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Anionic N-heterocyclic carbenes (NHCs): a versatile route to saturated NHCs bearing pendant weakly coordinating anions

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      Abstract

      A versatile methodology is reported for the synthesis of anionic NHCs featuring a 5-, 6-, or 7-membered saturated heterocyclic core.

      Abstract

      A versatile methodology is reported for the synthesis of anionic NHCs featuring a 5-, 6-, or 7-membered saturated heterocyclic core. Lewis acid promoted exocyclic ring closure generates systems in which the pendant borate functionality is incorporated via a CH 2 linker, allowing for electronic and steric isolation of the anionic component. Hence, a library of NHCs can be accessed which incorporate metal binding environments essentially identical to the neutral parent donors, but with significantly altered solubility profiles.

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      Most cited references 40

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      N-heterocyclic carbenes in late transition metal catalysis.

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        Heterocyclic Carbenes: Synthesis and Coordination Chemistry

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          N-Heterocyclic Carbenes: A New Concept in Organometallic Catalysis

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            Author and article information

            Affiliations
            [1 ]Inorganic Chemistry Laboratory
            [2 ]Department of Chemistry
            [3 ]University of Oxford
            [4 ]Oxford, UK
            Journal
            ICHBD9
            Dalton Trans.
            Dalton Trans.
            Royal Society of Chemistry (RSC)
            1477-9226
            1477-9234
            2014
            2014
            : 43
            : 41
            : 15279-15282
            10.1039/C4DT02662D
            © 2014
            Product
            Self URI (article page): http://xlink.rsc.org/?DOI=C4DT02662D

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