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      Fundamental transport mechanisms, fabrication and potential applications of nanoporous atomically thin membranes

      Author(s): , , , , ,
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      Journal: Nature Nanotechnology
      Publisher: Springer Nature

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          Abstract

          This Review examines the development of nanoporous atomically thin membranes, focusing on fundamental mechanisms of gas- and liquid-phase transport, membrane fabrication techniques, and advances towards practical applications.

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          The upper bound revisited

          Lloyd Robeson (2008)
          Article 0 comments Cited 919 times – based on 0 reviews     Review now
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            30 inch Roll-Based Production of High-Quality Graphene Films for Flexible Transparent Electrodes

            Jong-Hyun Ahn, Yi Zheng, Jae-Sung Park … (2009)
            We report that 30-inch scale multiple roll-to-roll transfer and wet chemical doping considerably enhance the electrical properties of the graphene films grown on roll-type Cu substrates by chemical vapor deposition. The resulting graphene films shows a sheet resistance as low as ~30 Ohm/sq at ~90 % transparency which is superior to commercial transparent electrodes such as indium tin oxides (ITO). The monolayer of graphene shows sheet resistances as low as ~125 Ohm/sq with 97.4% optical transmittance and half-integer quantum Hall effect, indicating the high-quality of these graphene films. As a practical application, we also fabricated a touch screen panel device based on the graphene transparent electrodes, showing extraordinary mechanical and electrical performances.
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              Stretching and breaking of ultrathin MoS2.

              Simone Bertolazzi, Jacopo Brivio, Andras Kis (2011)
              We report on measurements of the stiffness and breaking strength of monolayer MoS(2), a new semiconducting analogue of graphene. Single and bilayer MoS(2) is exfoliated from bulk and transferred to a substrate containing an array of microfabricated circular holes. The resulting suspended, free-standing membranes are deformed and eventually broken using an atomic force microscope. We find that the in-plane stiffness of monolayer MoS(2) is 180 ± 60 Nm(-1), corresponding to an effective Young's modulus of 270 ± 100 GPa, which is comparable to that of steel. Breaking occurs at an effective strain between 6 and 11% with the average breaking strength of 15 ± 3 Nm(-1) (23 GPa). The strength of strongest monolayer membranes is 11% of its Young's modulus, corresponding to the upper theoretical limit which indicates that the material can be highly crystalline and almost defect-free. Our results show that monolayer MoS(2) could be suitable for a variety of applications such as reinforcing elements in composites and for fabrication of flexible electronic devices.
              Article 0 comments Cited 646 times – based on 0 reviews     Review now
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                Author and article information

                Journal
                Title: Nature Nanotechnology
                Abbreviated Title: Nature Nanotech
                Publisher: Springer Nature
                ISSN (Print): 1748-3387
                ISSN (Electronic): 1748-3395
                Publication date Created: June 6 2017
                Publication date (Print): June 6 2017
                Volume: 12
                Issue: 6
                Pages: 509-522
                Article
                DOI: 10.1038/nnano.2017.72
                PubMed ID: 28584292
                SO-VID: 359ed44c-5ad1-43e9-979b-f532efb2591e
                Copyright © © 2017
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