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      Quartz-Enhanced Photoacoustic Spectroscopy: A Review

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          Abstract

          A detailed review on the development of quartz-enhanced photoacoustic sensors (QEPAS) for the sensitive and selective quantification of molecular trace gas species with resolved spectroscopic features is reported. The basis of the QEPAS technique, the technology available to support this field in terms of key components, such as light sources and quartz-tuning forks and the recent developments in detection methods and performance limitations will be discussed. Furthermore, different experimental QEPAS methods such as: on-beam and off-beam QEPAS, quartz-enhanced evanescent wave photoacoustic detection, modulation-cancellation approach and mid-IR single mode fiber-coupled sensor systems will be reviewed and analysed. A QEPAS sensor operating in the THz range, employing a custom-made quartz-tuning fork and a THz quantum cascade laser will be also described. Finally, we evaluated data reported during the past decade and draw relevant and useful conclusions from this analysis.

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          Most cited references165

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          Quartz-enhanced photoacoustic spectroscopy.

          A new approach to detecting a weak photoacoustic signal in a gas medium is described. Instead of a gas-filled resonant acoustic cavity, the sound energy is accumulated in a high- Q crystal element. Feasibility experiments utilizing a quartz-watch tuning fork demonstrate a sensitivity of 1.2x10(-7) cm(-1) W/ radicalHz . Potential further developments and applications of this technique are discussed.
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            QEPAS based ppb-level detection of CO and N2O using a high power CW DFB-QCL.

            An ultra-sensitive and selective quartz-enhanced photoacoustic spectroscopy (QEPAS) sensor platform was demonstrated for detection of carbon monoxide (CO) and nitrous oxide (N2O). This sensor used a state-of-the art 4.61 μm high power, continuous wave (CW), distributed feedback quantum cascade laser (DFB-QCL) operating at 10°C as the excitation source. For the R(6) CO absorption line, located at 2169.2 cm(-1), a minimum detection limit (MDL) of 1.5 parts per billion by volume (ppbv) at atmospheric pressure was achieved with a 1 sec acquisition time and the addition of 2.6% water vapor concentration in the analyzed gas mixture. For the N2O detection, a MDL of 23 ppbv was obtained at an optimum gas pressure of 100 Torr and with the same water vapor content of 2.6%. In both cases the presence of water vapor increases the detected CO and N2O QEPAS signal levels as a result of enhancing the vibrational-translational relaxation rate of both target gases. Allan deviation analyses were performed to investigate the long term performance of the CO and N2O QEPAS sensor systems. For the optimum data acquisition time of 500 sec a MDL of 340 pptv and 4 ppbv was obtained for CO and N2O detection, respectively. To demonstrate reliable and robust operation of the QEPAS sensor a continuous monitoring of atmospheric CO and N2O concentration levels for a period of 5 hours were performed.
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              Electrochemical sensors.

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                Author and article information

                Journal
                Sensors (Basel)
                Sensors (Basel)
                Sensors (Basel, Switzerland)
                Molecular Diversity Preservation International (MDPI)
                1424-8220
                April 2014
                28 March 2014
                : 14
                : 4
                : 6165-6206
                Affiliations
                [1 ] Department of Electrical and Computer Engineering, Rice University, 6100 Main Street, Houston, TX 77005, USA; E-Mail: fkt@ 123456rice.edu
                [2 ] Dipartimento Interateneo di Fisica, Università degli studi di Bari Aldo Moro e Politecnico di Bari, Via Amendola 173, Bari, I-70126, Italy; E-Mails: pietro.patimisco@ 123456uniba.it (P.P.); gaetano.scamarcio@ 123456uniba.it (G.S.)
                Author notes
                [* ] Author to whom correspondence should be addressed; E-Mail: v.spagnolo@ 123456poliba.it ; Tel.: +39-080-544-2373; Fax: +39-080-544-2219.
                Article
                sensors-14-06165
                10.3390/s140406165
                4029643
                24686729
                303a7064-f025-4087-8dc7-c969b984ff65
                © 2014 by the authors; licensee MDPI, Basel, Switzerland.

                This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license ( http://creativecommons.org/licenses/by/3.0/ http://creativecommons.org/licenses/by/3.0/).

                History
                : 29 November 2013
                : 18 February 2014
                : 21 March 2014
                Categories
                Review

                Biomedical engineering
                quartz enhanced photoacoustic spectroscopy,quartz tuning fork,gas sensing,mid-ir and thz laser spectroscopy

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