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      Catalytic asymmetric dearomatization (CADA) reactions of phenol and aniline derivatives

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          Abstract

          In this tutorial review, an up to date summary of recent progress in catalytic asymmetric dearomatization (CADA) reactions of phenol and aniline derivatives is presented.

          Abstract

          Phenols are widely used as starting materials in both industrial and academic society. Dearomatization reactions of phenols provide an efficient way to construct highly functionalized cyclohexadienones. The main challenge to make them asymmetric by catalytic methods is to control the selectivity while overcoming the loss of aromaticity. In this tutorial review, an up to date summary of recent progress in CADA reactions of phenol and aniline derivatives is presented.

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          Most cited references35

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          Catalytic Asymmetric Dearomatization Reactions

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            A Chiral Hypervalent Iodine(III) Reagent for Enantioselective Dearomatization of Phenols

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              Enantioselective Kita Oxidative Spirolactonization Catalyzed by In Situ Generated Chiral Hypervalent Iodine(III) Species

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                Author and article information

                Journal
                CSRVBR
                Chemical Society Reviews
                Chem. Soc. Rev.
                Royal Society of Chemistry (RSC)
                0306-0012
                1460-4744
                2016
                2016
                : 45
                : 6
                : 1570-1580
                Affiliations
                [1 ]State Key Laboratory of Organometallic Chemistry
                [2 ]Shanghai Institute of Organic Chemistry
                [3 ]Chinese Academy of Sciences
                [4 ]Shanghai 200032
                [5 ]China
                [6 ]Department of Chemistry & Biochemistry
                [7 ]University of California
                [8 ]Santa Barbara
                [9 ]USA
                Article
                10.1039/C5CS00356C
                26796922
                024359e3-5956-40f9-8d34-72c71420f47c
                © 2016
                History

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