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      Mixed-Matrix Membranes

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          Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites.

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            The upper bound revisited

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              Mechanochemistry: opportunities for new and cleaner synthesis.

              The aim of this critical review is to provide a broad but digestible overview of mechanochemical synthesis, i.e. reactions conducted by grinding solid reactants together with no or minimal solvent. Although mechanochemistry has historically been a sideline approach to synthesis it may soon move into the mainstream because it is increasingly apparent that it can be practical, and even advantageous, and because of the opportunities it provides for developing more sustainable methods. Concentrating on recent advances, this article covers industrial aspects, inorganic materials, organic synthesis, cocrystallisation, pharmaceutical aspects, metal complexes (including metal-organic frameworks), supramolecular aspects and characterization methods. The historical development, mechanistic aspects, limitations and opportunities are also discussed (314 references). This journal is © The Royal Society of Chemistry 2012
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                Author and article information

                Journal
                Angewandte Chemie International Edition
                Angew. Chem. Int. Ed.
                Wiley-Blackwell
                14337851
                July 2017
                :
                :
                Article
                10.1002/anie.201701109
                28378379
                15648378-9385-4942-988d-ee79441a59d5
                History

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