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      Residues, Distributions, Sources, and Ecological Risks of OCPs in the Water from Lake Chaohu, China

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          Abstract

          The levels of 18 organochlorine pesticides (OCPs) in the water from Lake Chaohu were measured by a solid phase extraction-gas chromatography-mass spectrometer detector. The spatial and temporal distribution, possible sources, and potential ecological risks of the OCPs were analyzed. The annual mean concentration for the OCPs in Lake Chaohu was 6.99 ng/L. Aldrin, HCHs, and DDTs accounted for large proportions of the OCPs. The spatial pollution followed the order of Central Lakes > Western Lakes > Eastern Lakes and water area. The sources of the HCHs were mainly from the historical usage of lindane. DDTs were degraded under aerobic conditions, and the main sources were from the use of technical DDTs. The ecological risks of 5 OCPs were assessed by the species sensitivity distribution (SSD) method in the order of heptachlor >  γ -HCH > p,p′-DDT > aldrin > endrin. The combining risks of all sampling sites were MS > JC > ZM > TX, and those of different species were crustaceans > fish > insects and spiders. Overall, the ecological risks of OCP contaminants on aquatic animals were very low.

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          Differential Toxicity and Environmental Fates of Hexachlorocyclohexane Isomers

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            Contribution of dicofol to the current DDT pollution in China.

            High DDT concentrations and o,p'-DDT/p,p'-DDT ratios observed in the air over Taihu Lake, a lake near Shanghai, China, led us to suggest that current use of dicofol in the area north of the lake was the main source of the measured DDTs. To examine this hypothesis, samples of commercially available formulated dicofol in China were collected in 2003 to measure the impurities of DDT related compounds (DDTs). The o,p'-DDT/p,p'-DDT ratio in the samples was 7.0, close to the observed value in the air over Taihu Lake. Average contents of o,p'-DDT, p,p'-CI-DDT, o,p'-DDE, and p,p'-DDT in the samples were 114, 69, 44, and 17 g per kg dicofol, respectively. On the basis of a production and distribution survey, total input of DDTs to the environment from the dicofol use in China was estimated to be 8770 t between 1988 and 2002. "Dicofol type DDT pollution", defined as DDT pollution caused by dicofol use and characterized with high o,p'-DDT/p,p'-DDT ratio, might be serious in China, especially in southern and eastern China. The conversion of p,p'-CI-DDT to p,p'-DDE can lead to high p,p'-DDE/p,p'-DDT ratio and could mislead the evaluation of p,p'-DDT resident time in the environment. Therefore, more studies on p,p'-CI-DDT in the environment are needed.
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              Factors Influencing the Distribution of Lindane and Other Hexachlorocyclohexanes in the Environment

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                Author and article information

                Journal
                ScientificWorldJournal
                ScientificWorldJournal
                TSWJ
                The Scientific World Journal
                The Scientific World Journal
                1537-744X
                2012
                28 November 2012
                : 2012
                : 897697
                Affiliations
                MOE Laboratory for Earth Surface Processes, College of Urban and Environmental Sciences, Peking University, Beijing 100871, China
                Author notes

                Academic Editors: G.-C. Fang and G. O. Thomas

                Article
                10.1100/2012/897697
                3515910
                23251107
                000be377-86a2-47bc-881c-54cc1b768652
                Copyright © 2012 Wen-Xiu Liu et al.

                This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

                History
                : 29 August 2012
                : 23 September 2012
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