Industrial development of reversible-deactivation radical polymerization: is the induction period over?

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Abstract

The commercial applications of polymers produced by reversible-deactivation radical polymerization are reviewed here.

Abstract

Reversible-deactivation radical polymerisation (RDRP) techniques are essential in modern polymer chemistry. Over the years, they have become not only fantastic lab tools for the easy preparation of structurally complex polymers but also an industrial reality. This article reviews industrial developments and commercial success based on RDRP processes. The nature of RDRP control agents is discussed and numerous industrial polymers and their applications are exemplified. While RDRP is firmly established as a powerful means for the development of next generation high-valued polymer products, there is room for improvement in terms of the cost/performance ratio for a broader adoption by industry. Some directions are proposed for the future.

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Polymerization-Induced Self-Assembly of Block Copolymer Nano-objects via RAFT Aqueous Dispersion Polymerization

Nicholas Warren, Steven Armes (2014)

In this Perspective, we discuss the recent development of polymerization-induced self-assembly mediated by reversible addition–fragmentation chain transfer (RAFT) aqueous dispersion polymerization. This approach has quickly become a powerful and versatile technique for the synthesis of a wide range of bespoke organic diblock copolymer nano-objects of controllable size, morphology, and surface functionality. Given its potential scalability, such environmentally-friendly formulations are expected to offer many potential applications, such as novel Pickering emulsifiers, efficient microencapsulation vehicles, and sterilizable thermo-responsive hydrogels for the cost-effective long-term storage of mammalian cells.