Influence of Inclined Magnetic Field on Carreau Nanoliquid Thin Film Flow and Heat Transfer with Graphene Nanoparticles

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Abstract

The thermodynamics of a Carreau nanoliquid thin film embedded with graphene nanoparticles past a stretching sheet is studied in the presence of inclined magnetic field and non-uniform heat source/sink. Graphene is a new two-dimensional amphiphilic macromolecule which has great applications due to its electrical and mechanical properties. The basic constitutive equations of Carreau nanoliquid for velocity and temperature have been used. Similarity transformations are adopted to achieve the nonlinear coupled differential equations accompanying boundary conditions embedded with different parameters. HAM (Homotopy Analysis Method) is used to solve the transformed equations for expressions of velocity and temperature. Graphs are shown which illustrate the effects of various parameters of interest. There exists a nice agreement between the present and published results. The results are useful for the thermal conductivity and in the analysis and design of coating processes.

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Catalyst-free synthesis of nitrogen-doped graphene via thermal annealing graphite oxide with melamine and its excellent electrocatalysis.

Ye-Lin Shao, Jing Chen, Feng Wang … (2011)

The electronic and chemical properties of graphene can be modulated by chemical doping foreign atoms and functional moieties. The general approach to the synthesis of nitrogen-doped graphene (NG), such as chemical vapor deposition (CVD) performed in gas phases, requires transitional metal catalysts which could contaminate the resultant products and thus affect their properties. In this paper, we propose a facile, catalyst-free thermal annealing approach for large-scale synthesis of NG using low-cost industrial material melamine as the nitrogen source. This approach can completely avoid the contamination of transition metal catalysts, and thus the intrinsic catalytic performance of pure NGs can be investigated. Detailed X-ray photoelectron spectrum analysis of the resultant products shows that the atomic percentage of nitrogen in doped graphene samples can be adjusted up to 10.1%. Such a high doping level has not been reported previously. High-resolution N1s spectra reveal that the as-made NG mainly contains pyridine-like nitrogen atoms. Electrochemical characterizations clearly demonstrate excellent electrocatalytic activity of NG toward the oxygen reduction reaction (ORR) in alkaline electrolytes, which is independent of nitrogen doping level. The present catalyst-free approach opens up the possibility for the synthesis of NG in gram-scale for electronic devices and cathodic materials for fuel cells and biosensors.

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Synthesis of nitrogen-doped graphene films for lithium battery application.

Pulickel M. Ajayan, Anchal Srivastava, Arava Reddy … (2010)

We demonstrate a controlled growth of nitrogen-doped graphene layers by liquid precursor based chemical vapor deposition (CVD) technique. Nitrogen-doped graphene was grown directly on Cu current collectors and studied for its reversible Li-ion intercalation properties. Reversible discharge capacity of N-doped graphene is almost double compared to pristine graphene due to the large number of surface defects induced due to N-doping. All the graphene films were characterized by Raman spectroscopy, transmission electron microscopy, and X-ray photoemission spectroscopy. Direct growth of active electrode material on current collector substrates makes this a feasible and efficient process for integration into current battery manufacture technology.