 1
C-Glycosylation Using Glycal Epoxides (Brigl's Anhydrides)
pp. 1
Synthesis Using 4-Methoxybenzyl Trichloroacetimidate
pp. 1
Of Allenes
pp. 1
Induced by Iodine Reagents
pp. 1
Molybdenum-Mediated Asymmetric Epoxidation
pp. 1
Synthesis of Aryldihydropyrans by Phenylselanyletherification–Oxidation
pp. 1
Using Other Peracids
pp. 1
Anomeric Reduction of Hexofuranose Derivatives
pp. 1
Cationic C-Glycosidation with Pentofuranosyl Derivatives
pp. 1
Electrochemically Promoted Anomeric Reduction
pp. 1
Substitution of Pent-4-enyl Ethers
pp. 1
3,6-Dihydro-2-pyrans
pp. 1
Deprotection of Triarylmethyl Ethers
pp. 1
From Diazo Carbonyl Compounds
pp. 1
Sharpless Asymmetric Dihydroxylation
pp. 1
Synthesis Using Hydroxides as Base
pp. 1
General Reaction
pp. 1
Synthesis of 2-Alkyl-4-halo-3,6-dihydro-2-pyrans by Iron(III) Halide Catalyzed Prins-Type Cyclization of Homopropargylic Alcohols and Aldehydes
pp. 1
Ring Contraction by 1,3-Elimination of Sulfonic Esters
pp. 1
Miscellaneous Methods
pp. 1
Nucleophilic C-Glycosylation
pp. 1
Synthesis by Salt Exchange
pp. 1
Sulfide Reactions
pp. 1
Reaction with Diazo(diphenyl)methane under Reflux
pp. 1
1,2:5,6-Dianhydrohexitols
pp. 1
Addition to 1,3:2,5-Dianhydrohexitol Derivatives
pp. 1
From Diazoalkanes
pp. 1
Electrophilic Addition of C2
pp. 1
Synthesis from Trichloroacetimidates
pp. 1
Synthesis of Alkyl Ethers from Vinylic Ethers
pp. 1
Total Syntheses via [4 + 3] Cycloadditions of Furan
pp. 1
Synthesis Using Dibutyltin Oxide
pp. 1
Addition to Alkenes
pp. 1
Manganese-Mediated Epoxidation with Hydrogen Peroxide
pp. 1
Synthesis Using Allyl Bromide and Potassium Carbonate
pp. 1
Katsuki–Sharpless Asymmetric Epoxidation
pp. 1
Hydride Reduction of Hexopyranosyl Halides
pp. 1
Ketone O-Alkylation
pp. 1
1,4:2,3-Dianhydroalditols
pp. 1
1,3-Anhydrohexitols
pp. 1
Ring Opening of Epoxides and Other Cyclic Ethers
pp. 1
By Reaction of an Ylide Generated by Deprotonation of a Sulfonium Salt
pp. 1
Using Dialkyl Sulfates
pp. 1
Imine Alkylation
pp. 1
Benzyl Ethers
pp. 1
With Stoichiometric Lewis Acid
pp. 1
Using 3-Methyl-3-(trifluoromethyl)dioxirane
pp. 1
Titanium-Mediated Asymmetric Epoxidation with Alkyl Hydroperoxides
pp. 1
With Alkoxyhydrosilanes
pp. 1
Synthesis from α-Diazo Ketones
pp. 1
Double 1,3-Elimination from 1,5-Dibromo-1,5-dideoxypentitols
pp. 1
With Hydrogen Peroxide
pp. 1
The "Naked Sugars" as Chirons
pp. 1
1,5-Anhydrohexitols
pp. 1
Tungsten-Mediated Epoxidation with Hydrogen Peroxide
pp. 1
From Benzylic Ethers
pp. 1
Ortho Ester Pyrolysis
pp. 1
Selective Reaction of Primary Alcohols Using a Bis(acetylacetonato)copper(II) Catalyst
pp. 1
Synthesis from Unprotected or Semiprotected Pyranoses
pp. 1
Chromium-Mediated Epoxidation
