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Ring-Opening 1,3-Dichlorination of Donor–Acceptor Cyclopropanes by Iodobenzene Dichloride
October 24 2014
October 22 2014
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Abstract
Donor-acceptor cyclopropanes are reacted with iodobenzene dichloride to afford ring-opened
products bearing chlorine atoms in the 1- and 3-positions, adjacent to the donor and
acceptor groups. A variety of different donors (e.g., alkyl, aryl, N, and O) and acceptor
moieties (e.g., ketones, diesters, and dinitriles) are used.