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      Two hybrid materials assembled from transition metal mono-substituted Keggin polyoxoanions as photocatalysts under visible light

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          Abstract

          Two novel hybrid materials assembled from transition metal mono-substituted Keggin polyoxoanions with an antenna molecule were obtained and exhibit photocatalytic activity under visible light.

          Abstract

          Two 2D isostructural organic–inorganic hybrid solid materials based on transition metal mono-substituted Keggin polyoxotungstate with an antenna molecule were synthesized under hydrothermal conditions. Compound 2 with the substituted Co( ii) exhibits good photocatalytic activity in the degradation of rhodamine-B (RB) under visible light irradiation.

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          Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials.

          Timothy R. Cook, Yao-Rong Zheng, Peter Stang (2013)
          Article 0 comments Cited 511 times – based on 0 reviews     Review now
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            Heteropoly and Isopoly Oxometalates

            Michael Thor Pope (1983)
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              Polyoxometalates: building blocks for functional nanoscale systems.

              De-Liang Long, Ryo Tsunashima, Leroy Cronin (2010)
              Polyoxometalates (POMs) are a subset of metal oxides that represent a diverse range of molecular clusters with an almost unmatched range of physical properties and the ability to form dynamic structures that can range in size from the nano- to the micrometer scale. Herein we present the very latest developments from synthesis to structure and function of POMs. We discuss the possibilities of creating highly sophisticated functional hierarchical systems with multiple, interdependent, functionalities along with a critical analysis that allows the non-specialist to learn the salient features. We propose and present a "periodic table of polyoxometalate building blocks". We also highlight some of the current issues and challenges that need to be addressed to work towards the design of functional systems based upon POM building blocks and look ahead to possible emerging application areas.
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                Author and article information

                Journal
                Journal ID (publisher-id): CRECF4
                Title: CrystEngComm
                Abbreviated Title: CrystEngComm
                Publisher: Royal Society of Chemistry (RSC)
                ISSN (Electronic): 1466-8033
                Publication date Created: 2014
                Publication date (Electronic): 2014
                Volume: 16
                Issue: 39
                Pages: 9163-9167
                Affiliations
                [1 ]Institute of Functional Material Chemistry
                [2 ]Key Laboratory of Polyoxometalate Science of Ministry of Education
                [3 ]Northeast Normal University
                [4 ]Changchun, People's Republic of China
                Article
                DOI: 10.1039/C4CE01148A
                SO-VID: 0623fa8c-3a5c-45c4-98f1-059a2c0c4437
                Copyright © © 2014
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