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      Practical water production from desert air

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          Abstract

          Next-generation MOF device and material for water production from desert air.

          Abstract

          Energy-efficient production of water from desert air has not been developed. A proof-of-concept device for harvesting water at low relative humidity was reported; however, it used external cooling and was not desert-tested. We report a laboratory-to-desert experiment where a prototype using up to 1.2 kg of metal-organic framework (MOF)–801 was tested in the laboratory and later in the desert of Arizona, USA. It produced 100 g of water per kilogram of MOF-801 per day-and-night cycle, using only natural cooling and ambient sunlight as a source of energy. We also report an aluminum-based MOF-303, which delivers more than twice the amount of water. The desert experiment uncovered key parameters pertaining to the energy, material, and air requirements for efficient production of water from desert air, even at a subzero dew point.

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          Most cited references17

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          Tuning the adsorption properties of UiO-66 via ligand functionalization.

          UiO-66 is one of the few known water-stable MOFs that are readily amenable to direct ligand substitution. In this work, UiO-66 has been synthesized with amino-, nitro-, methoxy-, and naphthyl-substituted ligands to impart polar, basic, and hydrophobic characteristics. Pure-component CO(2), CH(4), N(2), and water vapor adsorption isotherms were measured in the materials to study the effect of the functional group on the adsorption behavior. Heats of adsorption were calculated for each pure gas on each material. The results indicate that the amino-functionalized material possesses the best adsorption properties for each pure gas due to a combination of polarity and small functional group size. The naphthyl-functionalized material exhibits a good combination of inhibited water vapor adsorption and high selectivity for CO(2) over CH(4) and N(2).
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            Optimal design of permeable fiber network structures for fog harvesting.

            Fog represents a large untapped source of potable water, especially in arid climates. Numerous plants and animals use textural and chemical features on their surfaces to harvest this precious resource. In this work, we investigate the influence of the surface wettability characteristics, length scale, and weave density on the fog-harvesting capability of woven meshes. We develop a combined hydrodynamic and surface wettability model to predict the overall fog-collection efficiency of the meshes and cast the findings in the form of a design chart. Two limiting surface wettability constraints govern the re-entrainment of collected droplets and clogging of mesh openings. Appropriate tuning of the wetting characteristics of the surfaces, reducing the wire radii, and optimizing the wire spacing all lead to more efficient fog collection. We use a family of coated meshes with a directed stream of fog droplets to simulate a natural foggy environment and demonstrate a five-fold enhancement in the fog-collecting efficiency of a conventional polyolefin mesh. The design rules developed in this work can be applied to select a mesh surface with optimal topography and wetting characteristics to harvest enhanced water fluxes over a wide range of natural convected fog environments.
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              Fog as a fresh-water resource: overview and perspectives.

              The collection of fog water is a simple and sustainable technology to obtain fresh water for afforestation, gardening, and as a drinking water source for human and animal consumption. In regions where fresh water is sparse and fog frequently occurs, it is feasible to set up a passive mesh system for fog water collection. The mesh is directly exposed to the atmosphere, and the foggy air is pushed through the mesh by the wind. Fog droplets are deposited on the mesh, combine to form larger droplets, and run down passing into a storage tank. Fog water collection rates vary dramatically from site to site but yearly averages from 3 to 10 l m(-2) of mesh per day are typical of operational projects. The scope of this article is to review fog collection projects worldwide, to analyze factors of success, and to evaluate the prospects of this technology.
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                Author and article information

                Journal
                Sci Adv
                Sci Adv
                SciAdv
                advances
                Science Advances
                American Association for the Advancement of Science
                2375-2548
                June 2018
                08 June 2018
                : 4
                : 6
                : eaat3198
                Affiliations
                [1 ]Department of Chemistry, Kavli Energy NanoScience Institute, and Berkeley Global Science Institute, University of California, Berkeley, Berkeley, CA 94720, USA.
                [2 ]Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.
                [3 ]King Abdulaziz City for Science and Technology (KACST), Riyadh 11442, Saudi Arabia.
                Author notes
                [*]

                These authors contributed equally to this work.

                []Corresponding author. Email: yaghi@ 123456berkeley.edu
                Author information
                http://orcid.org/0000-0001-8123-3145
                http://orcid.org/0000-0002-4013-8827
                http://orcid.org/0000-0002-1192-7368
                http://orcid.org/0000-0002-5611-3325
                Article
                aat3198
                10.1126/sciadv.aat3198
                5993474
                29888332
                0871a826-9661-4a2e-a140-91c00732daa5
                Copyright © 2018 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC).

                This is an open-access article distributed under the terms of the Creative Commons Attribution-NonCommercial license, which permits use, distribution, and reproduction in any medium, so long as the resultant use is not for commercial advantage and provided the original work is properly cited.

                History
                : 15 February 2018
                : 24 April 2018
                Funding
                Funded by: German Research Foundation;
                Award ID: DFG, KA 4484/1-1
                Funded by: NSF and Berkely Center for Green Chemistry;
                Award ID: 1144885
                Categories
                Research Article
                Research Articles
                SciAdv r-articles
                Chemistry
                Physical Sciences
                Chemistry
                Custom metadata
                Rochelle Abragante

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