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Synthesis and Electrospraying of Nanoscale MOF (Metal Organic Framework) for High-Performance CO2 Adsorption Membrane

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      Abstract

      We report the sonochemical synthesis of MOF (metal organic framework) nanoparticles of 30–200 nm in size and electrospraying of those particles on electrospun nanofibers to process a MOF-attached nanofibrous membrane. This membrane displayed significant selectivity towards CO2 and capacity of adsorbing with 4000–5000 ppm difference from a mixed gas flow of 1% CO2 and 99% N2. Applying ultrasonic waves during the MOF synthesis offered rapid dispersion and formation of crystalline MOF nanoparticles in room temperature. The MOF nanoparticles of 100–200 nm in size displayed higher surface area and adsorption capacity comparing to that of 30–60 nm in size. Nanofibrous membrane was produced by electrospinning of MOF blended PAN solution followed by electrospraying of additional MOF nanoparticles. This yielded uniform MOF deposition on nanofibers, occurred due to electrostatic attraction between highly charged nanoparticles and conductive nanofibers. A test bench for real-time CO2 adsorption at room temperature was built with non-dispersive Infrared (NDIR) CO2 sensors. Comparative tests were performed on the membrane to investigate its enhanced adsorption capacity. Three layers of the as-produced membranes displayed CO2 adsorption for approximately 2 h. Thermogravimetric analysis (TGA) of the membrane showed the thermal stability of the MOF and PAN up to 290 and 425 °C, respectively.

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      Most cited references 39

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      Ultrahigh porosity in metal-organic frameworks.

      Crystalline solids with extended non-interpenetrating three-dimensional crystal structures were synthesized that support well-defined pores with internal diameters of up to 48 angstroms. The Zn4O(CO2)6 unit was joined with either one or two kinds of organic link, 4,4',4''-[benzene-1,3,5-triyl-tris(ethyne-2,1-diyl)]tribenzoate (BTE), 4,4',44''-[benzene-1,3,5-triyl-tris(benzene-4,1-diyl)]tribenzoate (BBC), 4,4',44''-benzene-1,3,5-triyl-tribenzoate (BTB)/2,6-naphthalenedicarboxylate (NDC), and BTE/biphenyl-4,4'-dicarboxylate (BPDC), to give four metal-organic frameworks (MOFs), MOF-180, -200, -205, and -210, respectively. Members of this series of MOFs show exceptional porosities and gas (hydrogen, methane, and carbon dioxide) uptake capacities. For example, MOF-210 has Brunauer-Emmett-Teller and Langmuir surface areas of 6240 and 10,400 square meters per gram, respectively, and a total carbon dioxide storage capacity of 2870 milligrams per gram. The volume-specific internal surface area of MOF-210 (2060 square meters per cubic centimeter) is equivalent to the outer surface of nanoparticles (3-nanometer cubes) and near the ultimate adsorption limit for solid materials.
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        Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks

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          CO2 capture by solid adsorbents and their applications: current status and new trends

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            Author and article information

            Affiliations
            [1 ]Department of Mechanical Engineering, Georgia Southern University, Statesboro, GA 30458 USA
            [2 ]Department of Chemistry, Georgia Southern University, Statesboro, GA 30458 USA
            Contributors
            ww01659@georgiasouthern.edu
            kallmond@ymail.com
            jstone@georgiasouthern.edu
            sharp@georgiasouthern.edu
            mkhan@georgiasouthern.edu
            Journal
            Nanoscale Res Lett
            Nanoscale Res Lett
            Nanoscale Research Letters
            Springer US (New York )
            1931-7573
            1556-276X
            5 January 2017
            5 January 2017
            2017
            : 12
            28058642
            5215997
            1798
            10.1186/s11671-016-1798-6
            © The Author(s). 2017

            Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License ( http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.

            Funding
            Funded by: Sustanibility Fee grant
            Funded by: NSF MRI
            Award ID: DMR 1337545
            Award Recipient :
            Categories
            Nano Express
            Custom metadata
            © The Author(s) 2017

            Nanomaterials

            co2 adsorption, mof, pan, electrospinning, nanofibers, electrospraying

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