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      Catalytic enantioselective aldol reactions

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          Abstract

          Recent developments in catalytic asymmetric aldol reactions have been summarized.

          Abstract

          Recent developments in catalytic asymmetric aldol reactions have been summarized. Enantioselective aldol reactions are important methods to synthesize β-hydroxy carbonyl compounds in optical pure form, and as such, numerous successful chiral catalysts were designed and applied for asymmetric aldol reactions. This review article is organized under the categories of: (1) catalytic enantioselective aldol reactions of preformed enolates, (2) catalytic enantioselective direct-type aldol reactions using chiral metal catalysts, (3) catalytic enantioselective direct-type aldol reactions using organocatalysts, (4) catalytic enantioselective aldol reactions in aqueous media. Examples of the aldol reactions that employ simple carbonyl compounds will be also the focus of this review.

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          Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides

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            Effective ionic radii in oxides and fluorides

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              Proline-Catalyzed Direct Asymmetric Aldol Reactions

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                Author and article information

                Contributors
                (View ORCID Profile)
                Journal
                CSRVBR
                Chemical Society Reviews
                Chem. Soc. Rev.
                Royal Society of Chemistry (RSC)
                0306-0012
                1460-4744
                2018
                2018
                : 47
                : 12
                : 4388-4480
                Affiliations
                [1 ]Department of Chemistry
                [2 ]School of Science
                [3 ]The University of Tokyo
                [4 ]Bunkyo-ku
                [5 ]Japan
                Article
                10.1039/C7CS00824D
                29845124
                14a7d578-de8c-4993-bbe2-8c8390532311
                © 2018

                http://rsc.li/journals-terms-of-use

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