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      Electrochemical Deposition of Nanomaterials for Electrochemical Sensing

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          Abstract

          The most commonly used methods to electrodeposit nanomaterials on conductive supports or to obtain electrosynthesis nanomaterials are described. Au, layered double hydroxides (LDHs), metal oxides, and polymers are the classes of compounds taken into account. The electrochemical approach for the synthesis allows one to obtain nanostructures with well-defined morphologies, even without the use of a template, and of variable sizes simply by controlling the experimental synthesis conditions. In fact, parameters such as current density, applied potential (constant, pulsed or ramp) and duration of the synthesis play a key role in determining the shape and size of the resulting nanostructures. This review aims to describe the most recent applications in the field of electrochemical sensors of the considered nanomaterials and special attention is devoted to the analytical figures of merit of the devices.

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          Most cited references125

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          Supported metal nanoparticles on porous materials. Methods and applications.

          Nanoparticles are regarded as a major step forward to achieving the miniaturisation and nanoscaling effects and properties that have been utilised by nature for millions of years. The chemist is no longer observing and describing the behaviour of matter but is now able to manipulate and produce new types of materials with specific desired physicochemical characteristics. Such materials are receiving extensive attention across a broad range of research disciplines. The fusion between nanoparticle and nanoporous materials technology represents one of the most interesting of these rapidly expanding areas. The harnessing of nanoscale activity and selectivity, potentially provides extremely efficient catalytic materials for the production of commodity chemicals, and energy needed for a future sustainable society. In this tutorial review, we present an introduction to the field of supported metal nanoparticles (SMNPs) on porous materials, focusing on their preparation and applications in different areas.
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            Electrochemistry of conducting polymers--persistent models and new concepts.

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              "Plugging into Enzymes": nanowiring of redox enzymes by a gold nanoparticle.

              The reconstitution of an apo-flavoenzyme, apo-glucose oxidase, on a 1.4-nanometer gold nanocrystal functionalized with the cofactor flavin adenine dinucleotide and integrated into a conductive film yields a bioelectrocatalytic system with exceptional electrical contact with the electrode support. The electron transfer turnover rate of the reconstituted bioelectrocatalyst is approximately 5000 per second, compared with the rate at which molecular oxygen, the natural cosubstrate of the enzyme, accepts electrons (approximately 700 per second). The gold nanoparticle acts as an electron relay or "electrical nanoplug" for the alignment of the enzyme on the conductive support and for the electrical wiring of its redox-active center.

                Author and article information

                Journal
                Sensors (Basel)
                Sensors (Basel)
                sensors
                Sensors (Basel, Switzerland)
                MDPI
                1424-8220
                08 March 2019
                March 2019
                : 19
                : 5
                : 1186
                Affiliations
                Department of Industrial Chemistry “Toso Montanari”, Viale del Risorgimento 4, 40136 Bologna, Italy; erika.scavetta2@ 123456unibo.it (E.S.); isacco.gualandi2@ 123456unibo.it (I.G.)
                Author notes
                Author information
                https://orcid.org/0000-0002-2844-9817
                https://orcid.org/0000-0002-6823-7501
                Article
                sensors-19-01186
                10.3390/s19051186
                6427742
                30857146
                3846533d-a8e2-4f85-9aff-ab96083e8280
                © 2019 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 12 February 2019
                : 04 March 2019
                Categories
                Review

                Biomedical engineering
                electrochemical deposition,electrochemical synthesis,electrochemical sensors,gold nanomaterials,layered double hydroxides,nanostructured polymers,molecularly imprinted polymers

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