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      Polymer Electrolyte Water Electrolysis: Correlating Performance and Porous Transport Layer Structure: Part II. Electrochemical Performance Analysis

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      Journal of The Electrochemical Society
      The Electrochemical Society

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          New Insights into Perfluorinated Sulfonic-Acid Ionomers.

          In this comprehensive review, recent progress and developments on perfluorinated sulfonic-acid (PFSA) membranes have been summarized on many key topics. Although quite well investigated for decades, PFSA ionomers' complex behavior, along with their key role in many emerging technologies, have presented significant scientific challenges but also helped create a unique cross-disciplinary research field to overcome such challenges. Research and progress on PFSAs, especially when considered with their applications, are at the forefront of bridging electrochemistry and polymer (physics), which have also opened up development of state-of-the-art in situ characterization techniques as well as multiphysics computation models. Topics reviewed stem from correlating the various physical (e.g., mechanical) and transport properties with morphology and structure across time and length scales. In addition, topics of recent interest such as structure/transport correlations and modeling, composite PFSA membranes, degradation phenomena, and PFSA thin films are presented. Throughout, the impact of PFSA chemistry and side-chain is also discussed to present a broader perspective.
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            Water Uptake by and Transport Through Nafion® 117 Membranes

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              Critical Review—Identifying Critical Gaps for Polymer Electrolyte Water Electrolysis Development

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                Author and article information

                Contributors
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                Journal
                Journal of The Electrochemical Society
                J. Electrochem. Soc.
                The Electrochemical Society
                0013-4651
                1945-7111
                May 24 2019
                2019
                May 24 2019
                2019
                : 166
                : 10
                : F555-F565
                Article
                10.1149/2.1241908jes
                2b7c7c29-75b7-4c86-963c-ed117659b37b
                © 2019

                Free to read

                http://creativecommons.org/licenses/by-nc-nd/4.0/

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