trans-(Pyrimidine-2-thiol­ato-κ ² N, S)[tris­(2-amino­ethyl)amine-κ ⁴ N, N′, N′′, N′′′]cobalt(III) chloride hexa­fluoridophosphate

Abstract

In the title compound, [Co(C ₄H ₃N ₂S)(C ₆H ₁₈N ₄)](Cl)PF ₆, the Co ^III ion is coordinated by a tripod-like tetra­dentate ligand and a monoanionic N, S-bidentate ligand in an approximately octa­hedral CoN ₄OS geometry. The anionic S atom of the pyrimidine-2-thiol­ate (pymt) ligand is coordinated in the trans position to the primary amine N atom (Nprim) of the tris­(2-amino­ethyl)amine (tren) ligand. The crystal structure exhibits short inter­molecular N—H⋯N hydrogen bonds (N⋯N <3.2 Å), and inter­molecular N—H⋯Cl and C—H⋯F contacts, leading to the formation of an infinite two-dimensional network.