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      Ammonia and related chemicals as potential indirect hydrogen storage materials

      , ,
      International Journal of Hydrogen Energy
      Elsevier BV

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          Most cited references106

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          Materials for fuel-cell technologies.

          Fuel cells convert chemical energy directly into electrical energy with high efficiency and low emission of pollutants. However, before fuel-cell technology can gain a significant share of the electrical power market, important issues have to be addressed. These issues include optimal choice of fuel, and the development of alternative materials in the fuel-cell stack. Present fuel-cell prototypes often use materials selected more than 25 years ago. Commercialization aspects, including cost and durability, have revealed inadequacies in some of these materials. Here we summarize recent progress in the search and development of innovative alternative materials.
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            Hydrogen storage in metal-organic frameworks.

            New materials capable of storing hydrogen at high gravimetric and volumetric densities are required if hydrogen is to be widely employed as a clean alternative to hydrocarbon fuels in cars and other mobile applications. With exceptionally high surface areas and chemically-tunable structures, microporous metal-organic frameworks have recently emerged as some of the most promising candidate materials. In this critical review we provide an overview of the current status of hydrogen storage within such compounds. Particular emphasis is given to the relationships between structural features and the enthalpy of hydrogen adsorption, spectroscopic methods for probing framework-H(2) interactions, and strategies for improving storage capacity (188 references).
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              How a century of ammonia synthesis changed the world

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                Author and article information

                Journal
                International Journal of Hydrogen Energy
                International Journal of Hydrogen Energy
                Elsevier BV
                03603199
                January 2012
                January 2012
                : 37
                : 2
                : 1482-1494
                Article
                10.1016/j.ijhydene.2011.10.004
                0df7972d-eaf0-4674-994f-c5bdd0ddf319
                © 2012

                http://www.elsevier.com/tdm/userlicense/1.0/

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