18
views
0
recommends
+1 Recommend
0 collections
    0
    shares
      • Record: found
      • Abstract: not found
      • Article: not found

      Improved synthesis, thermal stability and catalytic properties of the metal-organic framework compound Cu3(BTC)2

      , ,
      Microporous and Mesoporous Materials
      Elsevier BV

      Read this article at

      ScienceOpenPublisher
      Bookmark
          There is no author summary for this article yet. Authors can add summaries to their articles on ScienceOpen to make them more accessible to a non-specialist audience.

          Related collections

          Most cited references12

          • Record: found
          • Abstract: found
          • Article: not found

          Hydrogen storage in microporous metal-organic frameworks.

          Metal-organic framework-5 (MOF-5) of composition Zn4O(BDC)3 (BDC = 1,4-benzenedicarboxylate) with a cubic three-dimensional extended porous structure adsorbed hydrogen up to 4.5 weight percent (17.2 hydrogen molecules per formula unit) at 78 kelvin and 1.0 weight percent at room temperature and pressure of 20 bar. Inelastic neutron scattering spectroscopy of the rotational transitions of the adsorbed hydrogen molecules indicates the presence of two well-defined binding sites (termed I and II), which we associate with hydrogen binding to zinc and the BDC linker, respectively. Preliminary studies on topologically similar isoreticular metal-organic framework-6 and -8 (IRMOF-6 and -8) having cyclobutylbenzene and naphthalene linkers, respectively, gave approximately double and quadruple (2.0 weight percent) the uptake found for MOF-5 at room temperature and 10 bar.
            Bookmark
            • Record: found
            • Abstract: found
            • Article: not found

            Modular chemistry: secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks.

            Secondary building units (SBUs) are molecular complexes and cluster entities in which ligand coordination modes and metal coordination environments can be utilized in the transformation of these fragments into extended porous networks using polytopic linkers (1,4-benzenedicarboxylate, 1,3,5,7-adamantanetetracarboxylate, etc.). Consideration of the geometric and chemical attributes of the SBUs and linkers leads to prediction of the framework topology, and in turn to the design and synthesis of a new class of porous materials with robust structures and high porosity.
              Bookmark
              • Record: found
              • Abstract: not found
              • Article: not found

              Preparation, Clathration Ability, and Catalysis of a Two-Dimensional Square Network Material Composed of Cadmium(II) and 4,4'-Bipyridine

                Bookmark

                Author and article information

                Journal
                Microporous and Mesoporous Materials
                Microporous and Mesoporous Materials
                Elsevier BV
                13871811
                August 2004
                August 2004
                : 73
                : 1-2
                : 81-88
                Article
                10.1016/j.micromeso.2003.12.027
                0b9f132d-067d-4f3a-af13-3a122f45d320
                © 2004

                http://www.elsevier.com/tdm/userlicense/1.0/

                History

                Comments

                Comment on this article