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      Comparative thermodynamic study and phase equilibria of the Bi–Ga–Sn ternary system

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          Abstract

          The results of a comparative thermodynamic investigation of the Bi – Ga – Sn system, giving experimentally obtained results and calculated thermodynamic data, are presented in this paper. Oelsen calorimetry was performed for the experimental determination of thermodynamic properties in the section with a molar ratio of Bi: Sn = 1: 3, while the Redlich – Kister – Muggianu method was applied for thermodynamic predicting in the sections with molar ratio Bi: Sn = 1: 3, 1: 1, 3: 1. Thermodynamic parameters – partial and integral molar quantities, as well as gallium activities, were determined at the temperatures of 873 and 973 K. Phase equilibria in the Bi – Ga – Sn ternary system have been studied experimentally – using differential thermal analysis and scanning electron microscopy with energy dispersive X-rays, while the calculation of phase diagram was done according to the CALPHAD method. The phase diagram of the section with molar ratio of Bi: Sn = 1: 3 is given, as well as the phase diagram of the ternary Bi – Ga – Sn system at 373 K.

          Author and article information

          Journal
          ijmr
          International Journal of Materials Research
          Carl Hanser Verlag
          1862-5282
          2195-8556
          2007
          : 98
          : 10
          : 1025-1030
          Affiliations
          a University of Belgrade, Technical Faculty, Bor, Serbia
          b Osaka University, Graduate School of Engineering, Osaka, Japan
          c Copper Institute, Bor, Serbia
          d National Research Council (CNR), Institute for Energetics and Interphases, Genoa, Italy
          Author notes
          [* ] Correspondence address, Dr. Dragana Živković University of Belgrade Technical Faculty, VJ 12, 19210 Bor, Serbia Tel.: +381 30 424 555 Fax: +381 30 424 547 E-mail: dzivkovic@ 123456tf.bor.ac.yu
          Article
          MK101561
          10.3139/146.101561
          41601070-f945-4681-b711-a2d2e3e57aee
          © 2007, Carl Hanser Verlag, München
          History
          : 27 October 2006
          : 3 May 2007
          Page count
          References: 30, Pages: 6
          Categories
          Applied

          Materials technology,Materials characterization,Materials science
          Bi – Ga – Sn alloys,Oelsen calorimetry,Phase equilibria,Ternary systems,Alloy thermodynamics

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