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      Crystal structure of (±)-1-({[4-(all­yloxy)phen­yl]sulfan­yl}meth­yl)-2-(di­phenyl­thio­phosphor­yl)ferrocene

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          Abstract

          The title compound is a ferrocene derivative substituted in 1,2 positions by a di­phenyl­thio­phosphoroyl and a {[4-(all­yloxy)phen­yl]sulfan­yl}methyl chain.

          Abstract

          The title compound, [Fe(C 5H 5)(C 27H 24OPS 2)], is built up from a ferrocene moiety substituted in the 1- and 2-positions by {[4-(all­yloxy)phen­yl]sulfan­yl}methyl and di­phenyl­thio­phosphoryl groups, respectively. The two S atoms lie on opposite sides of the cyclo­penta­dienyl ring plane to which they are attached. In the crystal, C—H⋯S hydrogen bonds link the mol­ecules into a ribbon running parallel to the (-110) plane. C—H⋯π inter­actions link the ribbons to form a three-dimensional network.

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          Author and article information

          Journal
          Acta Crystallogr E Crystallogr Commun
          Acta Crystallogr E Crystallogr Commun
          Acta Cryst. E
          Acta Crystallographica Section E: Crystallographic Communications
          International Union of Crystallography
          2056-9890
          01 August 2015
          29 July 2015
          29 July 2015
          : 71
          : Pt 8 ( publisher-idID: e150800 )
          : 972-975
          Affiliations
          [a ]Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France
          [b ]CNRS, LCC (Laboratoire de Chimie de Coordination), IUT, Département de Chimie, avenue Georges Pompidou, BP258, 81104 Castres, France
          [c ]CIRIMAT, équipe PPB, Université Paul Sabatier, ENSIACET – Bureau 2-r1-5, 4 Allée Emile Monso BP 44362, 31432 Toulouse Cedex 4, France
          [d ]Laboratoire de Chimie de Coordination, 205 route de Narbonne, 31077 Toulouse, Cedex 04, France
          Author notes
          Correspondence e-mail: daran@ 123456lcc-toulouse.fr
          Article
          is5405 ACSECI S2056989015013560
          10.1107/S2056989015013560
          4571369
          1cf66ffd-3955-4a76-843b-4eea7df93e02
          © Michelot et al. 2015

          This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

          History
          : 03 July 2015
          : 15 July 2015
          Categories
          Research Communications

          crystal structure,ferrocenyl ligands,planar chirality,asymmetric catalysis

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