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      Geopolymer Based on Mechanically Activated Air-cooled Blast Furnace Slag

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          Abstract

          An efficient solution to increase the sustainability of building materials is to replace Portland cement with alkali-activated materials (AAM). Precursors for those systems are often based on water-cooled ground granulated blast furnace slags (GGBFS). Quenching of blast furnace slag can be done also by air but in that case, the final product is crystalline and with a very low reactivity. The present study aimed to evaluate the cementitious properties of a mechanically activated (MCA) air-cooled blast furnace slag (ACBFS) used as a precursor in sodium silicate alkali-activated systems. The unreactive ACBFS was processed in a planetary ball mill and its cementing performances were compared with an alkali-activated water-cooled GGBFS. Mixes based on mechanically activated ACBFS reached the 7-days compressive strength of 35 MPa and the 28-days compressive strength 45 MPa. The GGBFS-based samples showed generally higher compressive strength values.

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          Most cited references33

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          Hallmarks of mechanochemistry: from nanoparticles to technology.

          The aim of this review article on recent developments of mechanochemistry (nowadays established as a part of chemistry) is to provide a comprehensive overview of advances achieved in the field of atomistic processes, phase transformations, simple and multicomponent nanosystems and peculiarities of mechanochemical reactions. Industrial aspects with successful penetration into fields like materials engineering, heterogeneous catalysis and extractive metallurgy are also reviewed. The hallmarks of mechanochemistry include influencing reactivity of solids by the presence of solid-state defects, interphases and relaxation phenomena, enabling processes to take place under non-equilibrium conditions, creating a well-crystallized core of nanoparticles with disordered near-surface shell regions and performing simple dry time-convenient one-step syntheses. Underlying these hallmarks are technological consequences like preparing new nanomaterials with the desired properties or producing these materials in a reproducible way with high yield and under simple and easy operating conditions. The last but not least hallmark is enabling work under environmentally friendly and essentially waste-free conditions (822 references).
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            Geopolymers and Related Alkali-Activated Materials

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              Compatibility studies between N-A-S-H and C-A-S-H gels. Study in the ternary diagram Na2O–CaO–Al2O3–SiO2–H2O

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                Author and article information

                Journal
                Materials (Basel)
                Materials (Basel)
                materials
                Materials
                MDPI
                1996-1944
                04 March 2020
                March 2020
                : 13
                : 5
                : 1134
                Affiliations
                Building Materials, Department of Civil, Environmental and Natural Resources Engineering, Luleå University of Technology, 97187 Luleå, Sweden; magdalena.rajczakowska@ 123456ltu.se (M.R.); abeer.humad@ 123456ltu.se (A.H.); ankit.kothari@ 123456ltu.se (A.K.); andrzej.cwirzen@ 123456ltu.se (A.C.)
                Author notes
                [* ]Correspondence: ilda.tole@ 123456ltu.se
                Author information
                https://orcid.org/0000-0002-6797-9300
                https://orcid.org/0000-0001-8039-692X
                https://orcid.org/0000-0002-5328-4073
                https://orcid.org/0000-0001-6287-2240
                Article
                materials-13-01134
                10.3390/ma13051134
                7085006
                32143319
                02e42d58-10bd-4f8c-b195-fb3df716cbbb
                © 2020 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 16 February 2020
                : 28 February 2020
                Categories
                Article

                mechanochemistry,alkali activation,air-cooled slag,ground granulated slag,mechanical activation,cement-free mortars

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