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      Eco-Friendly, High-Density Fiberboards Bonded with Urea-Formaldehyde and Ammonium Lignosulfonate

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          Abstract

          The potential of producing eco-friendly, formaldehyde-free, high-density fiberboard (HDF) panels from hardwood fibers bonded with urea-formaldehyde (UF) resin and a novel ammonium lignosulfonate (ALS) is investigated in this paper. HDF panels were fabricated in the laboratory by applying a very low UF gluing factor (3%) and ALS content varying from 6% to 10% (based on the dry fibers). The physical and mechanical properties of the fiberboards, such as water absorption (WA), thickness swelling (TS), modulus of elasticity (MOE), bending strength (MOR), internal bond strength (IB), as well as formaldehyde content, were determined in accordance with the corresponding European standards. Overall, the HDF panels exhibited very satisfactory physical and mechanical properties, fully complying with the standard requirements of HDF for use in load-bearing applications in humid conditions. Markedly, the formaldehyde content of the laboratory fabricated panels was extremely low, ranging between 0.7–1.0 mg/100 g, which is, in fact, equivalent to the formaldehyde release of natural wood.

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          A concise review of current lignin production, applications, products and their environment impact

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            Recent developments in eco-efficient bio-based adhesives for wood bonding: opportunities and issues

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              Challenges in industrial applications of technical lignins

              The primary aim of modern biorefineries is the efficient conversion of lignocellulosic materials into valuable products. Sugars and oils can be converted into valuable chemicals, but processing of lignin is still a challenge. A vast amount of lignin is incinerated to produce process steam and energy, and only a very small part is used for the production of value-added products. Technical lignins are isolated as by-streams in lignocellulosic refineries, e.g., as kraft, soda, organosolv, and hydrolysis lignins, as well as lignosulphonates. They have a modified structure and contain impurities that are dependent on the processing method. The structure and the composition of technical lignins restrict their subsequent applications. This paper reviews limiting factors in utilization of technical lignins. Four major classes of problems are identified, and approaches to overcoming these problems are suggested.
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                Author and article information

                Journal
                Polymers (Basel)
                Polymers (Basel)
                polymers
                Polymers
                MDPI
                2073-4360
                10 January 2021
                January 2021
                : 13
                : 2
                : 220
                Affiliations
                [1 ]Department of Mechanical Wood Technology, Faculty of Forest Industry, University of Forestry, 1797 Sofia, Bulgaria; victor_savov@ 123456ltu.bg
                [2 ]Faculty of Wood Sciences and Technology, Technical University in Zvolen, T. G. Masaryka 24, 960 01 Zvolen, Slovakia; reh@ 123456tuzvo.sk
                [3 ]Lab of Wood Science and Technology, Department of Forestry, Wood Sciences and Design, University of Thessaly, 43100 Karditsa, Greece; mantanis@ 123456uth.gr
                Author notes
                [* ]Correspondence: p.antov@ 123456ltu.bg (P.A.); kristak@ 123456tuzvo.sk (Ľ.K.)
                Author information
                https://orcid.org/0000-0002-3837-5380
                https://orcid.org/0000-0001-5111-8760
                https://orcid.org/0000-0002-2385-5760
                Article
                polymers-13-00220
                10.3390/polym13020220
                7827569
                33435154
                1a35c56c-69fb-4bee-96b8-4a037d3a4f4e
                © 2021 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 17 December 2020
                : 06 January 2021
                Categories
                Article

                wood-based panels,high-density fiberboards,bio-adhesives,ammonium lignosulfonate,zero-formaldehyde emission

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