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      Grain boundary assisted photocurrent collection in thin film solar cells

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          Abstract

          The influence of absorber grain boundaries on the photocurrent transport in chalcopyrite based thin film solar cells has been calculated using a two dimensional numerical model. Considering extreme cases, the variation in red response is more expressed than in one dimensional models. These findings may offer an explanation for the strong influence of buffer layer preparation on the spectral response of cells with small grained absorbers.

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          Most cited references19

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          The electrical properties of polycrystalline silicon films

          John Seto (1975)
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            Anomalous grain boundary physics in polycrystalline CuInSe2: the existence of a hole barrier.

            First-principles modeling of grain boundaries (GB) in CuInSe2 semiconductors reveals that an energetic barrier exists for holes arriving from the grain interior (GI) to the GB. Consequently, the absence of holes inside the GB prevents GB electrons from recombining. At the same time, the GI is purer in polymaterials than in single crystals, since impurities segregated to the GBs. This explains the puzzle of the superiority of polycrystalline CuInSe2 solar cells over their crystalline counterpart. We identify a simple and universal mechanism for the barrier, arising from reduced p-d repulsion due to Cu-vacancy surface reconstruction. This discovery opens up possibilities for the future design of superior polycrystalline devices.
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              Grain-boundary recombination in Cu(In,Ga)Se2 solar cells

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                Author and article information

                Journal
                epjpv
                EPJ Photovoltaics
                an Open Access Journal in Photovoltaics
                EPJ Photovolt.
                EDP Sciences
                2105-0716
                15 June 2015
                2015
                15 June 2015
                15 June 2015
                : 6
                : ( publisher-idID: epjpv/2015/01 )
                : 60101
                Affiliations
                [1 ] Helmholtz-Zentrum Berlin für Materialien und Energie, , Hahn-Meitner-Platz 1, 14109 Berlin, Germany,
                [2 ] Weierstraß-Institut für Angewandte Analysis und Stochastik, , Mohrenstr. 39, 10117 Berlin, Germany,
                Author notes
                Article
                pv150006
                10.1051/epjpv/2015006
                0f1aac8a-2351-42ef-bfe1-244fee22b030
                © Harndt et al., published by EDP Sciences, 2015

                This is an Open Access article distributed under the terms of the Creative Commons Attribution License ( http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

                History
                : 25 February 2015
                : 22 May 2015
                Page count
                Figures: 6, References: 25, Pages: 5
                Categories
                Modelling
                Custom metadata
                EPJ Photovoltaics 6, 60101 (2015)
                2015
                2015
                2015

                Sustainable & Green chemistry,Materials technology,Semiconductors,Materials for energy,Technical & Applied physics,Renewable energy

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