Rhodium-Catalyzed Asymmetric [2 + 2 + 2] Cycloaddition of 1,6-Enynes with Cyclopropylideneacetamides.

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Abstract

It has been established that a cationic rhodium(I)/H8-BINAP complex catalyzes the asymmetric [2 + 2 + 2] cycloaddition of 1,6-enynes with cyclopropylideneacetamides to produce spirocyclohexenes in excellent enantioselectivity with retaining cyclopropane rings.

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Journal

Journal ID (iso-abbrev): Org Lett

Title: Organic letters

Publisher: American Chemical Society (ACS)

ISSN (Electronic): 1523-7052

ISSN (Print): 1523-7052

Publication date (Electronic): Feb 05 2016

Volume: 18

Issue: 3

Affiliations

[1 ] Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology , O-okayama, Meguro-ku, Tokyo 152-8550, Japan.

[2 ] Department of Applied Chemistry, Graduate School of Engineering, and §Instrumentation Analysis Center, Tokyo University of Agriculture and Technology , Koganei, Tokyo 184-8588, Japan.

Article

DOI: 10.1021/acs.orglett.5b03387

PubMed ID: 26756430

SO-VID: 240dd354-8cc5-47a1-956a-9a47e050594b

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