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      An electrochemical fungicide pyrimethanil sensor based on carbon nanotubes/ionic-liquid construction modified electrode.

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          Abstract

          In this study, a simple, rapid, sensitive and environmentally friendly electroanalytical detection method for pyrimethanil (PMT) was developed, which was based on multi-walled carbon nanotubes (MWCNTs) and ionic liquids (IL) 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]) modified glassy carbon electrode (GCE). MWCNTs-IL modified electrode significantly enhanced the oxidation peak current of PMT by combining the excellent electrochemical properties of MWCNTs and IL, suggesting that the modified electrode can remarkably improve the sensitivity of PMT detection. Under the optimum conditions, this electrochemical sensor exhibited a linear concentration range for PMT of 1.0 × 10(-7)-1.0 × 10(-4) mol L(-1) and the detection limit was 1.6 × 10(-8) mol L(-1) (S/N = 3). The fabricated electrode showed good reproducibility, stability and anti-interference, and also it was successfully employed to detect PMT in real samples.

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          Author and article information

          Journal
          Food Chem
          Food chemistry
          0308-8146
          0308-8146
          Nov 15 2015
          : 187
          Affiliations
          [1 ] College of Chemistry, Liaoning University, 66 Chongshan Middle Road, Shenyang 110036, People's Republic of China.
          [2 ] College of Chemistry, Liaoning University, 66 Chongshan Middle Road, Shenyang 110036, People's Republic of China. Electronic address: zhanglei63@126.com.
          Article
          S0308-8146(15)00540-3
          10.1016/j.foodchem.2015.04.009
          25976990
          306613e7-b67f-41cb-bc98-d6ae57b75d41
          Copyright © 2015 Elsevier Ltd. All rights reserved.
          History

          Electrochemical determination,Ionic liquids,Modified electrode,Multi-walled carbon nanotubes,Pyrimethanil

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