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      Anapole Modes in Hollow Nanocuboid Dielectric Metasurfaces for Refractometric Sensing

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          Abstract

          This work proposes the use of the refractive index sensitivity of non-radiating anapole modes of high-refractive-index nanoparticles arranged in planar metasurfaces as a novel sensing principle. The spectral position of anapole modes excited in hollow silicon nanocuboids is first investigated as a function of the nanocuboid geometry. Then, nanostructured metasurfaces of periodic arrays of nanocuboids on a glass substrate are designed. The metasurface parameters are properly selected such that a resonance with ultrahigh Q-factor, above one million, is excited at the target infrared wavelength of 1.55 µm. The anapole-induced resonant wavelength depends on the refractive index of the analyte superstratum, exhibiting a sensitivity of up to 180 nm/RIU. Such values, combined with the ultrahigh Q-factor, allow for refractometric sensing with very low detection limits in a broad range of refractive indices. Besides the sensing applications, the proposed device can also open new venues in other research fields, such as non-linear optics, optical switches, and optical communications.

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          Most cited references45

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          Planar metamaterial analogue of electromagnetically induced transparency for plasmonic sensing.

          We experimentally demonstrate a planar metamaterial analogue of electromagnetically induced transparency at optical frequencies. The structure consists of an optically bright dipole antenna and an optically dark quadrupole antenna, which are cut-out structures in a thin gold film. A pronounced coupling-induced reflectance peak is observed within a broad resonance spectrum. A metamaterial sensor based on these coupling effects is experimentally demonstrated and yields a sensitivity of 588 nm/RIU and a figure of merit of 3.8.
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            Nonradiating anapole modes in dielectric nanoparticles

            Nonradiating current configurations attract attention of physicists for many years as possible models of stable atoms. One intriguing example of such a nonradiating source is known as ‘anapole'. An anapole mode can be viewed as a composition of electric and toroidal dipole moments, resulting in destructive interference of the radiation fields due to similarity of their far-field scattering patterns. Here we demonstrate experimentally that dielectric nanoparticles can exhibit a radiationless anapole mode in visible. We achieve the spectral overlap of the toroidal and electric dipole modes through a geometry tuning, and observe a highly pronounced dip in the far-field scattering accompanied by the specific near-field distribution associated with the anapole mode. The anapole physics provides a unique playground for the study of electromagnetic properties of nontrivial excitations of complex fields, reciprocity violation and Aharonov–Bohm like phenomena at optical frequencies.
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              Label-free, single-molecule detection with optical microcavities.

              Current single-molecule detection techniques require labeling the target molecule. We report a highly specific and sensitive optical sensor based on an ultrahigh quality (Q) factor (Q > 10(8)) whispering-gallery microcavity. The silica surface is functionalized to bind the target molecule; binding is detected by a resonant wavelength shift. Single-molecule detection is confirmed by observation of single-molecule binding events that shift the resonant frequency, as well as by the statistics for these shifts over many binding events. These shifts result from a thermo-optic mechanism. Additionally, label-free, single-molecule detection of interleukin-2 was demonstrated in serum. These experiments demonstrate a dynamic range of 10(12) in concentration, establishing the microcavity as a sensitive and versatile detector.
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                Author and article information

                Journal
                Nanomaterials (Basel)
                Nanomaterials (Basel)
                nanomaterials
                Nanomaterials
                MDPI
                2079-4991
                27 December 2018
                January 2019
                : 9
                : 1
                : 30
                Affiliations
                [1 ]GDAF-UC3M, Displays and Photonics Applications Group, Department of Electronic Technology, Carlos III University of Madrid, Leganés, 28911 Madrid, Spain; brgarcia@ 123456ing.uc3m.es (B.G.-C.); rvergaz@ 123456ing.uc3m.es (R.V.); jmpena@ 123456ing.uc3m.es (J.M.S.-P.)
                [2 ]Consiglio Nazionale delle Ricerche, Istituto per la Microelettronica e Microsistemi, 00133 Rome, Italy; dimitrios.zografopoulos@ 123456artov.imm.cnr.it (D.C.Z.); antonio.ferraro@ 123456artov.imm.cnr.it (A.F.); romeo.beccherelli@ 123456artov.imm.cnr.it (R.B.)
                Author notes
                [* ]Correspondence: jalgorri@ 123456ing.uc3m.es ; Tel.: +34-916-245-964
                Author information
                https://orcid.org/0000-0002-2654-583X
                https://orcid.org/0000-0001-7499-5547
                https://orcid.org/0000-0003-0189-6729
                https://orcid.org/0000-0002-1231-0570
                https://orcid.org/0000-0002-2304-129X
                https://orcid.org/0000-0002-3768-726X
                https://orcid.org/0000-0002-5903-5967
                Article
                nanomaterials-09-00030
                10.3390/nano9010030
                6359158
                30591642
                0a571675-bb38-48e9-a34d-09c4ebb188b9
                © 2018 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 04 December 2018
                : 23 December 2018
                Categories
                Article

                dielectric nanoparticles,anapole mode,metasurfaces,sensing devices

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