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      Anionic N-heterocyclic carbenes (NHCs): a versatile route to saturated NHCs bearing pendant weakly coordinating anions

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          Abstract

          A versatile methodology is reported for the synthesis of anionic NHCs featuring a 5-, 6-, or 7-membered saturated heterocyclic core.

          Abstract

          A versatile methodology is reported for the synthesis of anionic NHCs featuring a 5-, 6-, or 7-membered saturated heterocyclic core. Lewis acid promoted exocyclic ring closure generates systems in which the pendant borate functionality is incorporated via a CH 2 linker, allowing for electronic and steric isolation of the anionic component. Hence, a library of NHCs can be accessed which incorporate metal binding environments essentially identical to the neutral parent donors, but with significantly altered solubility profiles.

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          Most cited references 40

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          N-heterocyclic carbenes in late transition metal catalysis.

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            N-Heterocyclic Carbenes: A New Concept in Organometallic Catalysis

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              Heterocyclic Carbenes: Synthesis and Coordination Chemistry

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                Author and article information

                Journal
                ICHBD9
                Dalton Trans.
                Dalton Trans.
                Royal Society of Chemistry (RSC)
                1477-9226
                1477-9234
                2014
                2014
                : 43
                : 41
                : 15279-15282
                Affiliations
                [1 ]Inorganic Chemistry Laboratory
                [2 ]Department of Chemistry
                [3 ]University of Oxford
                [4 ]Oxford, UK
                10.1039/C4DT02662D
                © 2014
                Product
                Self URI (article page): http://xlink.rsc.org/?DOI=C4DT02662D

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