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      A Highly Stable and Insensitive Fused Triazolo-Triazine Explosive (TTX).

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          Abstract

          A fused-ring conjugated energetic molecule, 4-amino-3,7-dinitro-[1,2,4]triazolo[5,1-c] [1,2,4]triazine (TTX), has been synthesized in good yield in a two-step process starting from the known 5-amino-3-nitro-1H-1,2,4-triazole (ANTA). Characterization of TTX shows that it possesses energetic properties approaching those of 1,3,5-trinitro-1,3,5-triazacyclohexane (RDX), but with a higher thermal stability and lower sensitivity towards impact and friction.

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          Author and article information

          Journal
          Chemistry
          Chemistry (Weinheim an der Bergstrasse, Germany)
          Wiley
          1521-3765
          0947-6539
          Feb 03 2017
          : 23
          : 8
          Affiliations
          [1 ] Department of Chemistry, University of Idaho, Moscow, Idaho, 83844-2343, USA.
          [2 ] Naval Research Laboratory, Code 6030, Washington, D.C., 20375-5001, USA.
          Article
          10.1002/chem.201604919
          27862432
          3dc5303d-d244-4ba0-8a03-97d767131ecc
          History

          fused-ring compounds,heterocycles,nitro-π interactions,insensitive materials,energetic materials

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