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      Comparison of thermodynamic data of the ternary Cu–Sn–Zn system, measured with the EMF and with the calorimetric method

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      1 , * , , 1
      Zeitschrift für Metallkunde
      Carl Hanser Verlag
      Cu–Sn–Zn, Calorimetry, Lead-Free

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          Abstract

          The enthalpy of mixing of the ternary Cu–Sn–Zn system was measured using a Calvet-type calorimeter. The investigations were carried out along the three cross sections Cu:Sn=1:2, 1:1, and 2:1. Zn was added in the concentration range between 0 and 50at.%.

          The calorimetric results were compared with EMF data investigated in an earlier work by Peng and Mikula [1]. The results of the calorimetric measurements show very good agreement in the copper-rich region, compared with the EMF measurements, but in the Cu:Sn=1:2 cross section the results do not fit perfectly. The difference between both measuring methods was at the most Δ H = 300J/mol at the cross section Cu:Sn=1:1 and Δ H=150 J/mol at the Cu:Sn=2:1 cross section.

          Most cited references5

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          The Sn−Zn (Tin-Zinc) system

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            Investigation of interfacial microstructure and wetting property of newly developed Sn–Zn–Cu solders with Cu substrate

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              Dissolution and Corrosion Inhibition of Copper, Zinc, and Their Alloys

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                Author and article information

                Journal
                meku
                Zeitschrift für Metallkunde
                Carl Hanser Verlag
                0044-3093
                2195-8556
                2006
                : 97
                : 4
                : 434-439
                Affiliations
                1 Institute of Inorganic Chemistry-Materials Chemistry, University of Vienna, Austria
                Author notes
                [* ] Correspondence address: Mag. Dr. Sabine Knott, Inst. für Anorganische Chemie – Materialchemie, Universität Wien, Währingerstr. 42, A-1090 Vienna, Austria, Tel.: +431427752913, Fax: +43142779529. E-mail: Sabine.Knott@ 123456univie.ac.at

                Dedicated to Prof. Dr. Ferdinand Sommer on the occasion of his 65th birthday

                Article
                MK101236
                10.3139/146.101236
                18f97bc0-26be-4af9-ae8d-acf3e64819f3
                © 2006, Carl Hanser Verlag, München
                History
                : 29 September 2005
                : 11 January 2006
                Page count
                References: 35, Pages: 6
                Categories
                Basic

                Materials technology,Materials characterization,Materials science
                Lead-Free,Cu–Sn–Zn,Calorimetry

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