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      Carboxylates as sources of carbon nucleophiles and electrophiles: comparison of decarboxylative and decarbonylative pathways

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      Chemical Science

      Royal Society of Chemistry (RSC)

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          Aryl-aryl bond formation by transition-metal-catalyzed direct arylation.

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            The heck reaction as a sharpening stone of palladium catalysis.

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              Decarboxylative coupling reactions: a modern strategy for C-C-bond formation.

              This critical review examines transition metal-catalyzed decarboxylative couplings that have emerged within recent years as a powerful strategy to form carbon-carbon or carbon-heteroatom bonds starting from carboxylic acids. In these reactions, C-C bonds to carboxylate groups are cleaved, and in their place, new carbon-carbon bonds are formed. Decarboxylative cross-couplings constitute advantageous alternatives to traditional cross-coupling or addition reactions involving preformed organometallic reagents. Decarboxylative reaction variants are also known for Heck reactions, direct arylation processes, and carbon-heteroatom bond forming reactions. This journal is © The Royal Society of Chemistry 2011
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                Author and article information

                Journal
                CSHCBM
                Chemical Science
                Chem. Sci.
                Royal Society of Chemistry (RSC)
                2041-6520
                2041-6539
                2012
                2012
                : 3
                : 9
                : 2671
                Article
                10.1039/c2sc20312j
                16888137
                © 2012
                Product
                Self URI (article page): http://xlink.rsc.org/?DOI=c2sc20312j

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