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      Aperiodic crystals and superspace concepts

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      Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials
      International Union of Crystallography (IUCr)

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          Abstract

          For several decades the lattice periodicity of crystals, as shown by Laue, was considered to be their essential property. In the early sixties of the last century compounds were found which for many reasons should be called crystals, but were not lattice periodic. This opened the field of aperiodic crystals. An overview of this development is given. Many materials of this kind were found, sometimes with very interesting properties. In the beginning the development was slow, but the number of structures of this type increased enormously. In the meantime hundreds of scientists have contributed to this field using a multi-disciplinary approach.

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          Should All Crystals Be bcc? Landau Theory of Solidification and Crystal Nucleation

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            Indexing problems in quasicrystal diffraction

            Veit Elser (1985)
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              Quasicrystalline order in self-assembled binary nanoparticle superlattices.

              The discovery of quasicrystals in 1984 changed our view of ordered solids as periodic structures and introduced new long-range-ordered phases lacking any translational symmetry. Quasicrystals permit symmetry operations forbidden in classical crystallography, for example five-, eight-, ten- and 12-fold rotations, yet have sharp diffraction peaks. Intermetallic compounds have been observed to form both metastable and energetically stabilized quasicrystals; quasicrystalline order has also been reported for the tantalum telluride phase with an approximate Ta(1.6)Te composition. Later, quasicrystals were discovered in soft matter, namely supramolecular structures of organic dendrimers and tri-block copolymers, and micrometre-sized colloidal spheres have been arranged into quasicrystalline arrays by using intense laser beams that create quasi-periodic optical standing-wave patterns. Here we show that colloidal inorganic nanoparticles can self-assemble into binary aperiodic superlattices. We observe formation of assemblies with dodecagonal quasicrystalline order in different binary nanoparticle systems: 13.4-nm Fe(2)O(3) and 5-nm Au nanocrystals, 12.6-nm Fe(3)O(4) and 4.7-nm Au nanocrystals, and 9-nm PbS and 3-nm Pd nanocrystals. Such compositional flexibility indicates that the formation of quasicrystalline nanoparticle assemblies does not require a unique combination of interparticle interactions, but is a general sphere-packing phenomenon governed by the entropy and simple interparticle potentials. We also find that dodecagonal quasicrystalline superlattices can form low-defect interfaces with ordinary crystalline binary superlattices, using fragments of (3(3).4(2)) Archimedean tiling as the 'wetting layer' between the periodic and aperiodic phases.
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                Author and article information

                Journal
                ACSBDA
                Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials
                Acta Crystallogr B Struct Sci Cryst Eng Mater
                International Union of Crystallography (IUCr)
                2052-5206
                August 2014
                July 31 2014
                : 70
                : 4
                : 617-651
                Article
                10.1107/S2052520614014917
                17ae61ba-4e25-4f45-aead-e3b7aa1557de
                © 2014

                http://journals.iucr.org/services/copyrightpolicy.html

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