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      Adsorción de cromo (VI) utilizando cáscara de yuca (Manihot esculenta) como biosorbente: Estudio cinético Translated title: Adsorption of chromium (VI) using cassava peel (Manihot esculenta) as biosorbent: A kinetic study

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          Abstract

          Resumen En esta investigación se utilizó cáscara de yuca (Manihot esculenta) para remover cromo (VI) de disoluciones acuosas simulando efluentes in dustriales. Se utilizó un esquema de operación por lotes y se realizaron pruebas variando la concentración inicial de cromo (30, 40 y 50 ppm) y la temperatura (25, 30 y 35 °C), manteniendo fija la concentración del adsorbente (3,33 g/l), el tiempo de contacto 40 minutos y el pH 2, el cual se ajustó con ácido sulfúrico (H2SO4). Los datos obtenidos fueron ajusta dos a cuatro modelos cinéticos: primer orden reversible, pseudosegundo orden, Elovich y difusión intrapartícula. Los datos se ajustaron mejor al modelo de pseudosegundo orden. También se realizaron pruebas usando una concentración inicial de 50 ppm y tiempo de contacto de 120 minutos, variando la concentración del adsorbente (2, 4, 20 y 25 g/l). Se determinó que a mayor concentración de bioadsorbente se presenta mayor porcentaje de remoción.

          Translated abstract

          Abstract In this research, cassava peel (Manihot esculenta) was used to remove chromium (VI) from aqueous solution simulating industrial effluents. Batch adsorption operation was used and tests were performed by vary ing the initial concentration of chromium solution (30, 40 and 50 ppm) and temperature (25, 30 and 35 °C), keeping fixed the adsorbent dosage (3.33 g/l), the contact time 40 minutos and pH 2, which was adjusted with sulfuric acid (H2SO4). Data were fitted to four kinetic models: reversible first-order, pseudo second-order, Elovich and intraparticle diffusion models. Pseudo second-order model fits best to most experimental data. Tests were also performed using an initial concentration of 50 ppm and contact time of 120 minutos, varying the adsorbent dosage (2, 4, 20 and 25 g/l). The higher adsorbent dosage is, the higher percent removal of Cr(VI) is observed.

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          Most cited references24

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          Selective adsorption of chromium(VI) in industrial wastewater using low-cost abundantly available adsorbents

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            Removal of Cr(VI) from aqueous solution by adsorption onto activated carbon.

            K. Selvi (2001)
            Activated carbon (AC) prepared from coconut tree sawdust was used as an adsorbent for the removal of Cr(VI) from aqueous solution. Batch mode adsorption studies were carried out by varying agitation time, initial Cr(VI) concentration, carbon concentration and pH. Langmuir and Freundlich adsorption isotherms were applied to model the adsorption data. Adsorption capacity was calculated from the Langmuir isotherm and was 3.46 mg/g at an initial pH of 3.0 for the particle size 125-250 microm. The adsorption of Cr(VI) was pH dependent and maximum removal was observed in the acidic pH range. Desorption studies were carried out using 0.01-1 M NaOH solutions.
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              Mechanism study on adsorption of acidified multiwalled carbon nanotubes to Pb(II).

              Adsorption of acidified multiwalled carbon nanotubes (MWCNTs) to heavy metal using Pb(II) as a model was investigated and characterized by many techniques. The main adsorption mechanism of acidified MWCNTs to Pb(II) is proposed on the basis of adequate analysis. The results show that the oxygenous functional groups can be formed on MWCNTs after MWCNTs were treated by concentrated nitric acid. The oxygenous functional groups play an important role in Pb(II) adsorption to form chemical complex adsorption, which accounts for 75.3% of all the Pb(II) adsorption capacity. The Pb(II) in the form of PbO, Pb(OH)(2), and PbCO(3) adsorbed on the surface of the acidified MWCNTs is only 3.4% of the total Pb(II) adsorption capacity. The Pb(II) species adsorbed on acidified MWCNTs mainly aggregate on the ends and at the defects sites on the acidified MWCNTs.
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                Author and article information

                Contributors
                Role: ND
                Role: ND
                Role: ND
                Journal
                inde
                Ingeniería y Desarrollo
                Ing. Desarro.
                Fundación Universidad del Norte (Barranquilla, Atlantico, Colombia )
                0122-3461
                2145-9371
                June 2017
                : 35
                : 1
                : 58-76
                Affiliations
                [2] Barranquilla Atlántico orgnameUniversidad del Atlántico orgdiv1Facultad de Ingenie ría Colombia cabarraza@ 123456uniatlantico.edu.co
                [3] Barranquilla Atlántico orgnameUniversidad del Atlántico orgdiv1Facultad de Ingeniería Colombia albertoal bis@ 123456uniatlantico.edu.co
                [1] Barranquilla Atlántico orgnameUniversidad del Atlántico orgdiv1Facultad de Ingenie ría Colombia hacosta@ 123456uniatlantico.edu.co
                Article
                S0122-34612017000100058
                10.14482/inde.35.1.8943
                18dac0d8-ec79-4b02-a4f4-570001475f28

                This work is licensed under a Creative Commons Attribution 4.0 International License.

                History
                : 13 September 2015
                : 29 August 2016
                Page count
                Figures: 0, Tables: 0, Equations: 0, References: 24, Pages: 19
                Product

                SciELO Colombia


                cinética,bioadsorción,adsorción,biosorption,chrome,removal.,kinetics,cromo,remoción.,adsorption

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