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      A mild carbon–boron bond formation from diaryliodonium salts

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          Abstract

          Metal-free borylation of diaryliodonium salts with diboron reagents toward formation of aryl boronic esters and concomitant two-step C–C coupling of both aryl groups of the initial diaryliodonium reagent.

          The direct metal-free borylation of diaryliodonium salts with diboron reagents is now demonstrated to be a feasible process toward formation of aryl boronic esters without any additive or catalysts, and it can be extended to a two-step C–C coupling of both aryl groups of the initial diaryliodonium reagent.

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          Most cited references 48

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          Chemistry of polyvalent iodine.

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            Cross-coupling reactions of organoboranes: an easy way to construct C-C bonds (Nobel Lecture).

             Akira Suzuki (2011)
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              Diaryliodonium Salts: A Journey from Obscurity to Fame

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                Author and article information

                Journal
                CHCOFS
                Chemical Communications
                Chem. Commun.
                Royal Society of Chemistry (RSC)
                1359-7345
                1364-548X
                2015
                2015
                : 51
                : 74
                : 14068-14071
                Article
                10.1039/C5CC04944J
                © 2015
                Product
                Self URI (article page): http://xlink.rsc.org/?DOI=C5CC04944J

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