Brønsted acid/visible-light-promoted Markovnikov hydroamination of vinylarenes with arylamines.

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Abstract

A Brønsted acid/visible-light-promoted Markovnikov hydroamination of vinylarenes with arylamines in the presence of TPT and CF3CO2H has been developed. This transformation provides a green approach to alpha-amino-substituted arylalkanes under metal-free conditions.

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Journal

Journal ID (iso-abbrev): Org Biomol Chem

Title: Organic & biomolecular chemistry

Publisher: Royal Society of Chemistry (RSC)

ISSN (Electronic): 1477-0539

ISSN (Print): 1477-0520

Publication date (Electronic): February 07 2020

Volume: 18

Issue: 5

Affiliations

[1 ] China Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, China. zengwei@scut.edu.cn.

[2 ] Guangdong Provincial Engineering Research Center for Modernization of TCM, College of Pharmacy, Jinan University, Guangzhou 510632, China.

[3 ] College of Chemistry, Beijing Normal University, Beijing 100875, China.

Article

DOI: 10.1039/c9ob02457c

PubMed ID: 31930235

SO-VID: 00529c0e-5671-47f0-9151-3c790e4ac831

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