36
views
0
recommends
+1 Recommend
0 collections
    0
    shares
      • Record: found
      • Abstract: found
      • Article: found
      Is Open Access

      The mechanics and design of a lightweight three-dimensional graphene assembly

      research-article

      Read this article at

      Bookmark
          There is no author summary for this article yet. Authors can add summaries to their articles on ScienceOpen to make them more accessible to a non-specialist audience.

          Abstract

          The mechanics of a lightweight three-dimensional graphene assembly, quantified by computational simulation and 3D printing, are discussed.

          Abstract

          Recent advances in three-dimensional (3D) graphene assembly have shown how we can make solid porous materials that are lighter than air. It is plausible that these solid materials can be mechanically strong enough for applications under extreme conditions, such as being a substitute for helium in filling up an unpowered flight balloon. However, knowledge of the elastic modulus and strength of the porous graphene assembly as functions of its structure has not been available, preventing evaluation of its feasibility. We combine bottom-up computational modeling with experiments based on 3D-printed models to investigate the mechanics of porous 3D graphene materials, resulting in new designs of carbon materials. Our study reveals that although the 3D graphene assembly has an exceptionally high strength at relatively high density (given the fact that it has a density of 4.6% that of mild steel and is 10 times as strong as mild steel), its mechanical properties decrease with density much faster than those of polymer foams. Our results provide critical densities below which the 3D graphene assembly starts to lose its mechanical advantage over most polymeric cellular materials.

          Related collections

          Most cited references27

          • Record: found
          • Abstract: found
          • Article: found
          Is Open Access

          The rise of graphene

          Graphene is a rapidly rising star on the horizon of materials science and condensed matter physics. This strictly two-dimensional material exhibits exceptionally high crystal and electronic quality and, despite its short history, has already revealed a cornucopia of new physics and potential applications, which are briefly discussed here. Whereas one can be certain of the realness of applications only when commercial products appear, graphene no longer requires any further proof of its importance in terms of fundamental physics. Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed matter physics, where quantum relativistic phenomena, some of which are unobservable in high energy physics, can now be mimicked and tested in table-top experiments. More generally, graphene represents a conceptually new class of materials that are only one atom thick and, on this basis, offers new inroads into low-dimensional physics that has never ceased to surprise and continues to provide a fertile ground for applications.
            Bookmark
            • Record: found
            • Abstract: found
            • Article: not found

            Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition.

            Integration of individual two-dimensional graphene sheets into macroscopic structures is essential for the application of graphene. A series of graphene-based composites and macroscopic structures have been recently fabricated using chemically derived graphene sheets. However, these composites and structures suffer from poor electrical conductivity because of the low quality and/or high inter-sheet junction contact resistance of the chemically derived graphene sheets. Here we report the direct synthesis of three-dimensional foam-like graphene macrostructures, which we call graphene foams (GFs), by template-directed chemical vapour deposition. A GF consists of an interconnected flexible network of graphene as the fast transport channel of charge carriers for high electrical conductivity. Even with a GF loading as low as ∼0.5 wt%, GF/poly(dimethyl siloxane) composites show a very high electrical conductivity of ∼10 S cm(-1), which is ∼6 orders of magnitude higher than chemically derived graphene-based composites. Using this unique network structure and the outstanding electrical and mechanical properties of GFs, as an example, we demonstrate the great potential of GF/poly(dimethyl siloxane) composites for flexible, foldable and stretchable conductors. © 2011 Macmillan Publishers Limited. All rights reserved
              Bookmark
              • Record: found
              • Abstract: not found
              • Article: not found

              A second-generation reactive empirical bond order (REBO) potential energy expression for hydrocarbons

                Bookmark

                Author and article information

                Journal
                Sci Adv
                Sci Adv
                SciAdv
                advances
                Science Advances
                American Association for the Advancement of Science
                2375-2548
                January 2017
                06 January 2017
                : 3
                : 1
                : e1601536
                Affiliations
                [1 ]Laboratory for Atomistic and Molecular Mechanics, Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139, USA.
                [2 ]Center for Computational Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.
                Author notes
                [*]

                These authors contributed equally to this work.

                []Corresponding author. Email: mbuehler@ 123456mit.edu
                Article
                1601536
                10.1126/sciadv.1601536
                5218516
                04c516e5-2947-48d3-b35e-842d1c41ff61
                Copyright © 2017, The Authors

                This is an open-access article distributed under the terms of the Creative Commons Attribution-NonCommercial license, which permits use, distribution, and reproduction in any medium, so long as the resultant use is not for commercial advantage and provided the original work is properly cited.

                History
                : 06 July 2016
                : 16 November 2016
                Funding
                Funded by: FundRef http://dx.doi.org/10.13039/100000006, Office of Naval Research;
                Award ID: ID0EM1BG11663
                Award Recipient :
                Funded by: U.S. Department of Defense (US), MURI;
                Award ID: ID0ENIAI11664
                Award ID: MURI
                Award Recipient :
                Categories
                Research Article
                Research Articles
                SciAdv r-articles
                Materials Science
                Custom metadata
                Justine Rey Diego Noriel

                materials design,multiscale,graphene,additive manufacturing,mechanical properties,hierarchical,porous materials

                Comments

                Comment on this article