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      Characterizing organic particle impacts on inert metal surfaces: Foundations for capturing organic molecules during hypervelocity transits of Enceladus plumes

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          Abstract

          The presence and accessibility of a sub‐ice‐surface saline ocean at Enceladus, together with geothermal activity and a rocky core, make it a compelling location to conduct further, in‐depth, astrobiological investigations to probe for organic molecules indicative of extraterrestrial life. Cryovolcanic plumes in the south polar region of Enceladus enable the use of remote in situ sampling and analysis techniques. However, efficient plume sampling and the transportation of captured organic materials to an organic analyzer present unique challenges for an Enceladus mission. A systematic study, accelerating organic ice‐particle simulants into soft inert metal targets at velocities ranging 0.5–3.0 km s −1, was carried out using a light gas gun to explore the efficacy of a plume capture instrument. Capture efficiency varied for different metal targets as a function of impact velocity and particle size. Importantly, organic chemical compounds remained chemically intact in particles captured at speeds up to ~2 km s −1. Calibration plots relating the velocity, crater, and particle diameter were established to facilitate future ice‐particle impact experiments where the size of individual ice particles is unknown.

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          A serpentinite-hosted ecosystem: the Lost City hydrothermal field.

          The serpentinite-hosted Lost City hydrothermal field is a remarkable submarine ecosystem in which geological, chemical, and biological processes are intimately interlinked. Reactions between seawater and upper mantle peridotite produce methane- and hydrogen-rich fluids, with temperatures ranging from <40 degrees to 90 degrees C at pH 9 to 11, and carbonate chimneys 30 to 60 meters tall. A low diversity of microorganisms related to methane-cycling Archaea thrive in the warm porous interiors of the edifices. Macrofaunal communities show a degree of species diversity at least as high as that of black smoker vent sites along the Mid-Atlantic Ridge, but they lack the high biomasses of chemosynthetic organisms that are typical of volcanically driven systems.
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            Cassini ion and neutral mass spectrometer: Enceladus plume composition and structure.

            The Cassini spacecraft passed within 168.2 kilometers of the surface above the southern hemisphere at 19:55:22 universal time coordinated on 14 July 2005 during its closest approach to Enceladus. Before and after this time, a substantial atmospheric plume and coma were observed, detectable in the Ion and Neutral Mass Spectrometer (INMS) data set out to a distance of over 4000 kilometers from Enceladus. INMS data indicate that the atmospheric plume and coma are dominated by water, with significant amounts of carbon dioxide, an unidentified species with a mass-to-charge ratio of 28 daltons (either carbon monoxide or molecular nitrogen), and methane. Trace quantities (<1%) of acetylene and propane also appear to be present. Ammonia is present at a level that does not exceed 0.5%. The radial and angular distributions of the gas density near the closest approach, as well as other independent evidence, suggest a significant contribution to the plume from a source centered near the south polar cap, as distinct from a separately measured more uniform and possibly global source observed on the outbound leg of the flyby.
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              Liquid water on Enceladus from observations of ammonia and 40Ar in the plume

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                Author and article information

                Contributors
                Jamesnew@berkeley.edu
                Journal
                Meteorit Planet Sci
                Meteorit Planet Sci
                10.1111/(ISSN)1945-5100
                MAPS
                Meteoritics & Planetary Science
                John Wiley and Sons Inc. (Hoboken )
                1086-9379
                1945-5100
                25 February 2020
                March 2020
                : 55
                : 3 ( doiID: 10.1111/maps.v55.3 )
                : 465-479
                Affiliations
                [ 1 ] Space Sciences Laboratory University of California Berkeley 7 Gauss Way Berkeley California 94720 USA
                [ 2 ] School of Physical Sciences University of Kent Canterbury Kent CT2 7NH UK
                [ 3 ] Department of Chemistry University of California Berkeley California 94720 USA
                Author notes
                [*] [* ]Corresponding author. E‐mail: Jamesnew@ 123456berkeley.edu
                Author information
                https://orcid.org/0000-0001-7473-8874
                Article
                MAPS13448
                10.1111/maps.13448
                7188319
                31a41aa9-6820-440b-8d88-5d4104b7c974
                © 2020 The Authors. Meteoritics & Planetary Science published by Wiley Periodicals, Inc. on behalf of The Meteoritical Society (MET)

                This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

                History
                : 18 November 2019
                : 08 January 2020
                Page count
                Figures: 10, Tables: 1, Pages: 15, Words: 8948
                Funding
                Funded by: NASA MatISSE
                Award ID: 80NSSC17K0600
                Funded by: National Aeronautics and Space Administration (NASA)
                Award ID: 80NSSC17K0600
                Funded by: Lin Graduate Fellowship
                Funded by: UC Retirement System
                Funded by: Mathies Royalty Fund
                Categories
                Original Article
                Articles
                Custom metadata
                2.0
                March 2020
                Converter:WILEY_ML3GV2_TO_JATSPMC version:5.8.1 mode:remove_FC converted:28.04.2020

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