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      Visible light photoactivity of Polypropylene coated Nano-TiO 2 for dyes degradation in water

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          Abstract

          The use of Polypropylene as support material for nano-TiO 2 photocatalyst in the photodegradation of Alizarin Red S in water solutions under the action of visible light was investigated. The optimization of TiO 2 pastes preparation using two commercial TiO 2, Aeroxide P-25 and Anatase, was performed and a green low-cost dip-coating procedure was developed. Scanning electron microscopy, Atomic Force Microscopy and X-Ray Diffraction analysis were used in order to obtain morphological and structural information of as-prepared TiO 2 on support material. Equilibrium and kinetics aspects in the adsorption and successive photodegradation of Alizarin Red S, as reference dye, are described using polypropylene-TiO 2 films in the Visible/TiO 2/water reactor showing efficient dyes degradation.

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          Most cited references17

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          TiO2-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations

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            TiO2 photocatalysis: Design and applications

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              Bactericidal activity of photocatalytic TiO(2) reaction: toward an understanding of its killing mechanism.

              When titanium dioxide (TiO(2)) is irradiated with near-UV light, this semiconductor exhibits strong bactericidal activity. In this paper, we present the first evidence that the lipid peroxidation reaction is the underlying mechanism of death of Escherichia coli K-12 cells that are irradiated in the presence of the TiO(2) photocatalyst. Using production of malondialdehyde (MDA) as an index to assess cell membrane damage by lipid peroxidation, we observed that there was an exponential increase in the production of MDA, whose concentration reached 1.1 to 2.4 nmol. mg (dry weight) of cells(-1) after 30 min of illumination, and that the kinetics of this process paralleled cell death. Under these conditions, concomitant losses of 77 to 93% of the cell respiratory activity were also detected, as measured by both oxygen uptake and reduction of 2,3,5-triphenyltetrazolium chloride from succinate as the electron donor. The occurrence of lipid peroxidation and the simultaneous losses of both membrane-dependent respiratory activity and cell viability depended strictly on the presence of both light and TiO(2). We concluded that TiO(2) photocatalysis promoted peroxidation of the polyunsaturated phospholipid component of the lipid membrane initially and induced major disorder in the E. coli cell membrane. Subsequently, essential functions that rely on intact cell membrane architecture, such as respiratory activity, were lost, and cell death was inevitable.
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                Author and article information

                Journal
                Sci Rep
                Sci Rep
                Scientific Reports
                Nature Publishing Group
                2045-2322
                02 December 2015
                2015
                : 5
                : 17801
                Affiliations
                [1 ]School of Science and Technology, Chemistry Division, University of Camerino , 62032 Camerino (MC), Italy
                [2 ]School of Science and Technology, Physics Division, University of Camerino , 62032 Camerino (MC), Italy
                Author notes
                Article
                srep17801
                10.1038/srep17801
                4667216
                26627118
                1a8ea302-97c0-4737-9ec1-b7dcf83bd835
                Copyright © 2015, Macmillan Publishers Limited

                This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/

                History
                : 21 July 2015
                : 06 November 2015
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