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      Noninterpenetrating Square-Grid Coordination Polymers With Dimensions of 25×25 Å2 Prepared by UsingN,N′-Type Ligands: The First Chiral Square-Grid Coordination Polymer

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      Angewandte Chemie International Edition
      Wiley-Blackwell

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          Interpenetrating Nets: Ordered, Periodic Entanglement

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            Interwoven metal-organic framework on a periodic minimal surface with extra-large pores.

            Interpenetration (catenation) has long been considered a major impediment in the achievement of stable and porous crystalline structures. A strategy for the design of highly porous and structurally stable networks makes use of metal-organic building blocks that can be assembled on a triply periodic P-minimal geometric surface to produce structures that are interpenetrating-more accurately considered as interwoven. We used 4,4',4"-benzene-1,3,5-triyl-tribenzoic acid (H(3)BTB), copper(II) nitrate, and N,N'-dimethylformamide (DMF) to prepare Cu(3)(BTB)(2)(H(2)O)(3).(DMF)(9)(H(2)O)(2) (MOF-14), whose structure reveals a pair of interwoven metal-organic frameworks that are mutually reinforced. The structure contains remarkably large pores, 16.4 angstroms in diameter, in which voluminous amounts of gases and organic solvents can be reversibly sorbed.
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              Self-Assembly, Symmetry, and Molecular Architecture:  Coordination as the Motif in the Rational Design of Supramolecular Metallacyclic Polygons and Polyhedra

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                Author and article information

                Journal
                Angewandte Chemie International Edition
                Angew. Chem. Int. Ed.
                Wiley-Blackwell
                1433-7851
                1521-3773
                February 15 2002
                February 15 2002
                : 41
                : 4
                : 583-585
                Article
                10.1002/1521-3773(20020215)41:4<583::AID-ANIE583>3.0.CO;2-I
                01d4c6b3-9d57-4139-8e55-1d273adb93bb
                © 2002

                http://doi.wiley.com/10.1002/tdm_license_1.1

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