pp. 1
Synthesis Using Alkylzinc Reagents
pp. 1
1,4-Anhydroalditols
pp. 1
Under Free-Radical Conditions
pp. 1
Corey's Epoxidation of Aldoses
pp. 1
Addition of Allylsilane Reagents
pp. 1
Addition of an α-Sulfimidoylmethyl Anion
pp. 1
Homo--nucleosides and Analogues
pp. 1
1,5:2,3-Dianhydrohexitols
pp. 1
[2 + 2] Cycloaddition
pp. 1
Synthesis of Product Subclass 3
pp. 1
Synthesis from Phosphonium Salts
pp. 1
Palladium-Catalyzed C—C Couplings
pp. 1
Other Transformations from Enol Ethers
pp. 1
Acid-Catalyzed Dehydration of Hexitols
pp. 1
Hydroxy Ketone or Hemiacetal Cyclization
pp. 1
Synthesis of Product Subclass 1
pp. 1
Using Selenonium Ylides Generated by Conjugate Addition to Vinylselenonium Salts
pp. 1
Thiocarbonyl S-Alkylation
pp. 1
With Alcohols in the Presence of Base
pp. 1
2,5-Anhydrohexitols
pp. 1
Titanium-Mediated Epoxidation with Alkyl Hydroperoxides
pp. 1
Synthesis Using Meerwein's Reagent
pp. 1
Synthesis of Product Subclass 2
pp. 1
-Glycosides
pp. 1
Using Oxone and Oxazolidinone-Containing Chiral Ketones
pp. 1
Deoxygenation Using Zinc and Sodium Iodide
pp. 1
Using Peroxyisoureas
pp. 1
Heck-Type Coupling Reactions
pp. 1
Radical C-Glycosidation
pp. 1
Ring-Closing Metathesis of Dienes
pp. 1
3,4-Anhydrohexitols
pp. 1
1,2-Anhydrotetritols
pp. 1
Diarylmethyl Ethers
pp. 1
1,2-Wittig Rearrangement
pp. 1
From Propargylic Ethers
pp. 1
Using Dibutyltin Oxide
pp. 1
Intermolecular Hydrogen Peroxide Activation
pp. 1
Synthesis from Vicinal Acyloxy Sulfonates
pp. 1
1,5-Elimination of Sulfonic Esters
pp. 1
Deamination of 1-Amino-1-deoxypentitols
pp. 1
Synthesis Using Silver(I) Oxide and Iodomethane
pp. 1
Butyllithium-Induced Rearrangement of Allyl 2,2-Dichlorovinyl Ethers
pp. 1
Formation of Five- and Six-Membered Oxacycloalk-3-enes Using Ruthenium Catalysts
pp. 1
In Situ Formation of Acetals, Followed by Reductive Cleavage
pp. 1
Oxetanes
pp. 1
Electrophilic C-Glycosylation
pp. 1
2,5-Anhydroalditols
pp. 1
Nitrogen Alkylation
pp. 1
Molybdenum-Mediated Epoxidation with Alkyl Hydroperoxides
pp. 1
Synthesis Using Arylboron Reagents
pp. 1
Methyl Ethers
pp. 1
Chloromethylation of 2-Phenylethanols Followed by Cyclization
pp. 1
Addition of Organocuprate Reagents
pp. 1
With a Catalytic Manganese Complex
pp. 1
Radical C-Glycosidation: Synthesis of Showdomycin
pp. 1
Rearrangement of Butynediol Monobenzoates Catalyzed by Gold(I)
pp. 1
The Sharpless Procedure
pp. 1
Synthesis by Nucleophilic Attack on Dimethoxycarbenium Tetrafluoroborate
pp. 1
Substitution of Benzylic Ethers
pp. 1
Diastereoselective Additions by Selenium Reagent Control
pp. 1
Synthesis from Homoallylic Alcohols
pp. 1
C-Glycosylation Using Glycosylidene Carbene Intermediates and Analogues
