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      Fabrication and investigation of the optoelectrical properties of MoS 2/CdS heterojunction solar cells

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          Abstract

          Molybdenum disulfide (MoS 2)/cadmium sulfide (CdS) heterojunction solar cells were successfully synthesized via chemical bath deposition (CBD) and chemical vapor deposition (CVD). The as-grown CdS film on a fluorine tin oxide (FTO) substrate deposited by CBD is continuous and compact. The MoS 2 film deposited by CVD is homogeneous and continuous, with a uniform color and a thickness of approximately 10 nm. The optical absorption range of the MoS 2/CdS heterojunction covers the visible and near-infrared spectral regions of 350 to 800 nm, which is beneficial for the improvement of solar cell efficiency. Moreover, the MoS 2/CdS solar cell exhibits good current-voltage ( I- V) characteristics and pronounced photovoltaic behavior, with an open-circuit voltage of 0.66 V and a short-circuit current density of 0.227 × 10 -6 A/cm 2, comparable to the results obtained from other MoS 2-based solar cells. This research is critical to investigate more efficient and stable solar cells based on graphene-like materials in the future.

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          Emerging photoluminescence in monolayer MoS2.

          Novel physical phenomena can emerge in low-dimensional nanomaterials. Bulk MoS(2), a prototypical metal dichalcogenide, is an indirect bandgap semiconductor with negligible photoluminescence. When the MoS(2) crystal is thinned to monolayer, however, a strong photoluminescence emerges, indicating an indirect to direct bandgap transition in this d-electron system. This observation shows that quantum confinement in layered d-electron materials like MoS(2) provides new opportunities for engineering the electronic structure of matter at the nanoscale.
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            Atomically thin MoS2: A new direct-gap semiconductor

            The electronic properties of ultrathin crystals of molybdenum disulfide consisting of N = 1, 2, ... 6 S-Mo-S monolayers have been investigated by optical spectroscopy. Through characterization by absorption, photoluminescence, and photoconductivity spectroscopy, we trace the effect of quantum confinement on the material's electronic structure. With decreasing thickness, the indirect band gap, which lies below the direct gap in the bulk material, shifts upwards in energy by more than 0.6 eV. This leads to a crossover to a direct-gap material in the limit of the single monolayer. Unlike the bulk material, the MoS2 monolayer emits light strongly. The freestanding monolayer exhibits an increase in luminescence quantum efficiency by more than a factor of 1000 compared with the bulk material.
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              Two Dimensional Atomic Crystals

              We report free-standing atomic crystals that are strictly 2D and can be viewed as individual atomic planes pulled out of bulk crystals or as unrolled single-wall nanotubes. By using micromechanical cleavage, we have prepared and studied a variety of 2D crystals, including single layers of boron nitride, graphite, several dichalcogenides and complex oxides. These atomically-thin sheets (essentially gigantic 2D molecules unprotected from the immediate environment) are stable under ambient conditions, exhibit high crystal quality and are continuous on a macroscopic scale.
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                Author and article information

                Contributors
                Journal
                Nanoscale Res Lett
                Nanoscale Res Lett
                Nanoscale Research Letters
                Springer
                1931-7573
                1556-276X
                2014
                9 December 2014
                : 9
                : 1
                : 662
                Affiliations
                [1 ]School of Mathematics and Physics, Suzhou University of Science and Technology, 1# Kerui Road, Suzhou, Jiangsu 215009, China
                [2 ]Electricity Engineer Department, University of Liverpool, L69 7ZX Liverpool, UK
                Article
                1556-276X-9-662
                10.1186/1556-276X-9-662
                4273683
                3d7108c5-0ea1-4473-b9c6-ce0153a9e651
                Copyright © 2014 Gu et al.; licensee Springer.

                This is an Open Access article distributed under the terms of the Creative Commons Attribution License ( http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly credited.

                History
                : 2 September 2014
                : 25 November 2014
                Categories
                Nano Express

                Nanomaterials
                molybdenum disulfide,cds,solar cells,cvd,cbd,i-v behaviors
                Nanomaterials
                molybdenum disulfide, cds, solar cells, cvd, cbd, i-v behaviors

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