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      Iron-Based Nanomaterials/Graphene Composites for Advanced Electrochemical Sensors

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          Abstract

          Iron oxide nanostructures (IONs) in combination with graphene or its derivatives—e.g., graphene oxide and reduced graphene oxide—hold great promise toward engineering of efficient nanocomposites for enhancing the performance of advanced devices in many applicative fields. Due to the peculiar electrical and electrocatalytic properties displayed by composite structures in nanoscale dimensions, increasing efforts have been directed in recent years toward tailoring the properties of IONs-graphene based nanocomposites for developing more efficient electrochemical sensors. In the present feature paper, we first reviewed the various routes for synthesizing IONs-graphene nanostructures, highlighting advantages, disadvantages and the key synthesis parameters for each method. Then, a comprehensive discussion is presented in the case of application of IONs-graphene based composites in electrochemical sensors for the determination of various kinds of (bio)chemical substances.

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          Most cited references131

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          Electric Field Effect in Atomically Thin Carbon Films

          We report a naturally-occurring two-dimensional material (graphene that can be viewed as a gigantic flat fullerene molecule, describe its electronic properties and demonstrate all-metallic field-effect transistor, which uniquely exhibits ballistic transport at submicron distances even at room temperature.
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            The reduction of graphene oxide

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              Superparamagnetic iron oxide nanoparticles (SPIONs): development, surface modification and applications in chemotherapy.

              At present, nanoparticles are used for various biomedical applications where they facilitate laboratory diagnostics and therapeutics. More specifically for drug delivery purposes, the use of nanoparticles is attracting increasing attention due to their unique capabilities and their negligible side effects not only in cancer therapy but also in the treatment of other ailments. Among all types of nanoparticles, biocompatible superparamagnetic iron oxide nanoparticles (SPIONs) with proper surface architecture and conjugated targeting ligands/proteins have attracted a great deal of attention for drug delivery applications. This review covers recent advances in the development of SPIONs together with their possibilities and limitations from fabrication to application in drug delivery. In addition, the state-of-the-art synthetic routes and surface modification of desired SPIONs for drug delivery purposes are described. Copyright © 2010 Elsevier B.V. All rights reserved.
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                Author and article information

                Journal
                Nanomaterials (Basel)
                Nanomaterials (Basel)
                nanomaterials
                Nanomaterials
                MDPI
                2079-4991
                23 November 2017
                December 2017
                : 7
                : 12
                : 406
                Affiliations
                [1 ]Center of Excellence in Electrochemistry, School of Chemistry, College of Science, University of Tehran, 14155-6455 Tehran, Iran; k.movlaee@ 123456ut.ac.ir (K.M.); ganjali@ 123456khayam.ut.ac.ir (M.R.G.); norouzi@ 123456khayam.ut.ac.ir. (P.N.)
                [2 ]Department of Engineering, University of Messina, I-98166 Messina, Italy
                Author notes
                [* ]Correspondence: gneri@ 123456unime.it ; Tel.: +39-090-397-7297
                Author information
                https://orcid.org/0000-0001-8999-060X
                Article
                nanomaterials-07-00406
                10.3390/nano7120406
                5746896
                29168771
                35de135a-32c3-4507-9251-a35b3bcf6ac3
                © 2017 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 10 October 2017
                : 16 November 2017
                Categories
                Review

                iron oxide,hematite,magnetite,maghemite,synthesis,electrochemical sensors

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