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Formal SN-Type Reactions in Rhodium(III)-Catalyzed CH Bond Activation

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Advanced Synthesis & Catalysis

Wiley-Blackwell

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      Palladium-catalyzed ligand-directed C-H functionalization reactions.

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        Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality.

        In the past decade, palladium-catalyzed C-H activation/C-C bond-forming reactions have emerged as promising new catalytic transformations; however, development in this field is still at an early stage compared to the state of the art in cross-coupling reactions using aryl and alkyl halides. This Review begins with a brief introduction of four extensively investigated modes of catalysis for forming C-C bonds from C-H bonds: Pd(II)/Pd(0), Pd(II)/Pd(IV), Pd(0)/Pd(II)/Pd(IV), and Pd(0)/Pd(II) catalysis. A more detailed discussion is then directed towards the recent development of palladium(II)-catalyzed coupling of C-H bonds with organometallic reagents through a Pd(II)/Pd(0) catalytic cycle. Despite the progress made to date, improving the versatility and practicality of this new reaction remains a tremendous challenge.
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          Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation.

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            Author and article information

            Journal
            Advanced Synthesis & Catalysis
            Adv. Synth. Catal.
            Wiley-Blackwell
            16154150
            May 05 2014
            May 05 2014
            : 356
            : 7
            : 1443-1460
            10.1002/adsc.201400197
            © 2014

            http://doi.wiley.com/10.1002/tdm_license_1.1

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