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      Synthesis of Aza-Heterocycles from Oximes by Amino-Heck Reaction

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      The Chemical Record

      Wiley-Blackwell

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          Abstract

          Oxidative addition of oximes to palladium(0) complexes generates alkylideneaminopalladium(II) species, which are utilized as key intermediates for carbon-nitrogen bond formation. Various aza-heterocycles, such as pyrrole, pyridine, isoquinoline, spiroimine, and azaazulene, can be synthesized from O-pentafluorobenzoyloximes having an olefinic moiety via an intramolecular Heck-type reaction (amino-Heck reaction) by treatment with a catalytic amount of a Pd(0) complex.

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          Most cited references 24

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          Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides

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            Arylation of Olefin with Aryl Iodide Catalyzed by Palladium

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              Palladium-assisted intramolecular amination of olefins. Synthesis of nitrogen heterocycles

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                Author and article information

                Journal
                The Chemical Record
                Chem. Record
                Wiley-Blackwell
                1527-8999
                1528-0691
                July 2002
                July 2002
                : 2
                : 4
                : 268-277
                Article
                10.1002/tcr.10030
                12203909
                © 2002
                Product
                Self URI (article page): http://doi.wiley.com/10.1002/tcr.10030

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