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      Syntheses and magnetic properties of high-dimensional cucurbit[6]uril-based metal-organic rotaxane frameworks.

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          Abstract

          Three new high-dimensional cucurbit[6]-based metal-organic rotaxane frameworks [Co2(PR43)(BDC)2Cl2]·4H2O (1), [Co2(PR43)(BTC)2]·6H2O (2) and [Co2(PR43)(BPT)2]·20H2O (3) were obtained via the hydrothermal synthesis method. Compound 1 comprised a two-dimensional layered structure, while compounds 2 and 3 exhibited three-dimensional pillared structures. All the compounds showed good thermal stabilities. Furthermore, the magnetic properties of compounds 1-3 were also investigated in detail.

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          Author and article information

          Journal
          Dalton Trans
          Dalton transactions (Cambridge, England : 2003)
          Royal Society of Chemistry (RSC)
          1477-9234
          1477-9226
          Jul 21 2019
          : 48
          : 27
          Affiliations
          [1 ] Jilin Provincial Science and Technology Innovation Center of Optical Materials and Chemistry, School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun, Jilin 130022, P. R. China. sj-cust@126.com zmsu@nenu.edu.cn.
          [2 ] National & Local United Engineering Laboratory for Power Battery Institution, Northeast Normal University, Changchun, Jilin 130024, P.R. China.
          [3 ] Jilin Provincial Science and Technology Innovation Center of Optical Materials and Chemistry, School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun, Jilin 130022, P. R. China. sj-cust@126.com zmsu@nenu.edu.cn and National & Local United Engineering Laboratory for Power Battery Institution, Northeast Normal University, Changchun, Jilin 130024, P.R. China.
          Article
          10.1039/c9dt01544b
          31204763
          34cad99f-d0da-4e13-9809-9e979894fe0e
          History

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