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      Bioinspired Perovskite Nanocrystals‐Integrated Photonic Crystal Microsphere Arrays for Information Security

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          Abstract

          Information security occupies an important position in the era of big data. Attempts to improve the security performance tend to impart them with more additional encryption strategies. Herein, inspired by the wettability feature of Stenocara beetle elytra and signal model of traffic light, a novel array of perovskite nanocrystals (PNs)‐integrated PhC microsphere for information security is presented. The photoluminescent PNs are encapsulated in angle‐independent PhC microspheres to impart them with binary optical signals as coding information. Through the multimask superposition approach, PNs‐integrated PhC microspheres with different codes are placed into fluorosilane‐treated PDMS substrate to form different arrays. These arrays could converge moisture on PhC microspheres in wet environment, which avoids the ions loss of the PNs and effectively prevented mutual contamination. In addition, the fluorescence of the PNs inside PhC microspheres could reversibly quench or recover in response to the environmental moisture. Based on these features, it is demonstrated that the PNs‐integrated PhC microsphere arrays could realize various information encryption modes, which indicate their excellent values in information security fields.

          Abstract

          Novel perovskite nanocrystals (PNs)‐integrated photonic crystals (PhC) microsphere arrays inspired by Stenocara beetle and traffic light are presented for information security. The photoluminescent PNs are encapsulated in angle‐independent PhC microspheres to impart them with binary optical signals as coding information. The PNs‐integrated PhC microsphere arrays could realize various information encryption modes, which indicate their excellent values in information security fields.

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          Author and article information

          Contributors
          luoranshang@fudan.edu.cn
          yjzhao@seu.edu.cn
          Journal
          Adv Sci (Weinh)
          Adv Sci (Weinh)
          10.1002/(ISSN)2198-3844
          ADVS
          Advanced Science
          John Wiley and Sons Inc. (Hoboken )
          2198-3844
          20 January 2022
          March 2022
          : 9
          : 9 ( doiID: 10.1002/advs.v9.9 )
          : 2105278
          Affiliations
          [ 1 ] Department of Clinical Laboratory Institute of Translational Medicine The Affiliated Drum Tower Hospital of Nanjing University Medical School Nanjing 210008 China
          [ 2 ] State Key Laboratory of Bioelectronics School of Biological Science and Medical Engineering Southeast University Nanjing 210096 China
          [ 3 ] Shanghai Xuhui Central Hospital Zhongshan‐Xuhui Hospital and the Shanghai Key Laboratory of Medical Epigenetics International Co‐laboratory of Medical Epigenetics and Metabolism (Ministry of Science and Technology Institutes of Biomedical Sciences) Fudan University Shanghai 200433 China
          [ 4 ] Oujiang Laboratory (Zhejiang Lab for Regenerative Medicine, Vision and Brain Health) Wenzhou Institute University of Chinese Academy of Sciences Wenzhou 325001 China
          Author notes
          Author information
          https://orcid.org/0000-0001-7187-6286
          https://orcid.org/0000-0003-3407-553X
          https://orcid.org/0000-0001-9242-4000
          Article
          ADVS3477
          10.1002/advs.202105278
          8948562
          35048564
          1efad357-4d0e-46c8-8ae5-161a20c6ce47
          © 2022 The Authors. Advanced Science published by Wiley‐VCH GmbH

          This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

          History
          : 01 December 2021
          Page count
          Figures: 7, Tables: 0, Pages: 9, Words: 5556
          Funding
          Funded by: National Key Research and Development Program of China , doi 10.13039/501100012166;
          Award ID: 2020YFA0908200
          Funded by: National Natural Science Foundation of China , doi 10.13039/501100001809;
          Award ID: 52073060
          Award ID: 22002018
          Award ID: 61971216
          Award ID: 82102181
          Funded by: Key Research and Development Project of Jiangsu Province , doi 10.13039/501100013058;
          Award ID: BE20210009
          Funded by: Shenzhen Fundamental Research Program , doi 10.13039/501100017607;
          Award ID: JCYJ20190813152616459
          Award ID: JCYJ20210324133214038
          Funded by: China Postdoctoral Science Foundation , doi 10.13039/501100002858;
          Award ID: 2020M681556
          Award ID: 2021T140318
          Funded by: Postdoctoral Research Program of Jiangsu Province
          Award ID: 2021K123B
          Funded by: Jiangsu Provincial Double‐Innovation Doctor Program
          Award ID: JSSCBS20211486
          Categories
          Research Article
          Research Articles
          Custom metadata
          2.0
          March 25, 2022
          Converter:WILEY_ML3GV2_TO_JATSPMC version:6.1.2 mode:remove_FC converted:25.03.2022

          bioinspired,hydrochromic,information security,perovskite nanocrystal,photonic crystal,structural color

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