pp. 1
Trimethylsilyl Cyanide Addition
pp. 1
From Halo Alcohols
pp. 1
Ring Closure by Chalcogen Alkylation
pp. 1
Preparation of Volatile Epoxides
pp. 1
Reaction with Formic Acid in Diethyl Ether
pp. 1
1,6-Elimination of Sulfonic Esters
pp. 1
Synthesis Mediated by Late Transition Metals (Groups 9–11)
pp. 1
Hydrogenolysis Using a Palladium Catalyst
pp. 1
Addition of a Selenonium Ylide
pp. 1
Intramolecular Addition of Alcohols
pp. 1
Oxetan-3-ols
pp. 1
Synthesis from Allylic Alcohols
pp. 1
C-Glycosylation Using Glycal-Derived Sulfonium Ions
pp. 1
Ring-Closing Alkene Metathesis
pp. 1
Nucleophilic Displacement of 1-Iodo-1-deoxyalditol Derivatives
pp. 1
Electrophilic Alkoxyselanylation
pp. 1
Synthesis by Nucleophilic Attack on Acyldialkyl Cations
pp. 1
Double 1,3-Elimination
pp. 1
Synthesis from Esters of Phosphorus Acids
pp. 1
Synthesis by Nucleophilic Attack on Diazomethane
pp. 1
1,4:2,3-Dianhydropentitols
pp. 1
Transition-Metal-Catalyzed Allylic Etherification
pp. 1
Allylsilane, But-2-enylsilane, and Silyl Ketene Acetal Addition
pp. 1
Polymerizations of Oxetanes, Tetrahydrofuran, and Oxepane
pp. 1
Furan–Maleic Anhydride and Furan–Maleimide Cycloadditions
pp. 1
Williamson-Type Reaction of Alkyl Halides
pp. 1
With Borane–Dimethyl Sulfide Complex
pp. 1
Ireland–Claisen Rearrangement
pp. 1
In Situ Sulfonylation of a Hydroxy Group
pp. 1
Synthesis from Dianhydrohexitols
pp. 1
Synthesis from Enol Ethers
pp. 1
Synthesis of Acyclic Ethers by Reduction of Acetals
pp. 1
Addition of a Telluronium Ylide
pp. 1
Aryl -Pentafuranosides
pp. 1
Reduction of Acetals
pp. 1
Synthesis of Ethers from Alcohols by Lewis Acids and Transition-Metal Complexes
pp. 1
Synthesis of Oxacycloalk-3-enes by Elimination/Deoxygenation Reactions
pp. 1
Deprotection of Benzyl Ethers
pp. 1
Hetero-Diels–Alder Cycloadditions
pp. 1
Room-Temperature Benzylation
pp. 1
Synthesis by a Two-Step Procedure Utilizing an α-Acetoxy Ether
pp. 1
Synthesis Using Tetrabutylammonium Fluoride
pp. 1
Synthesis by Nucleophilic Attack on Iodomethane
pp. 1
Palladium-Catalyzed Addition to Alkenes
pp. 1
Intramolecular Cyclization of 2,3-Allenols Using Gold(III) Chloride as Catalyst
pp. 1
Formation of Five-Membered Rings Using Molybdenum Catalysts
pp. 1
Amide Alkylation
pp. 1
Using Other Achiral Dioxiranes
pp. 1
Synthesis of 4-Methoxybenzyl Ethers
pp. 1
Reaction of Ketene Acetals
pp. 1
Epoxidation of Enepentitol Derivatives
pp. 1
Asymmetric Ring-Opening Metathesis/Ring-Closing Metathesis
pp. 1
Metal Hydride Reduction
pp. 1
Cleavage with Lithium Metal
pp. 1
-Glycosides via the Ramberg–Bäcklund Reaction
pp. 1
Lewis Acid Catalyzed Cyclization of 3,4-Allenols
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