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      Constraining the formation and transport of lunar impact glasses using the ages and chemical compositions of Chang’e-5 glass beads

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          Abstract

          Impact glasses found in lunar soils provide a possible window into the impact history of the inner solar system. However, their use for precise reconstruction of this history is limited by an incomplete understanding of the physical mechanisms responsible for their origin and distribution and possible relationships to local and regional geology. Here, we report U-Pb isotopic dates and chemical compositions of impact glasses from the Chang’e-5 soil and quantitative models of impact melt formation and ejection that account for the compositions of these glasses. The predominantly local provenance indicated by their compositions, which constrains transport distances to <~150 kilometers, and the age-frequency distribution are consistent with formation mainly in impact craters 1 to 5 kilometers in diameter. Based on geological mapping and impact cratering theory, we tentatively identify specific craters on the basaltic unit sampled by Chang’e-5 that may have produced these glasses and compare their ages with the impact record of the asteroid belt.

          Abstract

          The chronology of Chang’e-5 impact glasses suggests a dynamical link between lunar impacts and collisions in the asteroid belt.

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          Most cited references81

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          Correction of common lead in U–Pb analyses that do not report 204Pb

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            Volatile content of lunar volcanic glasses and the presence of water in the Moon's interior.

            The Moon is generally thought to have formed and evolved through a single or a series of catastrophic heating events, during which most of the highly volatile elements were lost. Hydrogen, being the lightest element, is believed to have been completely lost during this period. Here we make use of considerable advances in secondary ion mass spectrometry to obtain improved limits on the indigenous volatile (CO(2), H(2)O, F, S and Cl) contents of the most primitive basalts in the Moon-the lunar volcanic glasses. Although the pre-eruptive water content of the lunar volcanic glasses cannot be precisely constrained, numerical modelling of diffusive degassing of the very-low-Ti glasses provides a best estimate of 745 p.p.m. water, with a minimum of 260 p.p.m. at the 95 per cent confidence level. Our results indicate that, contrary to prevailing ideas, the bulk Moon might not be entirely depleted in highly volatile elements, including water. Thus, the presence of water must be considered in models constraining the Moon's formation and its thermal and chemical evolution.
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              On the Treatment of Concordant Uranium-Lead Ages

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                Author and article information

                Contributors
                Journal
                Science Advances
                Sci. Adv.
                American Association for the Advancement of Science (AAAS)
                2375-2548
                September 30 2022
                September 30 2022
                : 8
                : 39
                Affiliations
                [1 ]Beijing SHRIMP Center, Institute of Geology, Chinese Academy of Geological Sciences, Beijing 100037, China.
                [2 ]Planetary Science Institute, School of Earth Sciences, China University of Geosciences, Wuhan 430074, China.
                [3 ]Research School of Earth Sciences, The Australian National University, Canberra, ACT 2601 Australia.
                [4 ]School of Earth and Planetary Sciences, Curtin University, GPO Box U1987, Perth, WA 6845, Australia.
                [5 ]Department of Geological Sciences, University of Colorado Boulder, Boulder, CO 80309, USA.
                [6 ]Department of Earth, Environmental, and Planetary Sciences, Brown University, Providence, RI 02912, USA.
                [7 ]Department of Earth and Environmental Sciences, The University of Manchester, Manchester, M13 9PL, UK.
                [8 ]Department of Physics, Albion College, Albion, MI 49224, USA.
                [9 ]Shandong Institute of Geological Sciences, Jinan, Shandong 250013, China.
                [10 ]Department of Geosciences, Swedish Museum of Natural History, SE-104 05 Stockholm, Sweden.
                [11 ]Department of Civil and Environmental Engineering and Earth Sciences, University of Notre Dame, Notre Dame, IN 46556, USA.
                Article
                10.1126/sciadv.abq2542
                d13c11e7-c582-4310-98f7-34abaa280623
                © 2022
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