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      A High Power Rechargeable Nonaqueous Multivalent Zn/V2 O5 Battery

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          Most cited references28

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          Energetic zinc ion chemistry: the rechargeable zinc ion battery.

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            Prototype systems for rechargeable magnesium batteries.

            The thermodynamic properties of magnesium make it a natural choice for use as an anode material in rechargeable batteries, because it may provide a considerably higher energy density than the commonly used lead-acid and nickel-cadmium systems. Moreover, in contrast to lead and cadmium, magnesium is inexpensive, environmentally friendly and safe to handle. But the development of Mg batteries has been hindered by two problems. First, owing to the chemical activity of Mg, only solutions that neither donate nor accept protons are suitable as electrolytes; but most of these solutions allow the growth of passivating surface films, which inhibit any electrochemical reaction. Second, the choice of cathode materials has been limited by the difficulty of intercalating Mg ions in many hosts. Following previous studies of the electrochemistry of Mg electrodes in various non-aqueous solutions, and of a variety of intercalation electrodes, we have now developed rechargeable Mg battery systems that show promise for applications. The systems comprise electrolyte solutions based on Mg organohaloaluminate salts, and Mg(x)Mo3S4 cathodes, into which Mg ions can be intercalated reversibly, and with relatively fast kinetics. We expect that further improvements in the energy density will make these batteries a viable alternative to existing systems.
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              Towards High-Voltage Aqueous Metal-Ion Batteries Beyond 1.5 V: The Zinc/Zinc Hexacyanoferrate System

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                Author and article information

                Journal
                Advanced Energy Materials
                Adv. Energy Mater.
                Wiley
                16146832
                December 2016
                December 2016
                August 26 2016
                : 6
                : 24
                : 1600826
                Affiliations
                [1 ]Joint Center for Energy Storage Research; Argonne National Laboratory; Argonne IL 60439 USA
                [2 ]Chemical Sciences and Engineering Division; Argonne National Laboratory; Argonne IL 60439 USA
                [3 ]Material Science Division; Argonne National Laboratory; Argonne IL 60439 USA
                Article
                10.1002/aenm.201600826
                267c97e6-b9c1-40de-9556-38042e737d25
                © 2016

                http://doi.wiley.com/10.1002/tdm_license_1.1

                http://onlinelibrary.wiley.com/termsAndConditions#am

                http://onlinelibrary.wiley.com/termsAndConditions#vor

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